CA1071413A - Process for recovering vanadium from deactivated catalysts - Google Patents
Process for recovering vanadium from deactivated catalystsInfo
- Publication number
- CA1071413A CA1071413A CA233,512A CA233512A CA1071413A CA 1071413 A CA1071413 A CA 1071413A CA 233512 A CA233512 A CA 233512A CA 1071413 A CA1071413 A CA 1071413A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- vanadium
- acid
- deactivated
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 198
- 238000000034 method Methods 0.000 title claims abstract description 99
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 95
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 230000008569 process Effects 0.000 title claims abstract description 66
- 239000002253 acid Substances 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 26
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 26
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- 239000001257 hydrogen Substances 0.000 claims abstract description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 15
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 7
- 239000011707 mineral Substances 0.000 claims abstract description 7
- 230000008929 regeneration Effects 0.000 claims abstract description 7
- 238000011069 regeneration method Methods 0.000 claims abstract description 7
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 40
- 238000000605 extraction Methods 0.000 claims description 38
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 21
- 239000001117 sulphuric acid Substances 0.000 claims description 21
- 235000011149 sulphuric acid Nutrition 0.000 claims description 21
- 235000010269 sulphur dioxide Nutrition 0.000 claims description 20
- 239000004291 sulphur dioxide Substances 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 8
- 230000001603 reducing effect Effects 0.000 claims description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 230000009849 deactivation Effects 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- 230000003247 decreasing effect Effects 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- 238000011084 recovery Methods 0.000 abstract description 16
- 230000003197 catalytic effect Effects 0.000 abstract description 9
- 239000000243 solution Substances 0.000 abstract description 8
- 238000002955 isolation Methods 0.000 abstract description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 110
- 229910052759 nickel Inorganic materials 0.000 description 56
- 239000003921 oil Substances 0.000 description 41
- 229910052751 metal Inorganic materials 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 150000002739 metals Chemical class 0.000 description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 14
- 239000005864 Sulphur Substances 0.000 description 14
- 239000000571 coke Substances 0.000 description 13
- 229920006395 saturated elastomer Polymers 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 235000010755 mineral Nutrition 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004517 catalytic hydrocracking Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- OGUCKKLSDGRKSH-UHFFFAOYSA-N oxalic acid oxovanadium Chemical compound [V].[O].C(C(=O)O)(=O)O OGUCKKLSDGRKSH-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003568 thioethers Chemical class 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 102000018210 Recoverin Human genes 0.000 description 1
- 108010076570 Recoverin Proteins 0.000 description 1
- 241000765309 Vanadis Species 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- WHDPTDWLEKQKKX-UHFFFAOYSA-N cobalt molybdenum Chemical compound [Co].[Co].[Mo] WHDPTDWLEKQKKX-UHFFFAOYSA-N 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000007775 late Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- DDTIGTPWGISMKL-UHFFFAOYSA-N molybdenum nickel Chemical compound [Ni].[Mo] DDTIGTPWGISMKL-UHFFFAOYSA-N 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- MOWMLACGTDMJRV-UHFFFAOYSA-N nickel tungsten Chemical compound [Ni].[W] MOWMLACGTDMJRV-UHFFFAOYSA-N 0.000 description 1
- HBVFXTAPOLSOPB-UHFFFAOYSA-N nickel vanadium Chemical compound [V].[Ni] HBVFXTAPOLSOPB-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/92—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/20—Obtaining niobium, tantalum or vanadium
- C22B34/22—Obtaining vanadium
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB44604/74A GB1526927A (en) | 1974-10-15 | 1974-10-15 | Process for recovering vanadium from deactivated catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1071413A true CA1071413A (en) | 1980-02-12 |
Family
ID=10434046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA233,512A Expired CA1071413A (en) | 1974-10-15 | 1975-08-15 | Process for recovering vanadium from deactivated catalysts |
Country Status (15)
| Country | Link |
|---|---|
| JP (1) | JPS6012908B2 (en, 2012) |
| AR (1) | AR224854A1 (en, 2012) |
| AU (1) | AU498495B2 (en, 2012) |
| BE (1) | BE834257A (en, 2012) |
| CA (1) | CA1071413A (en, 2012) |
| DE (1) | DE2545787A1 (en, 2012) |
| FR (1) | FR2288154A1 (en, 2012) |
| GB (1) | GB1526927A (en, 2012) |
| IT (1) | IT1043322B (en, 2012) |
| MX (1) | MX3049E (en, 2012) |
| NL (1) | NL186587C (en, 2012) |
