CA1065347A - Methanol - Google Patents
MethanolInfo
- Publication number
- CA1065347A CA1065347A CA230,565A CA230565A CA1065347A CA 1065347 A CA1065347 A CA 1065347A CA 230565 A CA230565 A CA 230565A CA 1065347 A CA1065347 A CA 1065347A
- Authority
- CA
- Canada
- Prior art keywords
- synthesis
- gas
- heat
- water
- methanol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 144
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 94
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 93
- 238000000034 method Methods 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 239000003054 catalyst Substances 0.000 claims abstract description 30
- 238000009835 boiling Methods 0.000 claims abstract description 8
- 239000002826 coolant Substances 0.000 claims description 7
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 238000000926 separation method Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000010926 purge Methods 0.000 abstract description 18
- 239000007789 gas Substances 0.000 description 101
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 18
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 16
- 238000011084 recovery Methods 0.000 description 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- 229910002090 carbon oxide Inorganic materials 0.000 description 8
- 239000003345 natural gas Substances 0.000 description 8
- 238000010791 quenching Methods 0.000 description 8
- 238000010438 heat treatment Methods 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000003546 flue gas Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000002918 waste heat Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000629 steam reforming Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1512—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by reaction conditions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
- C07C29/154—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing copper, silver, gold, or compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S203/00—Distillation: processes, separatory
- Y10S203/24—Mobile, marine distiller
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA315,567A CA1110664A (en) | 1974-07-02 | 1978-10-31 | Methanol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB29260/74A GB1484366A (en) | 1974-07-02 | 1974-07-02 | Methanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1065347A true CA1065347A (en) | 1979-10-30 |
Family
ID=10288695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA230,565A Expired CA1065347A (en) | 1974-07-02 | 1975-07-02 | Methanol |
Country Status (8)
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4072625A (en) * | 1975-03-03 | 1978-02-07 | Imperial Chemical Industries Limited | Steam-hydrocarbon process |
| GB1595413A (en) * | 1976-12-15 | 1981-08-12 | Ici Ltd | Engergy recovery from chemical process off-gas |
| US4235800A (en) * | 1978-05-31 | 1980-11-25 | Imperial Chemical Industries Limited | Synthesis gas |
| JPS5555890A (en) * | 1978-10-18 | 1980-04-24 | Shiseido Co Ltd | Laser-beam printing method and method therefor |
| JPS55117687A (en) * | 1979-03-05 | 1980-09-10 | Nippon Telegr & Teleph Corp <Ntt> | Direct recording method by laser |
| US4226795A (en) * | 1979-05-04 | 1980-10-07 | E. I. Du Pont De Nemours And Company | Purge gas in methanol synthesis |
| NZ194405A (en) * | 1979-08-02 | 1982-05-25 | Dut Pty Ltd | Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock |
| DE2934332C2 (de) * | 1979-08-24 | 1982-06-03 | Uhde Gmbh, 4600 Dortmund | Verfahren zur katalytischen Synthese von Methanol |
| DE3028646A1 (de) * | 1980-07-29 | 1982-03-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur verbesserung der gleichgewichtseinstellung und gleichzeitigen erzeugung von wasserdampf mit hohem druck bei der herstellung von methanol |
| DE3122273A1 (de) * | 1981-06-04 | 1982-12-23 | Uhde Gmbh, 4600 Dortmund | "verfahren zur katalytischen spaltung von erdgas" |
| GB8309359D0 (en) * | 1983-04-06 | 1983-05-11 | Ici Plc | Synthesis gas |
| JPS60106527A (ja) * | 1983-11-14 | 1985-06-12 | Mitsubishi Heavy Ind Ltd | 二重管式発熱反応器 |
| JPS6130542A (ja) * | 1984-07-20 | 1986-02-12 | Mitsubishi Heavy Ind Ltd | メタノ−ル合成反応の熱回収方法 |
| JPS6176080U (US20110009641A1-20110113-C00185.png) * | 1984-10-25 | 1986-05-22 | ||
| JPH01151599U (US20110009641A1-20110113-C00185.png) * | 1988-03-31 | 1989-10-19 | ||
| DE4004862A1 (de) * | 1990-02-16 | 1991-08-22 | Uhde Gmbh | Methanolsynthese mit frischgaszufuhr |
| US5902524A (en) * | 1994-02-02 | 1999-05-11 | Wootten; William A. | Method and apparatus for heat treatment of an extrusion to extract chemicals and gases for injection into a second cold extrusion of inert media to combine and liquefy these in production of a product |
| US5964985A (en) * | 1994-02-02 | 1999-10-12 | Wootten; William A. | Method and apparatus for converting coal to liquid hydrocarbons |
| JP4043235B2 (ja) | 1999-09-07 | 2008-02-06 | ウーデ・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 水素、一酸化炭素および二酸化炭素から加圧下にメタノールを合成する方法および装置 |
| DE19948585A1 (de) * | 1999-09-07 | 2001-03-08 | Krupp Uhde Gmbh | Verfahren und Anlage zur Methanolherstellung |
| CN1181023C (zh) | 1999-09-07 | 2004-12-22 | 犹德有限公司 | 甲醇合成工艺和设备 |
| EP2228357A1 (en) * | 2009-03-12 | 2010-09-15 | Methanol Casale S.A. | A process for synthesis of methanol |
| WO2010149361A2 (de) * | 2009-06-24 | 2010-12-29 | Uhde Gmbh | Primärreformer mit variablem rauchgasstrom |
| CN103373898B (zh) * | 2012-04-20 | 2016-02-24 | 新奥科技发展有限公司 | 甲醇合成工艺、甲醇合成系统 |
| EP3205387A1 (en) | 2016-02-15 | 2017-08-16 | Johannes August Lercher | Preparation and use of zeolitic membranes for selective removal of water |
| RU2619101C1 (ru) * | 2016-05-26 | 2017-05-12 | Андрей Владиславович Курочкин | Установка получения метанола из углеводородного сырья |
| RU2616977C1 (ru) * | 2016-05-26 | 2017-04-19 | Андрей Владиславович Курочкин | Установка синтеза метанола |
| CN107141195B (zh) * | 2017-05-24 | 2023-09-22 | 河南心连心化学工业集团股份有限公司 | 一种中低压联醇和单醇生产甲醇的装置 |
| US10961121B2 (en) * | 2018-11-09 | 2021-03-30 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method for improving thermal efficiency of steam production |
| US10933394B2 (en) * | 2018-11-09 | 2021-03-02 | L'air Liquide Societe Anonyme Pour L'etude Et L 'exploitation Des Procedes Georges Claude | Apparatus for improving thermal efficiency of steam production |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2632528A (en) * | 1947-09-27 | 1953-03-24 | Union Oil Co | Iron-group impregnated adsorbent in adsorption process |
| US2662911A (en) * | 1948-10-01 | 1953-12-15 | Metallgesellschaft Ag | Temperature control in the catalytic hydrogenation of carbon monoxide |
| US3254967A (en) * | 1963-06-17 | 1966-06-07 | Chem Processes Inc | Multiple bed catalyst apparatus having close temperature control |
| GB1143946A (en) * | 1965-05-28 | 1969-02-26 | Humphreys & Glasgow Ltd | Process and apparatus for the manufacture of nitric acid |
| US3441393A (en) * | 1966-01-19 | 1969-04-29 | Pullman Inc | Process for the production of hydrogen-rich gas |
| US3615200A (en) * | 1967-06-14 | 1971-10-26 | Toyo Engineering Corp | Process for concentrating inert components in pressurized synthesis loop |
| US3531266A (en) * | 1968-01-31 | 1970-09-29 | Chemical Construction Corp | Production of synthetic methanol |
| US3598527A (en) * | 1968-10-11 | 1971-08-10 | Pullman Inc | Ammonia and methanol production |
| US3501516A (en) * | 1968-11-29 | 1970-03-17 | Pritchard & Co J F | Method for production of methanol |
| GB1307845A (en) * | 1969-05-28 | 1973-02-21 | Ici Ltd | Reactor |
| GB1272798A (en) * | 1969-10-27 | 1972-05-03 | Haldor Frederik Axel Topsoe | Low temperature methanol synthesis |
| DE2013297B2 (de) * | 1970-03-20 | 1973-10-25 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Ausnutzung der Reaktionswarme bei der Herstellung von Methanol |
| DE2024301C3 (de) * | 1970-05-19 | 1974-07-04 | Metallgesellschaft Ag, 6000 Frankfurt | Verfahren zur Herstellung von Methanol |
| US3920717A (en) * | 1973-03-26 | 1975-11-18 | Texaco Development Corp | Production of methanol |
-
1974
- 1974-07-02 GB GB29260/74A patent/GB1484366A/en not_active Expired
-
1975
- 1975-06-24 ZA ZA00754038A patent/ZA754038B/xx unknown
- 1975-06-24 US US05/590,012 patent/US4065483A/en not_active Expired - Lifetime
- 1975-07-01 JP JP50081356A patent/JPS593971B2/ja not_active Expired
- 1975-07-01 IT IT25013/75A patent/IT1039619B/it active
- 1975-07-01 FR FR7520632A patent/FR2280617A1/fr active Granted
- 1975-07-02 CA CA230,565A patent/CA1065347A/en not_active Expired
- 1975-07-02 DE DE19752529591 patent/DE2529591A1/de not_active Ceased
-
1976
- 1976-03-09 FR FR7606697A patent/FR2292688A1/fr active Granted
-
1982
- 1982-07-01 JP JP57114767A patent/JPS5883642A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2292688A1 (fr) | 1976-06-25 |
| FR2292688B1 (US20110009641A1-20110113-C00185.png) | 1983-02-11 |
| JPS5129408A (US20110009641A1-20110113-C00185.png) | 1976-03-12 |
| US4065483A (en) | 1977-12-27 |
| AU8250275A (en) | 1977-01-06 |
| GB1484366A (en) | 1977-09-01 |
| IT1039619B (it) | 1979-12-10 |
| DE2529591A1 (de) | 1976-01-22 |
| ZA754038B (en) | 1976-05-26 |
| JPS593971B2 (ja) | 1984-01-27 |
| FR2280617A1 (fr) | 1976-02-27 |
| FR2280617B1 (US20110009641A1-20110113-C00185.png) | 1981-05-29 |
| JPS612652B2 (US20110009641A1-20110113-C00185.png) | 1986-01-27 |
| JPS5883642A (ja) | 1983-05-19 |
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