CA1066023A - Process for production of titanium tetrachloride - Google Patents
Process for production of titanium tetrachlorideInfo
- Publication number
- CA1066023A CA1066023A CA248,922A CA248922A CA1066023A CA 1066023 A CA1066023 A CA 1066023A CA 248922 A CA248922 A CA 248922A CA 1066023 A CA1066023 A CA 1066023A
- Authority
- CA
- Canada
- Prior art keywords
- solid
- gas
- process according
- reactor
- carbonaceous substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 37
- 230000008569 process Effects 0.000 title claims abstract description 37
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title abstract description 9
- 239000000463 material Substances 0.000 claims abstract description 33
- 239000003575 carbonaceous material Substances 0.000 claims abstract description 26
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000460 chlorine Substances 0.000 claims abstract description 19
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 18
- 238000005243 fluidization Methods 0.000 claims abstract description 14
- 239000007787 solid Substances 0.000 claims description 84
- 239000000725 suspension Substances 0.000 claims description 31
- 238000006243 chemical reaction Methods 0.000 claims description 28
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 12
- 239000000571 coke Substances 0.000 claims description 11
- 239000002893 slag Substances 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 10
- 229910052719 titanium Inorganic materials 0.000 claims description 10
- 239000007795 chemical reaction product Substances 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 6
- 238000010992 reflux Methods 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000012141 concentrate Substances 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- 241001149900 Fusconaia subrotunda Species 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 238000010924 continuous production Methods 0.000 claims description 2
- 230000036647 reaction Effects 0.000 claims 1
- 239000007789 gas Substances 0.000 description 44
- 239000012071 phase Substances 0.000 description 17
- 238000005660 chlorination reaction Methods 0.000 description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 4
- 230000032258 transport Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000012159 carrier gas Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 101100238304 Mus musculus Morc1 gene Proteins 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000011329 calcined coke Substances 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009491 slugging Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 230000000153 supplemental effect Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B34/00—Obtaining refractory metals
- C22B34/10—Obtaining titanium, zirconium or hafnium
- C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
- C22B34/1218—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by dry processes
- C22B34/1222—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by dry processes using a halogen containing agent
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/02—Halides of titanium
- C01G23/022—Titanium tetrachloride
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3826075A JPS51112499A (en) | 1975-03-28 | 1975-03-28 | The formation of titanium tetrachloride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1066023A true CA1066023A (en) | 1979-11-13 |
Family
ID=12520339
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA248,922A Expired CA1066023A (en) | 1975-03-28 | 1976-03-26 | Process for production of titanium tetrachloride |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US4014976A (enExample) |
| JP (1) | JPS51112499A (enExample) |
| CA (1) | CA1066023A (enExample) |
| DE (1) | DE2612804C2 (enExample) |
| GB (1) | GB1506691A (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2273604C2 (ru) * | 2004-06-07 | 2006-04-10 | Корюшин Александр Порфирьевич | Способ получения раствора четыреххлористого титана |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2460893A1 (fr) * | 1979-07-12 | 1981-01-30 | Inst Titana | Procede de production de tetrachlorure de titane et dispositif pour sa mise en oeuvre |
| US4435365A (en) | 1982-05-12 | 1984-03-06 | Kerr-Mcgee Chemical Corporation | Process for producing titanium tetrachloride |
| US4442076A (en) * | 1982-11-17 | 1984-04-10 | Scm Corporation | Entrained downflow chlorination of fine titaniferous material |
| US4440730A (en) * | 1982-11-17 | 1984-04-03 | Scm Corporation | Chlorination of titanium ores using lignitic reactive carbons |
| JPS59164550U (ja) * | 1983-04-18 | 1984-11-05 | 池田物産株式会社 | 車両用シ−トにおける取出し回動部材の取付構造 |
| US4540551A (en) * | 1984-08-08 | 1985-09-10 | Scm Corporation | Two stage chlorination of titaniferous ore with FeCl3 reclamation |
| US4519988A (en) * | 1984-08-08 | 1985-05-28 | Scm Corporation | Two stage chlorination of titaniferous ore |
| US5320815A (en) * | 1987-07-13 | 1994-06-14 | E. I. Du Pont De Nemours And Company | Fluidized bed process |
| AU628791B2 (en) * | 1987-11-10 | 1992-09-24 | E.I. Du Pont De Nemours And Company | Improved fluidized bed process for chlorinating titanium-containing material and coke useful in such process |
| US5032372A (en) * | 1988-06-08 | 1991-07-16 | Scm Chemicals, Inc. | Dilute-phase chlorination procedure |
| DE4442783A1 (de) * | 1994-12-01 | 1996-06-05 | Kronos Titan Gmbh | Verfahren zum Erhöhen der Ausbeute bei der Chlorierung titanhaltiger Rohstoffe |
| US20050135991A1 (en) * | 2003-12-19 | 2005-06-23 | Engle Michael J. | Carbonaceous reductant for use in the fluidized bed chlorination of titanium-containing solids |
| US20090148364A1 (en) * | 2007-12-05 | 2009-06-11 | Heiko Frahm | Method for Increasing the Yield When Chlorinating Titaniferous Raw Materials |
| DE102008014722A1 (de) * | 2007-12-05 | 2009-07-30 | Kronos International, Inc. | Verfahren zur Erhöhung der Ausbeute bei der Chlorierung titanhaltiger Rohstoffe |
| JP6211940B2 (ja) * | 2014-01-27 | 2017-10-11 | 株式会社大阪チタニウムテクノロジーズ | 四塩化チタン製造方法 |
| CN104911336B (zh) * | 2015-06-29 | 2017-05-17 | 北京科技大学 | 一种下行流石煤预富集钒的方法及装置 |
| CN105056855B (zh) * | 2015-07-30 | 2017-06-06 | 重庆大学 | 一种底部进排料的循环氯化装置 |
| CN106379935B (zh) * | 2016-11-11 | 2018-01-26 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种生产四氯化钛的装置和方法 |
| JP6944342B2 (ja) * | 2017-10-30 | 2021-10-06 | 東邦チタニウム株式会社 | 四塩化チタンの製造方法 |
| CN111847507A (zh) * | 2020-07-06 | 2020-10-30 | 南通江山农药化工股份有限公司 | 一种气相法纳米二氧化钛的制备工艺 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2320273A (en) * | 1940-05-16 | 1943-05-25 | Standard Oil Dev Co | Regeneration of solid contact material |
| BE461070A (enExample) * | 1941-07-03 | |||
| GB661560A (en) * | 1949-02-05 | 1951-11-21 | New Jersey Zinc Co | Improvements in process for contacting solids and gases employing fluid bed operation |
| US2683685A (en) * | 1951-07-28 | 1954-07-13 | Standard Oil Dev Co | Elutriation of finely divided solids |
| US2786280A (en) * | 1954-03-12 | 1957-03-26 | Ca Nat Research Council | Method of contacting solid particles with fluids |
| US2940826A (en) * | 1957-09-12 | 1960-06-14 | Monsanto Chemicals | Zirconium tetrachloride production |
| US3488143A (en) * | 1966-06-08 | 1970-01-06 | Cabot Corp | Metal halides production in fluid bed |
| US3495936A (en) * | 1967-06-08 | 1970-02-17 | Du Pont | Dilute phase chlorination of titaniferous ores |
| JPS5550895B2 (enExample) * | 1974-03-23 | 1980-12-20 |
-
1975
- 1975-03-28 JP JP3826075A patent/JPS51112499A/ja active Granted
-
1976
- 1976-03-24 US US05/670,074 patent/US4014976A/en not_active Expired - Lifetime
- 1976-03-25 DE DE2612804A patent/DE2612804C2/de not_active Expired
- 1976-03-26 CA CA248,922A patent/CA1066023A/en not_active Expired
- 1976-03-26 GB GB1230776A patent/GB1506691A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2273604C2 (ru) * | 2004-06-07 | 2006-04-10 | Корюшин Александр Порфирьевич | Способ получения раствора четыреххлористого титана |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2612804A1 (de) | 1976-09-30 |
| US4014976A (en) | 1977-03-29 |
| JPS51112499A (en) | 1976-10-04 |
| DE2612804C2 (de) | 1984-01-05 |
| GB1506691A (en) | 1978-04-12 |
| JPS5720250B2 (enExample) | 1982-04-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1066023A (en) | Process for production of titanium tetrachloride | |
| EP0125259B1 (en) | Improvement in entrained downflow chlorination of fine titaniferous material | |
| US3495936A (en) | Dilute phase chlorination of titaniferous ores | |
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