CA1059812A - Heat-developable light-sensitive materials - Google Patents

Info

Publication number

CA1059812A

CA1059812A CA231,543A CA231543A CA1059812A CA 1059812 A CA1059812 A CA 1059812A CA 231543 A CA231543 A CA 231543A CA 1059812 A CA1059812 A CA 1059812A

Authority

CA

Canada

Prior art keywords

group

silver

light

acid

heat

Prior art date

1974-07-15

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

• Espacenet
• Global Dossier
• CIPO
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• 239000000463 material Substances 0.000 title claims abstract description 91
• -1 silver halide Chemical class 0.000 claims abstract description 136
• 229910052709 silver Inorganic materials 0.000 claims abstract description 129
• 239000004332 silver Substances 0.000 claims abstract description 129
• GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims abstract description 72
• 239000003638 chemical reducing agent Substances 0.000 claims abstract description 36
• 125000000217 alkyl group Chemical group 0.000 claims abstract description 24
• 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
• 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 16
• 125000003118 aryl group Chemical group 0.000 claims abstract description 14
• 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims abstract description 10
• 125000003277 amino group Chemical group 0.000 claims abstract description 8
• 125000005843 halogen group Chemical group 0.000 claims abstract description 7
• 125000001624 naphthyl group Chemical group 0.000 claims abstract description 7
• 125000004171 alkoxy aryl group Chemical group 0.000 claims abstract description 6
• 125000004414 alkyl thio group Chemical group 0.000 claims abstract description 6
• 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract description 5
• 229910052801 chlorine Inorganic materials 0.000 claims abstract description 5
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 4
• 125000002768 hydroxyalkyl group Chemical group 0.000 claims abstract description 4
• 125000003282 alkyl amino group Chemical group 0.000 claims abstract description 3
• 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 3
• 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims abstract description 3
• 239000007795 chemical reaction product Substances 0.000 claims abstract description 3
• 125000001309 chloro group Chemical group Cl* 0.000 claims abstract description 3
• 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims abstract description 3
• 125000001188 haloalkyl group Chemical group 0.000 claims abstract description 3
• 125000003106 haloaryl group Chemical group 0.000 claims abstract description 3
• 125000004573 morpholin-4-yl group Chemical group N1(CCOCC1)* 0.000 claims abstract 2
• 150000001875 compounds Chemical class 0.000 claims description 45
• 239000002253 acid Substances 0.000 claims description 23
• CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 18
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
• QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 13
• 235000010323 ascorbic acid Nutrition 0.000 claims description 10
• 229960005070 ascorbic acid Drugs 0.000 claims description 10
• 239000011668 ascorbic acid Substances 0.000 claims description 10
• 150000002894 organic compounds Chemical class 0.000 claims description 9
• 150000002989 phenols Chemical class 0.000 claims description 9
• 150000002148 esters Chemical class 0.000 claims description 7
• ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 6
• 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
• 230000001603 reducing effect Effects 0.000 claims description 6
• 125000001424 substituent group Chemical group 0.000 claims description 6
• 229930185605 Bisphenol Natural products 0.000 claims description 4
• 241001061127 Thione Species 0.000 claims description 4
• FUWUEFKEXZQKKA-UHFFFAOYSA-N beta-thujaplicin Chemical compound CC(C)C=1C=CC=C(O)C(=O)C=1 FUWUEFKEXZQKKA-UHFFFAOYSA-N 0.000 claims description 4
• 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
• 125000001841 imino group Chemical group [H]N=* 0.000 claims description 4
• XBYRMPXUBGMOJC-UHFFFAOYSA-N 1,2-dihydropyrazol-3-one Chemical compound OC=1C=CNN=1 XBYRMPXUBGMOJC-UHFFFAOYSA-N 0.000 claims description 3
• 150000001720 carbohydrates Chemical class 0.000 claims description 3
