CA1068696A - Catalytic trimerization of aromatic nitriles and triaryl-s-triazine ring cross-linked high temperature resistant polymers and co-polymers made thereby - Google Patents

Catalytic trimerization of aromatic nitriles and triaryl-s-triazine ring cross-linked high temperature resistant polymers and co-polymers made thereby

Info

Publication number
CA1068696A
CA1068696A CA237,372A CA237372A CA1068696A CA 1068696 A CA1068696 A CA 1068696A CA 237372 A CA237372 A CA 237372A CA 1068696 A CA1068696 A CA 1068696A
Authority
CA
Canada
Prior art keywords
range
aromatic
group
nitrile
aromatic nitrile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA237,372A
Other languages
English (en)
French (fr)
Inventor
Li-Chen Hsu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
National Aeronautics and Space Administration NASA
Original Assignee
National Aeronautics and Space Administration NASA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Aeronautics and Space Administration NASA filed Critical National Aeronautics and Space Administration NASA
Application granted granted Critical
Publication of CA1068696A publication Critical patent/CA1068696A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/14—Polyamide-imides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
    • C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
    • C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
    • C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
    • C07D251/24—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to three ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/0622—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms
    • C08G73/0638—Polycondensates containing six-membered rings, not condensed with other rings, with nitrogen atoms as the only ring hetero atoms with at least three nitrogen atoms in the ring
    • C08G73/065—Preparatory processes
    • C08G73/0655—Preparatory processes from polycyanurates
    • C08G73/0661—Preparatory processes from polycyanurates characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1003—Preparatory processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C08G73/1067—Wholly aromatic polyimides, i.e. having both tetracarboxylic and diamino moieties aromatically bound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/18—Polybenzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/20—Pyrrones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CA237,372A 1974-10-10 1975-10-09 Catalytic trimerization of aromatic nitriles and triaryl-s-triazine ring cross-linked high temperature resistant polymers and co-polymers made thereby Expired CA1068696A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/513,613 US4061856A (en) 1974-10-10 1974-10-10 Trimerization of aromatic nitriles

Publications (1)

Publication Number Publication Date
CA1068696A true CA1068696A (en) 1979-12-25

Family

ID=24043979

Family Applications (1)

Application Number Title Priority Date Filing Date
CA237,372A Expired CA1068696A (en) 1974-10-10 1975-10-09 Catalytic trimerization of aromatic nitriles and triaryl-s-triazine ring cross-linked high temperature resistant polymers and co-polymers made thereby

Country Status (7)

Country Link
US (2) US4061856A (enExample)
JP (1) JPS6030674B2 (enExample)
CA (1) CA1068696A (enExample)
DE (1) DE2544740A1 (enExample)
FR (1) FR2287448A1 (enExample)
GB (1) GB1518836A (enExample)
SE (1) SE430890B (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4458041A (en) * 1979-02-01 1984-07-03 Chernikhov Alexei Y Heat-resistant composition
US4555565A (en) * 1983-03-31 1985-11-26 Hsu Li Chen Ring-chain polymer containing triaryl-s-triazine ring and other heat-resistant heterocyclic rings
JPS61182165U (enExample) * 1985-05-01 1986-11-13
US4963645A (en) * 1987-08-25 1990-10-16 Ube Industries, Ltd. Terminal-modified imide oligomer and solution composition of the same
US5026822A (en) * 1988-07-12 1991-06-25 Hoechst Celanese Corp. High molecular weight polyimide, method of making same and articles formed therefrom
US5049649A (en) * 1988-07-12 1991-09-17 Hoechst Celanese Corp. Colorless films formed from fluorinated polyimides
US5208852A (en) * 1988-09-27 1993-05-04 Seiko Epson Corporation Sound generation circuit
JP2597181B2 (ja) * 1989-04-18 1997-04-02 宇部興産株式会社 熱硬化性樹脂組成物およびドライフィルム
US5338827A (en) * 1990-01-30 1994-08-16 Trw Inc. Polyimide resins useful at high temperatures
US5432001A (en) * 1990-01-30 1995-07-11 Trw Inc. Concentrated prepolymer composition useful for forming polyimide articles
CH686305A5 (de) * 1993-09-28 1996-02-29 Ciba Geigy Ag Verfahren zur Herstellung von 1,3,5-Triazinen.
JP5041271B2 (ja) * 2005-05-31 2012-10-03 宇部興産株式会社 加熱硬化性溶液組成物および未硬化樹脂複合体
CN101899014B (zh) * 2010-08-13 2012-06-13 中南大学 2,4-二（4-甲羧基苯基）-6-苯基-1,3,5-三嗪及其衍生物和制备方法
CN103012297B (zh) * 2012-12-13 2015-05-06 中南大学 一种含均三嗪结构的氰酸酯和聚合物及制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3060179A (en) * 1962-10-23 Polymerization of aromatic nitriles
DE1157781B (de) * 1960-12-21 1963-11-21 Chemische Fakultaet Der Mgu Ia Verfahren zur Polymerisation von aliphatischen oder aromatischen Nitrilen
US3502579A (en) * 1964-11-13 1970-03-24 Monsanto Res Corp Perfluorocarbondinitrile bearings
US3470176A (en) * 1967-03-10 1969-09-30 Minnesota Mining & Mfg Catalyzed nitrile trimerization process
FR1548307A (enExample) * 1967-06-05 1968-12-06
DE1770796A1 (de) * 1968-07-04 1971-12-02 Dynamit Nobel Ag Verfahren zur Herstellung von Polyimiden
US3654192A (en) * 1968-08-19 1972-04-04 Minnesota Mining & Mfg Poly(arylene s-triazines)
US3560444A (en) * 1968-09-09 1971-02-02 Monsanto Res Corp Heat reactive mixtures of bis(hydrocarbyloxyalkyl) esters of aromatic tetracarboxylic acids and aromatic diamines
US3518264A (en) * 1968-10-25 1970-06-30 Goodrich Co B F Process for the preparation of triacrylyl perhydro-s-triazines
US3728344A (en) * 1970-05-22 1973-04-17 Hooker Chemical Corp Process for preparing triazines and crosslinked polymers of copolymers
US3655632A (en) * 1970-09-15 1972-04-11 Kuraray Co Process for the production of aromatic polybenzimidazoles
US3804804A (en) * 1970-11-23 1974-04-16 Horizons Inc Preparation of heterocyclic polymers from heteroaromatic tetramines
US3809693A (en) * 1971-09-01 1974-05-07 Texaco Inc Process for the trimerization of nitriles
US3943107A (en) * 1974-01-04 1976-03-09 Ciba-Geigy Corporation Processable high temperature polymers prepared from amine terminated polymers and cyanamides of polyfunctional secondary amines
US3993631A (en) * 1974-08-23 1976-11-23 The United States Of America As Represented By The Secretary Of The Navy Polyphthalocyanines prepared from N,N-bis(3,4-dicyanophenyl) alkanediamides

Also Published As

Publication number Publication date
JPS5165780A (en) 1976-06-07
SE7510867L (sv) 1976-04-12
JPS6030674B2 (ja) 1985-07-17
US4061856A (en) 1977-12-06
GB1518836A (en) 1978-07-26
SE430890B (sv) 1983-12-19
DE2544740A1 (de) 1976-04-22
FR2287448A1 (fr) 1976-05-07
FR2287448B1 (enExample) 1979-07-13
US4159262A (en) 1979-06-26

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