CA1057448A - Olefin polymerization process - Google Patents
Olefin polymerization processInfo
- Publication number
- CA1057448A CA1057448A CA222,874A CA222874A CA1057448A CA 1057448 A CA1057448 A CA 1057448A CA 222874 A CA222874 A CA 222874A CA 1057448 A CA1057448 A CA 1057448A
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- organoaluminum compound
- alpha
- reaction zone
- contaminants
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 33
- 150000001336 alkenes Chemical class 0.000 title abstract description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract description 68
- 150000001875 compounds Chemical class 0.000 claims abstract description 28
- 239000000356 contaminant Substances 0.000 claims abstract description 19
- 238000000034 method Methods 0.000 claims abstract description 16
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims description 46
- 229920000642 polymer Polymers 0.000 claims description 31
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 21
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 21
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 239000002002 slurry Substances 0.000 claims description 13
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 12
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 10
- 238000000926 separation method Methods 0.000 claims description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 5
- 238000010924 continuous production Methods 0.000 claims description 3
- 230000004913 activation Effects 0.000 claims description 2
- 238000002288 cocrystallisation Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 11
- 239000003085 diluting agent Substances 0.000 abstract description 7
- 239000004711 α-olefin Substances 0.000 abstract description 3
- 239000012190 activator Substances 0.000 abstract description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 239000010936 titanium Substances 0.000 description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 7
- 239000012535 impurity Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 229910052719 titanium Inorganic materials 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- -1 ethylene, propylene Chemical group 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 230000001627 detrimental effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 239000004264 Petrolatum Substances 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229910010061 TiC13 Inorganic materials 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 150000002899 organoaluminium compounds Chemical class 0.000 description 2
- 229940066842 petrolatum Drugs 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000003039 volatile agent Substances 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US454509A US3912701A (en) | 1974-03-25 | 1974-03-25 | Olefin polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1057448A true CA1057448A (en) | 1979-06-26 |
Family
ID=23804901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA222,874A Expired CA1057448A (en) | 1974-03-25 | 1975-03-24 | Olefin polymerization process |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US3912701A (en, 2012) |
| JP (1) | JPS5910361B2 (en, 2012) |
| BR (1) | BR7501758A (en, 2012) |
| CA (1) | CA1057448A (en, 2012) |
| DE (1) | DE2512941A1 (en, 2012) |
| DK (1) | DK124075A (en, 2012) |
| ES (1) | ES436009A1 (en, 2012) |
| FR (1) | FR2265767B1 (en, 2012) |
| GB (1) | GB1450367A (en, 2012) |
| NO (1) | NO144572C (en, 2012) |
| SE (1) | SE7503381L (en, 2012) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4146693A (en) * | 1977-12-02 | 1979-03-27 | The B. F. Goodrich Company | Process for preparation of cis-1,4 poly(isoprene) |
| US4851488A (en) * | 1987-04-23 | 1989-07-25 | Shell Oil Company | Process for altering hydrogenated polymer compositions from high melt flow to low melt flow |
| US5643846A (en) * | 1993-04-28 | 1997-07-01 | Fina Technology, Inc. | Process for a isotactic/syndiotactic polymer blend in a single reactor |
| US5804524A (en) * | 1993-04-28 | 1998-09-08 | Fina Technology, Inc. | Process for a isotactic/syndiotactic polymer blend in a single reactor |
| US6239235B1 (en) | 1997-07-15 | 2001-05-29 | Phillips Petroleum Company | High solids slurry polymerization |
| WO2001005842A1 (en) * | 1999-07-15 | 2001-01-25 | Phillips Petroleum Company | Slotted slurry take off |
| US10029230B1 (en) | 2017-01-24 | 2018-07-24 | Chevron Phillips Chemical Company Lp | Flow in a slurry loop reactor |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE973626C (de) * | 1953-11-17 | 1960-04-14 | Karl Dr Dr E H Ziegler | Verfahren zur Herstellung von hochmolekularen Polyaethylenen |
| US2993036A (en) * | 1956-04-13 | 1961-07-18 | Dow Chemical Co | Polymerization process |
| US3220998A (en) * | 1961-05-04 | 1965-11-30 | Phillips Petroleum Co | Control of exothermic process carried out in series of reactors |
| DE1805765C3 (de) * | 1968-10-29 | 1980-09-11 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Polymerisation von Propylen |
| US3729455A (en) * | 1971-03-11 | 1973-04-24 | Gulf Research Development Co | Electroconductive method for controlling organometallic catalytic polymerizations |
-
1974
- 1974-03-25 US US454509A patent/US3912701A/en not_active Expired - Lifetime
-
1975
- 1975-03-19 FR FR7508601A patent/FR2265767B1/fr not_active Expired
- 1975-03-21 GB GB1199575A patent/GB1450367A/en not_active Expired
- 1975-03-24 BR BR1759/75A patent/BR7501758A/pt unknown
- 1975-03-24 NO NO751006A patent/NO144572C/no unknown
- 1975-03-24 DE DE19752512941 patent/DE2512941A1/de not_active Withdrawn
- 1975-03-24 CA CA222,874A patent/CA1057448A/en not_active Expired
- 1975-03-24 DK DK124075A patent/DK124075A/da not_active Application Discontinuation
- 1975-03-24 SE SE7503381A patent/SE7503381L/xx unknown
- 1975-03-25 JP JP50036690A patent/JPS5910361B2/ja not_active Expired
- 1975-03-25 ES ES75436009A patent/ES436009A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| SE7503381L (en, 2012) | 1975-09-26 |
| GB1450367A (en) | 1976-09-22 |
| FR2265767A1 (en, 2012) | 1975-10-24 |
| US3912701A (en) | 1975-10-14 |
| DE2512941A1 (de) | 1975-10-09 |
| NO144572B (no) | 1981-06-15 |
| JPS5910361B2 (ja) | 1984-03-08 |
| ES436009A1 (es) | 1977-01-01 |
| BR7501758A (pt) | 1975-12-23 |
| NO751006L (en, 2012) | 1975-09-26 |
| FR2265767B1 (en, 2012) | 1978-06-23 |
| JPS50129688A (en, 2012) | 1975-10-14 |
| NO144572C (no) | 1981-09-23 |
| DK124075A (en, 2012) | 1975-09-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |
Effective date: 19960626 |