CA1058640A - Production of polybutene with static mixer and apparatus - Google Patents
Production of polybutene with static mixer and apparatusInfo
- Publication number
- CA1058640A CA1058640A CA232,839A CA232839A CA1058640A CA 1058640 A CA1058640 A CA 1058640A CA 232839 A CA232839 A CA 232839A CA 1058640 A CA1058640 A CA 1058640A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- reactor
- mixture
- inlet
- feed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 230000003068 static effect Effects 0.000 title claims abstract description 21
- 229920001083 polybutene Polymers 0.000 title claims abstract description 10
- 239000003054 catalyst Substances 0.000 claims abstract description 59
- 239000007789 gas Substances 0.000 claims abstract description 14
- 239000011541 reaction mixture Substances 0.000 claims abstract description 11
- 238000005727 Friedel-Crafts reaction Methods 0.000 claims abstract description 6
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 3
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical class CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 239000000725 suspension Substances 0.000 claims description 5
- 238000007865 diluting Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000010924 continuous production Methods 0.000 claims description 2
- 239000012429 reaction media Substances 0.000 claims description 2
- 238000004064 recycling Methods 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 description 14
- 239000000047 product Substances 0.000 description 9
- 239000004215 Carbon black (E152) Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 8
- 239000012530 fluid Substances 0.000 description 8
- 229930195733 hydrocarbon Natural products 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 239000010802 sludge Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 4
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000012295 chemical reaction liquid Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- WFAULHLDTDDABL-UHFFFAOYSA-N Proxazole citrate Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O.C=1C=CC=CC=1C(CC)C1=NOC(CCN(CC)CC)=N1 WFAULHLDTDDABL-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013844 butane Nutrition 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000012809 cooling fluid Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000006194 liquid suspension Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000011027 product recovery Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F240/00—Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/919—Apparatus considerations
- Y10S585/921—Apparatus considerations using recited apparatus structure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/949—Miscellaneous considerations
- Y10S585/955—Specified mixing procedure
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/508,658 US3991129A (en) | 1974-09-23 | 1974-09-23 | Production of polybutene with static mixer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1058640A true CA1058640A (en) | 1979-07-17 |
Family
ID=24023560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA232,839A Expired CA1058640A (en) | 1974-09-23 | 1975-08-05 | Production of polybutene with static mixer and apparatus |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US3991129A (enExample) |
| JP (1) | JPS5944287B2 (enExample) |
| AR (1) | AR205937A1 (enExample) |
| BE (1) | BE833565A (enExample) |
| CA (1) | CA1058640A (enExample) |
| DE (1) | DE2540918A1 (enExample) |
| FR (1) | FR2285402A1 (enExample) |
| GB (1) | GB1497139A (enExample) |
| IT (1) | IT1042230B (enExample) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4225739A (en) * | 1979-03-19 | 1980-09-30 | Mobil Oil Corporation | Process for improving olefin polymer oil properties |
| US4465887A (en) * | 1983-06-27 | 1984-08-14 | Standard Oil Company (Indiana) | Process for producing butylene polymers having molecular weights in the range of from about 400 to 5000 molecular weight |
