CA1070909A - Nitrogen dioxide-oxygen delignification - Google Patents
Nitrogen dioxide-oxygen delignificationInfo
- Publication number
- CA1070909A CA1070909A CA251,752A CA251752A CA1070909A CA 1070909 A CA1070909 A CA 1070909A CA 251752 A CA251752 A CA 251752A CA 1070909 A CA1070909 A CA 1070909A
- Authority
- CA
- Canada
- Prior art keywords
- pulp
- oxygen
- consistency
- stage
- treatment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- SZELVZBEQSHILI-UHFFFAOYSA-N [N+](=O)[O-].[O] Chemical compound [N+](=O)[O-].[O] SZELVZBEQSHILI-UHFFFAOYSA-N 0.000 title 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000001301 oxygen Substances 0.000 claims abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 41
- 238000000034 method Methods 0.000 claims abstract description 33
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000012978 lignocellulosic material Substances 0.000 claims abstract description 22
- MGWGWNFMUOTEHG-UHFFFAOYSA-N 4-(3,5-dimethylphenyl)-1,3-thiazol-2-amine Chemical compound CC1=CC(C)=CC(C=2N=C(N)SC=2)=C1 MGWGWNFMUOTEHG-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 20
- 239000002655 kraft paper Substances 0.000 claims abstract description 18
- 238000005406 washing Methods 0.000 claims abstract description 8
- 229920001131 Pulp (paper) Polymers 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 75
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 60
- 239000004155 Chlorine dioxide Substances 0.000 claims description 30
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 30
- 239000000460 chlorine Substances 0.000 claims description 24
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 23
- 229910052801 chlorine Inorganic materials 0.000 claims description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000012736 aqueous medium Substances 0.000 claims description 10
- 239000002585 base Substances 0.000 claims description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 7
- 238000000605 extraction Methods 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 5
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 2
- 239000002609 medium Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 15
- 238000011084 recovery Methods 0.000 abstract description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 7
- 238000004537 pulping Methods 0.000 abstract description 5
- 230000009467 reduction Effects 0.000 abstract description 4
- 229920005610 lignin Polymers 0.000 abstract description 2
- 238000004061 bleaching Methods 0.000 description 30
- 239000011122 softwood Substances 0.000 description 8
- 239000011121 hardwood Substances 0.000 description 7
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000007900 aqueous suspension Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 239000003518 caustics Substances 0.000 description 5
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 239000002023 wood Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 241000609240 Ambelania acida Species 0.000 description 1
- 239000004857 Balsam Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 244000305267 Quercus macrolepis Species 0.000 description 1
- 240000003021 Tsuga heterophylla Species 0.000 description 1
- 235000008554 Tsuga heterophylla Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000006172 buffering agent Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004076 pulp bleaching Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Paper (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (12)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA251,752A CA1070909A (en) | 1976-05-04 | 1976-05-04 | Nitrogen dioxide-oxygen delignification |
| NZ183555A NZ183555A (en) | 1976-05-04 | 1977-03-09 | Nitrogen dioxide-alkali/oxygen treatment for lignocellulose delignification |
| ZA00771424A ZA771424B (en) | 1976-05-04 | 1977-03-09 | Nitrogen dioxide-oxygen delignification |
| AU23111/77A AU498646B2 (en) | 1976-05-04 | 1977-03-10 | Delignification |
| NO771297A NO771297L (no) | 1976-05-04 | 1977-04-14 | Fremgangsm}te til delignifisering av cellulosemateriale under anvendelse av nitrogendioksyd |
| DE19772717257 DE2717257A1 (de) | 1976-05-04 | 1977-04-19 | Verfahren zur entholzung von lignocellulosematerial |
| BR7702713A BR7702713A (pt) | 1976-05-04 | 1977-04-28 | Processo para deslignificacao de material lignocelulosico |
| FI771383A FI771383A7 (cs) | 1976-05-04 | 1977-04-29 | |
| JP5003677A JPS52134690A (en) | 1976-05-04 | 1977-05-02 | Process for removing lignin from lignocellulose substance |
| SE7705136A SE7705136L (sv) | 1976-05-04 | 1977-05-03 | Forfarande for delignifiering av cellulosamaterial |
| FR7713425A FR2350421A1 (fr) | 1976-05-04 | 1977-05-03 | Procede de delignification utilisant successivement du bioxyde d'azote et de l'oxygene |
| ES458434A ES458434A1 (es) | 1976-05-04 | 1977-05-04 | Procedimiento para la deslignificacion de material lignoce- lulosico. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA251,752A CA1070909A (en) | 1976-05-04 | 1976-05-04 | Nitrogen dioxide-oxygen delignification |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1070909A true CA1070909A (en) | 1980-02-05 |
Family
ID=4105864
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA251,752A Expired CA1070909A (en) | 1976-05-04 | 1976-05-04 | Nitrogen dioxide-oxygen delignification |
Country Status (12)
| Country | Link |
|---|---|
| JP (1) | JPS52134690A (cs) |
| AU (1) | AU498646B2 (cs) |
| BR (1) | BR7702713A (cs) |
| CA (1) | CA1070909A (cs) |
| DE (1) | DE2717257A1 (cs) |
| ES (1) | ES458434A1 (cs) |
| FI (1) | FI771383A7 (cs) |
| FR (1) | FR2350421A1 (cs) |
| NO (1) | NO771297L (cs) |
| NZ (1) | NZ183555A (cs) |
| SE (1) | SE7705136L (cs) |
| ZA (1) | ZA771424B (cs) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4406735A (en) * | 1980-05-27 | 1983-09-27 | Mo Och Domsjo Aktiebolag | Process for alkaline oxygen gas bleaching of cellulose pulp |
| US4897156A (en) * | 1981-09-21 | 1990-01-30 | Mo Och Domsjo Aktiebolag | Process for activating cellulose pulp with NO and/or NO2 and oxygen in the presence of nitric acid and then delignifying bleaching the activated cellulose pulp |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE421938B (sv) * | 1980-06-05 | 1982-02-08 | Mo Och Domsjoe Ab | Forfarande for behandling av cellulosamassa med kveveoxider fore syrgasblekning |
| SE445122B (sv) * | 1980-12-17 | 1986-06-02 | Mo Och Domsjoe Ab | Forfarande for delignifiering av cellulosamassa i nervaro av kvevedioxid |
| SE425674B (sv) * | 1981-03-23 | 1982-10-25 | Mo Och Domsjoe Ab | Forfarande for delignifiering av cellulosamassa med kvevedioxid och syrgas |
| DE3118384C1 (de) * | 1981-05-09 | 1982-11-11 | Mannesmann AG, 4000 Düsseldorf | Verfahren zum Bleichen von chemisch hergestelltem Zellstoff mit Ozon |
| SE450394B (sv) * | 1981-12-30 | 1987-06-22 | Mo Och Domsjoe Ab | Forfarande for blekning av ligninhaltig cellulosamassa |
| JP2002302888A (ja) * | 2001-04-05 | 2002-10-18 | Oji Paper Co Ltd | 漂白パルプの製造方法 |
| FI20115754A0 (fi) * | 2011-03-22 | 2011-07-15 | Andritz Oy | Menetelmä ja järjestely kemiallisen massan käsittelemiseksi |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1505070A (en) * | 1974-06-11 | 1978-03-22 | Canadian Ind | Process for bleaching of lignocellulosic material |
-
1976
- 1976-05-04 CA CA251,752A patent/CA1070909A/en not_active Expired
-
1977
- 1977-03-09 ZA ZA00771424A patent/ZA771424B/xx unknown
- 1977-03-09 NZ NZ183555A patent/NZ183555A/xx unknown
- 1977-03-10 AU AU23111/77A patent/AU498646B2/en not_active Expired
- 1977-04-14 NO NO771297A patent/NO771297L/no unknown
- 1977-04-19 DE DE19772717257 patent/DE2717257A1/de not_active Withdrawn
- 1977-04-28 BR BR7702713A patent/BR7702713A/pt not_active IP Right Cessation
- 1977-04-29 FI FI771383A patent/FI771383A7/fi not_active Application Discontinuation
- 1977-05-02 JP JP5003677A patent/JPS52134690A/ja active Pending
- 1977-05-03 SE SE7705136A patent/SE7705136L/xx unknown
- 1977-05-03 FR FR7713425A patent/FR2350421A1/fr active Granted
- 1977-05-04 ES ES458434A patent/ES458434A1/es not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4406735A (en) * | 1980-05-27 | 1983-09-27 | Mo Och Domsjo Aktiebolag | Process for alkaline oxygen gas bleaching of cellulose pulp |
| US4897156A (en) * | 1981-09-21 | 1990-01-30 | Mo Och Domsjo Aktiebolag | Process for activating cellulose pulp with NO and/or NO2 and oxygen in the presence of nitric acid and then delignifying bleaching the activated cellulose pulp |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2311177A (en) | 1978-09-14 |
| NO771297L (no) | 1977-11-07 |
| AU498646B2 (en) | 1979-03-22 |
| SE7705136L (sv) | 1977-11-05 |
| FR2350421A1 (fr) | 1977-12-02 |
| FR2350421B1 (cs) | 1982-08-13 |
| DE2717257A1 (de) | 1977-11-17 |
| ES458434A1 (es) | 1978-03-16 |
| FI771383A7 (cs) | 1977-11-05 |
| NZ183555A (en) | 1978-11-13 |
| BR7702713A (pt) | 1978-03-21 |
| ZA771424B (en) | 1978-02-22 |
| JPS52134690A (en) | 1977-11-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |