CA1061942A - Manufacture of copolymers of ethylene - Google Patents
Manufacture of copolymers of ethyleneInfo
- Publication number
- CA1061942A CA1061942A CA252,152A CA252152A CA1061942A CA 1061942 A CA1061942 A CA 1061942A CA 252152 A CA252152 A CA 252152A CA 1061942 A CA1061942 A CA 1061942A
- Authority
- CA
- Canada
- Prior art keywords
- ethylene
- tert
- zone
- per cent
- butyl acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005977 Ethylene Substances 0.000 title claims abstract description 27
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 229920001577 copolymer Polymers 0.000 title claims abstract description 15
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 239000011541 reaction mixture Substances 0.000 claims abstract description 18
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 9
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 claims description 16
- 238000002955 isolation Methods 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 239000004831 Hot glue Substances 0.000 abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract description 2
- 229920001897 terpolymer Polymers 0.000 abstract 1
- 229940093470 ethylene Drugs 0.000 description 22
- 229920001038 ethylene copolymer Polymers 0.000 description 16
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000010408 film Substances 0.000 description 14
- 229920000642 polymer Polymers 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- 239000000203 mixture Substances 0.000 description 10
- 125000004432 carbon atom Chemical group C* 0.000 description 9
- 239000000178 monomer Substances 0.000 description 7
- 238000000197 pyrolysis Methods 0.000 description 7
- 239000000155 melt Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 150000002978 peroxides Chemical class 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 101100117236 Drosophila melanogaster speck gene Proteins 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 208000036366 Sensation of pressure Diseases 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000012943 hotmelt Substances 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 239000012442 inert solvent Substances 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000007870 radical polymerization initiator Substances 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- 101100087530 Caenorhabditis elegans rom-1 gene Proteins 0.000 description 1
- 241000448280 Elates Species 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 101100305983 Mus musculus Rom1 gene Proteins 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate group Chemical group C(C=C)(=O)[O-] NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000002313 adhesive film Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 229940063557 methacrylate Drugs 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 150000008028 secondary esters Chemical class 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 150000008027 tertiary esters Chemical group 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2524274A DE2524274C3 (de) | 1975-05-31 | 1975-05-31 | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1061942A true CA1061942A (en) | 1979-09-04 |
Family
ID=5947971
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA252,152A Expired CA1061942A (en) | 1975-05-31 | 1976-05-10 | Manufacture of copolymers of ethylene |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6011725B2 (Direct) |
| AT (1) | AT343353B (Direct) |
| BE (1) | BE842394A (Direct) |
| CA (1) | CA1061942A (Direct) |
| DE (1) | DE2524274C3 (Direct) |
| FR (1) | FR2313406A1 (Direct) |
| GB (1) | GB1538894A (Direct) |
| NL (1) | NL7605786A (Direct) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4599392A (en) * | 1983-06-13 | 1986-07-08 | The Dow Chemical Company | Interpolymers of ethylene and unsaturated carboxylic acids |
| SE453622B (sv) * | 1983-12-08 | 1988-02-15 | Asea Ab | Halvledarkomponent for generering av optisk stralning |
| DE3404743A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
| JPS61127709A (ja) * | 1984-11-27 | 1986-06-16 | Sumitomo Chem Co Ltd | エチレン共重合体の製造方法 |
| US5945083A (en) * | 1995-03-10 | 1999-08-31 | Kawasaki Jukogyo Kabushiki Kaisha | Process for producing iron carbide and equipment therefor |
| DE10008931A1 (de) * | 2000-02-25 | 2001-08-30 | Basf Ag | Verfahren zur Herstellung von emulgierbaren Ethylenpolymerisaten |
| JP2008050148A (ja) * | 2006-08-28 | 2008-03-06 | Kansai Kanaami Kk | 搬送ベルトおよび搬送装置 |
| WO2008120912A1 (en) * | 2007-03-30 | 2008-10-09 | Lg Chem, Ltd. | Copolymer comprising alkene, acrylate and unsaturated organic acid, and method for preparing the same |
| EP3181599A1 (en) * | 2015-12-18 | 2017-06-21 | Borealis AG | Novel process for producing a polar ethylene copolymer with low melt flow rate |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE591916A (Direct) * | 1959-06-23 | |||
| US3132120A (en) * | 1961-02-03 | 1964-05-05 | Du Pont | Method for the preparation of ethylene copolymers |
| DE1720335C3 (de) * | 1967-12-21 | 1985-01-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
| DE1770777A1 (de) * | 1968-07-03 | 1971-12-02 | Basf Ag | Verfahren zum Herstellen von wachsartigen Mischpolymerisaten des AEthylens |
| DE2119047C3 (de) * | 1971-04-20 | 1978-09-14 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von Mischpolymerisaten des Äthylens |
-
1975
- 1975-05-31 DE DE2524274A patent/DE2524274C3/de not_active Expired
-
1976
- 1976-05-10 CA CA252,152A patent/CA1061942A/en not_active Expired
- 1976-05-21 JP JP51058003A patent/JPS6011725B2/ja not_active Expired
- 1976-05-27 GB GB22031/76A patent/GB1538894A/en not_active Expired
- 1976-05-28 AT AT393676A patent/AT343353B/de not_active IP Right Cessation
- 1976-05-28 NL NL7605786A patent/NL7605786A/xx not_active Application Discontinuation
- 1976-05-28 FR FR7616211A patent/FR2313406A1/fr active Granted
- 1976-05-31 BE BE167479A patent/BE842394A/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATA393676A (de) | 1977-09-15 |
| AT343353B (de) | 1978-05-26 |
| DE2524274C3 (de) | 1987-09-10 |
| BE842394A (fr) | 1976-12-01 |
| GB1538894A (en) | 1979-01-24 |
| FR2313406B1 (Direct) | 1980-12-19 |
| JPS52886A (en) | 1977-01-06 |
| JPS6011725B2 (ja) | 1985-03-27 |
| DE2524274A1 (de) | 1976-12-09 |
| DE2524274B2 (de) | 1980-03-13 |
| NL7605786A (nl) | 1976-12-02 |
| FR2313406A1 (fr) | 1976-12-31 |
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