| US5326921A (en) * | 1988-10-26 | 1994-07-05 | Exxon Chemical Patents Inc. | AlCl3 -catalyzed process for preparing poly-N-butenes from mixed butenes |
| US4952739A (en) * | 1988-10-26 | 1990-08-28 | Exxon Chemical Patents Inc. | Organo-Al-chloride catalyzed poly-n-butenes process |
| US4935576A (en) * | 1988-11-25 | 1990-06-19 | Exxon Chemical Patents Inc. | Polybutene process |
| US5177288A (en) * | 1988-11-25 | 1993-01-05 | Exxon Chemical Patents Inc. | Polybutene process |
| US6562913B1 (en) | 1999-09-16 | 2003-05-13 | Texas Petrochemicals Lp | Process for producing high vinylidene polyisobutylene |
| DE60045897D1 (de) | 1999-09-16 | 2011-06-09 | Tpc Group Llc | Verfahren zur herstellung von polyolefinprodukten |
| US6884858B2 (en) | 1999-10-19 | 2005-04-26 | Texas Petrochemicals Lp | Process for preparing polyolefin products |
| US6858188B2 (en) * | 2003-05-09 | 2005-02-22 | Texas Petrochemicals, Lp | Apparatus for preparing polyolefin products and methodology for using the same |
| US6992152B2 (en) * | 1999-10-19 | 2006-01-31 | Texas Petrochemicals Lp | Apparatus and method for controlling olefin polymerization process |
| US7037999B2 (en) * | 2001-03-28 | 2006-05-02 | Texas Petrochemicals Lp | Mid-range vinylidene content polyisobutylene polymer product and process for producing the same |
| JP5016809B2 (ja) * | 2005-11-09 | 2012-09-05 | 出光興産株式会社 | ビニリデン化合物オリゴマーの製造方法 |
| US7829640B2 (en) * | 2006-08-30 | 2010-11-09 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
| US7906598B2 (en) * | 2006-08-30 | 2011-03-15 | Intertape Polymer Corp. | Recirculation loop reactor bulk polymerization process |
| US20100105847A1 (en) | 2006-01-24 | 2010-04-29 | Intertape Polymer Corp. | Plug flow bulk polymerization of vinyl monomers |
| US20100298507A1 (en) * | 2009-05-19 | 2010-11-25 | Menschig Klaus R | Polyisobutylene Production Process With Improved Efficiencies And/Or For Forming Products Having Improved Characteristics And Polyisobutylene Products Produced Thereby |
| RU2561092C2 (ru) * | 2011-05-26 | 2015-08-20 | Консер Спа | Усовершенствованный полимеризационный реактор, предназначенный для производства бутилкаучука |
| DE102021130372A1 (de) | 2021-11-19 | 2023-05-25 | Deutsches Zentrum für Luft- und Raumfahrt e.V. | Verfahren und Anordnung zur Herstellung eines Treibstoffgemisches |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2508744A (en) * | 1947-12-30 | 1950-05-23 | Standard Oil Dev Co | Propylene polymerization |
| US2521939A (en) * | 1948-05-22 | 1950-09-12 | Socony Vacuum Oil Co Inc | Catalytic polymerization of olefins with hydrogen bromide promoter |
| US2528876A (en) * | 1948-07-03 | 1950-11-07 | Standard Oil Co | Propylene polymerization with hf-bf |
| US2957930A (en) * | 1956-08-27 | 1960-10-25 | Cosden Petroleum Corp | Process for the production of polyisobutylene |
| US3119884A (en) * | 1958-03-27 | 1964-01-28 | Cosden Oil & Chem Co | Reactor and method for polymerizing olefins |
-
1974
- 1974-09-23 US US05/508,658 patent/US3991129A/en not_active Expired - Lifetime
-
1975
- 1975-01-01 AR AR259906A patent/AR205937A1/es active
- 1975-08-05 CA CA232,839A patent/CA1058640A/en not_active Expired
- 1975-09-02 IT IT26811/75A patent/IT1042230B/it active
- 1975-09-13 DE DE19752540918 patent/DE2540918A1/de not_active Withdrawn
- 1975-09-18 BE BE160160A patent/BE833565A/xx not_active IP Right Cessation
- 1975-09-18 JP JP50112203A patent/JPS5944287B2/ja not_active Expired
- 1975-09-19 GB GB38603/75A patent/GB1497139A/en not_active Expired
- 1975-09-23 FR FR7529045A patent/FR2285402A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| AU8492675A (en) | 1977-03-24 |
| AR205937A1 (es) | 1976-06-15 |
| BE833565A (fr) | 1976-01-16 |
| FR2285402A1 (fr) | 1976-04-16 |
| JPS5944287B2 (ja) | 1984-10-29 |
| JPS5157795A (en) | 1976-05-20 |
| FR2285402B1 (enExample) | 1979-07-13 |
| US3991129A (en) | 1976-11-09 |
| DE2540918A1 (de) | 1976-04-08 |
| GB1497139A (en) | 1978-01-05 |
| IT1042230B (it) | 1980-01-30 |
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