| NO (1) | NO143521C (en, 2012) |
| SE (1) | SE410474B (en, 2012) |
| SU (1) | SU741780A3 (en, 2012) |
| ZA (1) | ZA756443B (en, 2012) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7703181A (nl) * | 1977-03-24 | 1978-09-26 | Shell Int Research | Verbeterde werkwijze voor het winnen van vanadium van gedesactiveerde katalysatoren. |
| NL7703180A (nl) * | 1977-03-24 | 1978-09-26 | Shell Int Research | Verbeterde werkwijze voor het winnen van vanadium van gedesactiveerde katalysatoren. |
| US4272401A (en) | 1978-09-01 | 1981-06-09 | Exxon Research & Engineering Co. | Regeneration of spent hydrodesulfurization catalyst with heteropoly acids |
| CA1163810A (en) * | 1980-02-20 | 1984-03-20 | Petrus J.W.M. Van Den Bosch | Process for the removal of vanadium-containing acid from an acid-extracted deactivated demetallization catalyst |
| NL8103964A (nl) | 1981-08-26 | 1983-03-16 | Shell Int Research | Werkwijze voor het winnen van vijfwaardige vanadium verbindingen uit zure katalysator extracten. |
| US4595666A (en) * | 1981-11-02 | 1986-06-17 | Hri, Inc. | Catalyst rejuvenation process for removal of metal contaminants |
| US4454240A (en) * | 1981-11-02 | 1984-06-12 | Hri, Inc. | Catalyst regeneration process including metal contaminants removal |
| DE3460144D1 (en) * | 1983-04-01 | 1986-06-26 | Monsanto Co | Recovery of vanadium and copper from adipic acid production |
| DD239348A5 (de) * | 1985-07-19 | 1986-09-24 | ��������@�����������@�@������������@���������@����@����������@���k�� | Verfahren zur verarbeitung von vanadinhaltigen altkatalysatoren |
| CA1293380C (en) * | 1985-12-11 | 1991-12-24 | Just Jan Christiaan Jansz | Vanadium recovery process |
| GB8610442D0 (en) * | 1986-04-29 | 1986-06-04 | Shell Int Research | Regeneration of spent alumina-based catalysts |
| FR2614613B1 (fr) * | 1987-04-29 | 1989-06-09 | Rhone Poulenc Chimie | Procede de recuperation du vanadium |
| US5254513A (en) * | 1991-05-20 | 1993-10-19 | Texaco, Inc. | Method for the reactivation of spent alumina-supported hydrotreating catalysts |
| US5230791A (en) * | 1991-07-03 | 1993-07-27 | Texaco Inc. | Process for the reactivation of spent alumina-supported hydrotreating catalysts |
| DE4216798A1 (de) * | 1992-05-21 | 1993-11-25 | Metallgesellschaft Ag | Verfahren zur Aufarbeitung von vanadiumhaltigen Rückständen |
| BR122023003434B1 (pt) | 2016-02-23 | 2024-01-30 | John Crane Uk Ltd | Sistema de vedação mecânica configurado para detectar autonomamente uma perda de lubrificação dentro de uma interface de vedação deslizante de uma vedação mecânica, sistema de vedação mecânica que tem um subsistema de diagnóstico preditivo customizável configurado para ser adaptado para se adequar às necessidades individuais do onsumidor, condições ambientais particulares e/ou aplicações específicas, e sistema de vedação mecânica configurado para detectar condições de operação e fornecer avaliações de integridade em tempo real a um usuário durante a operação |
| CN116920877B (zh) * | 2022-04-06 | 2025-08-05 | 中国石油化工股份有限公司 | 一种金属沉积失活加氢催化剂的再生方法 |
| CN116920878B (zh) * | 2022-04-06 | 2025-07-04 | 中国石油化工股份有限公司 | 一种失活催化剂的再利用方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL106228C (en, 2012) * | 1956-12-28 | |||
| US3791989A (en) * | 1971-03-12 | 1974-02-12 | Chevron Res | Catalyst rejuvenation with oxalic acid |
| JPS4923447A (en, 2012) * | 1972-06-27 | 1974-03-01 |
-
1974
- 1974-10-15 GB GB44604/74A patent/GB1526927A/en not_active Expired
-
1975
- 1975-08-15 CA CA233,512A patent/CA1071413A/en not_active Expired
- 1975-10-07 BE BE1006931A patent/BE834257A/xx not_active IP Right Cessation
- 1975-10-13 JP JP50122575A patent/JPS6012908B2/ja not_active Expired
- 1975-10-13 SE SE7511450A patent/SE410474B/xx not_active IP Right Cessation
- 1975-10-13 AU AU85669/75A patent/AU498495B2/en not_active Expired
- 1975-10-13 SU SU752182547A patent/SU741780A3/ru active
- 1975-10-13 MX MX100089U patent/MX3049E/es unknown
- 1975-10-13 NL NLAANVRAGE7511993,A patent/NL186587C/xx not_active IP Right Cessation
- 1975-10-13 ZA ZA00756443A patent/ZA756443B/xx unknown
- 1975-10-13 FR FR7531255A patent/FR2288154A1/fr active Granted
- 1975-10-13 AR AR260772A patent/AR224854A1/es active
- 1975-10-13 IT IT28227/75A patent/IT1043322B/it active
- 1975-10-13 NO NO753452A patent/NO143521C/no unknown
- 1975-10-13 DE DE19752545787 patent/DE2545787A1/de active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| NL7511993A (nl) | 1976-04-21 |
| AU498495B2 (en) | 1979-03-15 |
| GB1526927A (en) | 1978-10-04 |
| FR2288154A1 (fr) | 1976-05-14 |
| ZA756443B (en) | 1976-09-29 |
| FR2288154B1 (en, 2012) | 1980-07-25 |
| JPS5164412A (en, 2012) | 1976-06-03 |
| NO143521B (no) | 1980-11-24 |
| BE834257A (nl) | 1976-04-07 |
| SU741780A3 (ru) | 1980-06-15 |
| SE410474B (sv) | 1979-10-15 |
| AR224854A1 (es) | 1982-01-29 |
| NO143521C (no) | 1981-03-04 |
| NL186587B (nl) | 1990-08-01 |
| JPS6012908B2 (ja) | 1985-04-04 |
| MX3049E (es) | 1980-03-04 |
| AU8566975A (en) | 1977-04-21 |
| SE7511450L (sv) | 1976-04-20 |
| NO753452L (en, 2012) | 1976-04-21 |
| IT1043322B (it) | 1980-02-20 |
| DE2545787A1 (de) | 1976-04-29 |
| NL186587C (nl) | 1991-01-02 |
| DE2545787C2 (en, 2012) | 1989-08-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |