CA1065885A - Preparation de diacetate d'ethylidene - Google Patents

Preparation de diacetate d'ethylidene

Info

Publication number
CA1065885A
CA1065885A CA246,466A CA246466A CA1065885A CA 1065885 A CA1065885 A CA 1065885A CA 246466 A CA246466 A CA 246466A CA 1065885 A CA1065885 A CA 1065885A
Authority
CA
Canada
Prior art keywords
accordance
promoter
group
noble metal
reaction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA246,466A
Other languages
English (en)
Inventor
Charles N. Winnick
Nabil Rizkalla
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Halcon International Inc
Original Assignee
Halcon International Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/654,662 external-priority patent/US5138093A/en
Application filed by Halcon International Inc filed Critical Halcon International Inc
Application granted granted Critical
Publication of CA1065885A publication Critical patent/CA1065885A/fr
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
CA246,466A 1975-03-10 1976-02-24 Preparation de diacetate d'ethylidene Expired CA1065885A (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55674975A 1975-03-10 1975-03-10
US06/654,662 US5138093A (en) 1975-03-10 1976-02-05 Process for preparing ethylidene diacetate

Publications (1)

Publication Number Publication Date
CA1065885A true CA1065885A (fr) 1979-11-06

Family

ID=27071246

Family Applications (1)

Application Number Title Priority Date Filing Date
CA246,466A Expired CA1065885A (fr) 1975-03-10 1976-02-24 Preparation de diacetate d'ethylidene

Country Status (13)

Country Link
JP (1) JPS5946936B2 (fr)
BR (1) BR7601412A (fr)
CA (1) CA1065885A (fr)
DD (1) DD124247A5 (fr)
DE (1) DE2610035C2 (fr)
ES (1) ES445919A1 (fr)
FR (1) FR2303788A1 (fr)
GB (1) GB1538782A (fr)
IT (1) IT1057944B (fr)
NL (1) NL176452C (fr)
NO (1) NO148712C (fr)
RO (1) RO69285A (fr)
SE (1) SE426583B (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4246195A (en) * 1978-10-06 1981-01-20 Halcon Research And Development Corporation Purification of carbonylation products
US4302611A (en) * 1978-12-29 1981-11-24 Halcon Research & Development Corp. Preparation of acetaldehyde
NL7908980A (nl) * 1978-12-29 1980-07-01 Halcon Res & Dev Werkwijze voor het bereiden van aceetaldehyde.
JPS5643241A (en) * 1979-09-13 1981-04-21 Mitsubishi Gas Chem Co Inc Preparation of ethylidene diacetate
DE2941232A1 (de) * 1979-10-11 1981-04-23 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von 1,1-diacetoxiethan
DE3067179D1 (en) * 1979-11-02 1984-04-26 Mitsubishi Gas Chemical Co Process for producing ethylidenediacetate
JPS5934164B2 (ja) * 1980-03-06 1984-08-21 三菱瓦斯化学株式会社 エチリデンジアセテ−トの製造法
US4429150A (en) * 1980-09-15 1984-01-31 Shell Oil Company Manufacture of ethylidene diacetate
EP0048173B1 (fr) * 1980-09-16 1985-01-16 Mitsubishi Gas Chemical Company, Inc. Procédé de production d'acétate de vinyle en une étape
JPS6033418B2 (ja) * 1980-09-16 1985-08-02 三菱瓦斯化学株式会社 酢酸ビニルの製造方法
US4323697A (en) * 1980-12-24 1982-04-06 The Halcon Sd Group, Inc. Process for preparing ethylidene diacetate
US4328362A (en) * 1980-12-24 1982-05-04 The Halcon Sd Group, Inc. Conversion of acetic anhydride to ethylidene diacetate
US4733006A (en) * 1980-12-29 1988-03-22 Monsanto Company Carbonylation process with an alkali metal acetate as catalyst stabilizer
US4886905A (en) * 1981-01-30 1989-12-12 Eastman Kodak Company Preparation of ethyl acetate
US4581473A (en) * 1981-01-30 1986-04-08 Eastman Kodak Company Preparation of ethylidene diacetate
WO1982002712A1 (fr) * 1981-01-30 1982-08-19 Kodak Co Eastman Procede d'hydrogenation de l'anhydride acetique utilisant un catalyseur contenant un metal noble
US4340569A (en) 1981-03-06 1982-07-20 The Halcon Sd Group, Inc. Treatment of carbonylation residues
US4341741A (en) 1981-03-06 1982-07-27 The Halcon Sd Group, Inc. Recovery of rhodium from carbonylation residues
IT1144698B (it) * 1981-04-06 1986-10-29 Giuseppe Braca Processo di produzione all'acetato di etile mediante omologazione dell'acetato di metile
US4461910A (en) * 1981-05-15 1984-07-24 Shell Oil Company Process for the co-production of dicarboxylates and acids
US4476237A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
US4476238A (en) * 1981-05-28 1984-10-09 The Halcon Sd Group, Inc. Separation of tars from carbonylation reaction mixtures
YU43520B (en) * 1981-10-09 1989-08-31 Monsanto Co Preparation of ethylidene diacetates
US4810821A (en) * 1981-10-09 1989-03-07 Monsanto Company Preparation of alkylidene diesters
FR2514755A1 (fr) * 1981-10-21 1983-04-22 Rhone Poulenc Chim Base Procede de preparation de l'anhydride acetique
NL8204901A (nl) * 1981-12-30 1983-07-18 Halcon Sd Group Inc Zuivering van carbonyleringsprodukten.
US4664851A (en) * 1981-12-30 1987-05-12 Shell Oil Company Process for the co-production of carboxylic acids and carboxylic acid esters
JPS58144340A (ja) * 1982-02-18 1983-08-27 Kuraray Co Ltd アセトアルデヒドの製造方法
JPS58157746A (ja) * 1982-03-16 1983-09-19 Mitsubishi Gas Chem Co Inc 酢酸ビニルの製造方法
EP0097978B1 (fr) * 1982-06-18 1985-12-18 Shell Internationale Researchmaatschappij B.V. Procédé de coproduction d'acides carboxyliques
DE3363531D1 (en) * 1982-11-01 1986-06-19 Shell Int Research Process for the preparation of ethylidene diacetate and/or acetic acid anhydride
US5026903A (en) * 1984-03-29 1991-06-25 Union Carbide Chemicals And Plastics Technology Corporation Production of ethylidene diacetate from dimethyl acetal
US5155261A (en) * 1987-02-05 1992-10-13 Reilly Industries, Inc. Process for acetic acid preparation and heterogenous catalyst for same
KR930003648B1 (ko) * 1990-10-05 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 무기체 담지 촉매, 그 제조방법 및 이에 의한 에틸리덴 디 아세테이트의 제조방법
KR930003649B1 (ko) * 1990-10-05 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 고체촉매, 그의 제조방법 및 이를 이용한 연속식, 공정에 의한 에틸리덴 디 아세테이트의 제조방법
KR930003650B1 (ko) * 1990-10-08 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 유기체 담지 촉매 및 이를 이용한 에틸리덴 디 아세테이트의 제조방법
US5502243A (en) * 1992-04-15 1996-03-26 Air Products And Chemicals, Inc. Hydrocarbonylation of dimethyl ether
CA2093747C (fr) * 1992-04-15 1999-06-15 Francis J. Waller Methode pour convertir de l'oxyde de dimethyle en diacetate d'ethylidene
CA2093752C (fr) * 1992-04-15 1999-06-15 David W. Studer Procede integre pour la preparation de composes acetyles oxygenes a partir de gaz de synthese via l'oxyde de dimethyle
US5227517A (en) * 1992-04-15 1993-07-13 Air Products And Chemicals, Inc. Process for preparing ethylidene diacetate using iodide catalysts
US5744636A (en) * 1996-05-21 1998-04-28 Air Products And Chemicals, Inc. Process for the production of ethylidene diacetate from dimethyl ether using a heterogeneous catalyst
US5767307A (en) * 1996-05-21 1998-06-16 Air Products And Chemicals, Inc. Heterogeneous catalyst for the production of ethylidene diacetate from acetic anhydride

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE364255B (fr) * 1967-04-05 1974-02-18 Monsanto Co

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9938217B2 (en) 2016-07-01 2018-04-10 Res Usa, Llc Fluidized bed membrane reactor
US9981896B2 (en) 2016-07-01 2018-05-29 Res Usa, Llc Conversion of methane to dimethyl ether
US10189763B2 (en) 2016-07-01 2019-01-29 Res Usa, Llc Reduction of greenhouse gas emission

Also Published As

Publication number Publication date
NL7602096A (nl) 1976-09-14
JPS5946936B2 (ja) 1984-11-15
DE2610035C2 (de) 1984-06-28
FR2303788B1 (fr) 1979-08-31
NL176452C (nl) 1985-04-16
JPS51115409A (en) 1976-10-12
RO69285A (fr) 1982-04-12
DE2610035A1 (de) 1976-09-23
FR2303788A1 (fr) 1976-10-08
SE7601739L (sv) 1976-09-13
NO148712C (no) 1983-11-30
SE426583B (sv) 1983-01-31
GB1538782A (en) 1979-01-24
ES445919A1 (es) 1977-10-01
AU1166076A (en) 1977-09-08
NO760816L (fr) 1976-09-13
NO148712B (no) 1983-08-22
DD124247A5 (fr) 1977-02-09
IT1057944B (it) 1982-03-30
BR7601412A (pt) 1976-09-14

Similar Documents

Publication Publication Date Title
CA1065885A (fr) Preparation de diacetate d'ethylidene
US5138093A (en) Process for preparing ethylidene diacetate
US4115444A (en) Process for preparing carboxylic acid anhydrides
CA1058636A (fr) Procede pour la preparation d'anhydrides d'acides carboxyliques
US4252741A (en) Carbonylation with Group VIII noble metal catalysts
US4002678A (en) Preparation of carboxylic acid anhydrides
US4659518A (en) Preparation of carboxylic acids
CA1154036A (fr) Procede pour l'homologation selective du methanol en ethanol
US4356320A (en) Preparation of carboxylic acids
US4335059A (en) Preparation of carboxylic acid anhydrides
CA1187096A (fr) Methode de co-production d'acides carboxyliques et d'esters d'acides carboxyliques
US4251458A (en) Process for preparing carboxylic acid anhydrides
US4284585A (en) Process for the preparation of acetic anhydride
US4339545A (en) Alkanols from synthesis gas
US4629809A (en) Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system
US4323697A (en) Process for preparing ethylidene diacetate
US4354036A (en) Preparation of carboxylic acid esters
EP0037586A1 (fr) Procédé d'hydroformulation sélective de méthanol en acétaldéhyde
US4284586A (en) Process for the preparation of acetic anhydride
US4519956A (en) Process for selectively preparing acetic anhydride by carbonylation of methyl acetate in the presence of an iodide-free catalyst system
CA1218998A (fr) Preparation d'acetate d'ethylidene et d'anhydride d'acide acetique
CA1181734A (fr) Preparation d'acide carboxilique
US4302611A (en) Preparation of acetaldehyde
US4407726A (en) Preparation of carboxylic acids
US4661631A (en) Process for the preparation of acetic acid