• NDGRWYRVNANFNB-UHFFFAOYSA-N pyrazolidin-3-one Chemical compound O=C1CCNN1 NDGRWYRVNANFNB-UHFFFAOYSA-N 0.000 claims description 3
• 125000003396 thiol group Chemical group [H]S* 0.000 claims description 3
• UHKAJLSKXBADFT-UHFFFAOYSA-N 1,3-indandione Chemical compound C1=CC=C2C(=O)CC(=O)C2=C1 UHKAJLSKXBADFT-UHFFFAOYSA-N 0.000 claims description 2
• AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 2
• TUFYVOCKVJOUIR-UHFFFAOYSA-N alpha-Thujaplicin Natural products CC(C)C=1C=CC=CC(=O)C=1O TUFYVOCKVJOUIR-UHFFFAOYSA-N 0.000 claims description 2
• BEJNERDRQOWKJM-UHFFFAOYSA-N kojic acid Chemical compound OCC1=CC(=O)C(O)=CO1 BEJNERDRQOWKJM-UHFFFAOYSA-N 0.000 claims description 2
• 229960004705 kojic acid Drugs 0.000 claims description 2
• WZNJWVWKTVETCG-UHFFFAOYSA-N kojic acid Natural products OC(=O)C(N)CN1C=CC(=O)C(O)=C1 WZNJWVWKTVETCG-UHFFFAOYSA-N 0.000 claims description 2
• 150000005846 sugar alcohols Polymers 0.000 claims description 2
• 229930007845 β-thujaplicin Natural products 0.000 claims description 2
• CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 claims 1
• CSXHUONYHRDYGM-UHFFFAOYSA-N 2-(hydroxyamino)-2-oxoacetic acid Chemical compound ONC(=O)C(O)=O CSXHUONYHRDYGM-UHFFFAOYSA-N 0.000 claims 1
• NVXLIZQNSVLKPO-UHFFFAOYSA-N Glucosereductone Chemical compound O=CC(O)C=O NVXLIZQNSVLKPO-UHFFFAOYSA-N 0.000 claims 1
• 238000011161 development Methods 0.000 abstract description 14
• 239000003054 catalyst Substances 0.000 abstract description 3
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 62
• 239000000243 solution Substances 0.000 description 57
• 238000000034 method Methods 0.000 description 45
• 150000003839 salts Chemical class 0.000 description 45
• 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 33
• 229940124024 weight reducing agent Drugs 0.000 description 33
• 239000003795 chemical substances by application Substances 0.000 description 32
• 239000000975 dye Substances 0.000 description 31
• 150000003378 silver Chemical class 0.000 description 27
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 26
• 230000008569 process Effects 0.000 description 22
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 19
• YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 18
• 229910052751 metal Inorganic materials 0.000 description 18
• 239000002184 metal Substances 0.000 description 18
• 239000006185 dispersion Substances 0.000 description 17
• 239000007864 aqueous solution Substances 0.000 description 16
• 229920000642 polymer Polymers 0.000 description 16
• UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
• 230000008859 change Effects 0.000 description 15
• 230000000052 comparative effect Effects 0.000 description 15
• 238000010438 heat treatment Methods 0.000 description 15
• 230000018109 developmental process Effects 0.000 description 13
• 229910001961 silver nitrate Inorganic materials 0.000 description 13
• CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 12
• 238000000576 coating method Methods 0.000 description 11
• 239000000839 emulsion Substances 0.000 description 11
• 238000012545 processing Methods 0.000 description 11
• 239000011248 coating agent Substances 0.000 description 10
• 150000004820 halides Chemical class 0.000 description 10
• 239000000203 mixture Substances 0.000 description 10
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
• 235000019441 ethanol Nutrition 0.000 description 9
• 238000002156 mixing Methods 0.000 description 9
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
• 239000003921 oil Substances 0.000 description 8
• 230000035945 sensitivity Effects 0.000 description 8
• 239000000654 additive Substances 0.000 description 7
• 125000001931 aliphatic group Chemical group 0.000 description 7
• 239000011230 binding agent Substances 0.000 description 7
• 238000006243 chemical reaction Methods 0.000 description 7
• 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 7
• 238000002360 preparation method Methods 0.000 description 7
• 239000003381 stabilizer Substances 0.000 description 7
• QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 6
• ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 6
• 239000001856 Ethyl cellulose Substances 0.000 description 6
• KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
• HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
• GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
• XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
• 150000007513 acids Chemical class 0.000 description 6
• 125000004429 atom Chemical group 0.000 description 6
• 229920002678 cellulose Polymers 0.000 description 6
• POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
• 229920001249 ethyl cellulose Polymers 0.000 description 6
• 235000019325 ethyl cellulose Nutrition 0.000 description 6
• 125000001475 halogen functional group Chemical group 0.000 description 6
• 229960004337 hydroquinone Drugs 0.000 description 6
• MLFHJEHSLIIPHL-UHFFFAOYSA-N isoamyl acetate Chemical compound CC(C)CCOC(C)=O MLFHJEHSLIIPHL-UHFFFAOYSA-N 0.000 description 6
• 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
• DZVCFNFOPIZQKX-LTHRDKTGSA-M merocyanine Chemical compound [Na+].O=C1N(CCCC)C(=O)N(CCCC)C(=O)C1=C\C=C\C=C/1N(CCCS([O-])(=O)=O)C2=CC=CC=C2O\1 DZVCFNFOPIZQKX-LTHRDKTGSA-M 0.000 description 6
• VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
• VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
• IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical compound C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 description 6
• BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
• 230000001235 sensitizing effect Effects 0.000 description 6
• 229920002554 vinyl polymer Polymers 0.000 description 6
• IBWXIFXUDGADCV-UHFFFAOYSA-N 2h-benzotriazole;silver Chemical compound [Ag].C1=CC=C2NN=NC2=C1 IBWXIFXUDGADCV-UHFFFAOYSA-N 0.000 description 5
• 229940081735 acetylcellulose Drugs 0.000 description 5
• 239000012964 benzotriazole Substances 0.000 description 5
• 239000001913 cellulose Substances 0.000 description 5
• 239000004815 dispersion polymer Substances 0.000 description 5
• QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
• 229910052753 mercury Inorganic materials 0.000 description 5
• 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
• 239000002245 particle Substances 0.000 description 5
• 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 5
• 239000011118 polyvinyl acetate Substances 0.000 description 5
• 229920002689 polyvinyl acetate Polymers 0.000 description 5
• 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
• MNMYRUHURLPFQW-UHFFFAOYSA-M silver;dodecanoate Chemical compound [Ag+].CCCCCCCCCCCC([O-])=O MNMYRUHURLPFQW-UHFFFAOYSA-M 0.000 description 5
• IWDUDCDZGOLTTJ-UHFFFAOYSA-N 1h-imidazole;silver Chemical compound [Ag].C1=CNC=N1 IWDUDCDZGOLTTJ-UHFFFAOYSA-N 0.000 description 4
• IZXIZTKNFFYFOF-UHFFFAOYSA-N 2-Oxazolidone Chemical compound O=C1NCCO1 IZXIZTKNFFYFOF-UHFFFAOYSA-N 0.000 description 4
• 108010010803 Gelatin Proteins 0.000 description 4
• CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 4
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
• UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
• OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
• XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
• 125000003545 alkoxy group Chemical group 0.000 description 4
• QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 4
• 150000001565 benzotriazoles Chemical class 0.000 description 4
• 229920002301 cellulose acetate Polymers 0.000 description 4
• 239000004927 clay Substances 0.000 description 4
• 229940125904 compound 1 Drugs 0.000 description 4
• 229920001577 copolymer Polymers 0.000 description 4
• GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
• UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
• 229920000159 gelatin Polymers 0.000 description 4
• 239000008273 gelatin Substances 0.000 description 4
• 235000019322 gelatine Nutrition 0.000 description 4
• 235000011852 gelatine desserts Nutrition 0.000 description 4
• 229910052737 gold Inorganic materials 0.000 description 4
• 239000010931 gold Substances 0.000 description 4
• 238000005286 illumination Methods 0.000 description 4
• 230000006872 improvement Effects 0.000 description 4
• 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
• XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
• 239000004926 polymethyl methacrylate Substances 0.000 description 4
• KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical class O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 4
• 239000000377 silicon dioxide Substances 0.000 description 4
• OIZSSBDNMBMYFL-UHFFFAOYSA-M silver;decanoate Chemical compound [Ag+].CCCCCCCCCC([O-])=O OIZSSBDNMBMYFL-UHFFFAOYSA-M 0.000 description 4
• 239000002904 solvent Substances 0.000 description 4
• 230000003595 spectral effect Effects 0.000 description 4
• 238000003756 stirring Methods 0.000 description 4
• 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
• 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 description 3
• KAESVJOAVNADME-UHFFFAOYSA-N 1H-pyrrole Natural products C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 3
• KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 3
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
• CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 3
• NEAQRZUHTPSBBM-UHFFFAOYSA-N 2-hydroxy-3,3-dimethyl-7-nitro-4h-isoquinolin-1-one Chemical class C1=C([N+]([O-])=O)C=C2C(=O)N(O)C(C)(C)CC2=C1 NEAQRZUHTPSBBM-UHFFFAOYSA-N 0.000 description 3
• WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
• 239000005995 Aluminium silicate Substances 0.000 description 3
• DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 3
• 229920000623 Cellulose acetate phthalate Polymers 0.000 description 3
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
• 239000005639 Lauric acid Substances 0.000 description 3
• ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
• 239000004793 Polystyrene Substances 0.000 description 3
• 206010070834 Sensitisation Diseases 0.000 description 3
• 235000012211 aluminium silicate Nutrition 0.000 description 3
• QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 3
• 229910001864 baryta Inorganic materials 0.000 description 3
• 229910052794 bromium Inorganic materials 0.000 description 3
• 229910052793 cadmium Inorganic materials 0.000 description 3
• 229920006217 cellulose acetate butyrate Polymers 0.000 description 3
• 229940081734 cellulose acetate phthalate Drugs 0.000 description 3
• 229940125782 compound 2 Drugs 0.000 description 3
• 239000010419 fine particle Substances 0.000 description 3
• 150000004676 glycans Chemical class 0.000 description 3
• PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
• 229910052736 halogen Inorganic materials 0.000 description 3
• 150000002367 halogens Chemical class 0.000 description 3
• FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
• 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 3
• 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
• RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
• 229940117955 isoamyl acetate Drugs 0.000 description 3
• NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
• 238000004519 manufacturing process Methods 0.000 description 3
• 229940100892 mercury compound Drugs 0.000 description 3
• 150000002731 mercury compounds Chemical class 0.000 description 3
• 229910052763 palladium Inorganic materials 0.000 description 3
• FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 3
• 229910052697 platinum Inorganic materials 0.000 description 3
• 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
• 229920000139 polyethylene terephthalate Polymers 0.000 description 3
• 239000005020 polyethylene terephthalate Substances 0.000 description 3
• 229920001282 polysaccharide Polymers 0.000 description 3
• 239000005017 polysaccharide Substances 0.000 description 3
• 229920000915 polyvinyl chloride Polymers 0.000 description 3
• 239000004800 polyvinyl chloride Substances 0.000 description 3
• 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
• 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
• 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
• 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
• 230000005855 radiation Effects 0.000 description 3
• 229910052703 rhodium Inorganic materials 0.000 description 3
• 239000010948 rhodium Substances 0.000 description 3
• MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 3
• 230000008313 sensitization Effects 0.000 description 3
• AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 3
• ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 3
• 230000000087 stabilizing effect Effects 0.000 description 3
• 239000000126 substance Substances 0.000 description 3
• 239000004408 titanium dioxide Substances 0.000 description 3
• WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
• 229910052721 tungsten Inorganic materials 0.000 description 3
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