CA1055882A - Process for the electrolytic recovery of gallium and/or alkali metals - Google Patents
Process for the electrolytic recovery of gallium and/or alkali metalsInfo
- Publication number
- CA1055882A CA1055882A CA235,643A CA235643A CA1055882A CA 1055882 A CA1055882 A CA 1055882A CA 235643 A CA235643 A CA 235643A CA 1055882 A CA1055882 A CA 1055882A
- Authority
- CA
- Canada
- Prior art keywords
- mercury
- gallium
- cathode
- metal
- process defined
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229910052733 gallium Inorganic materials 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000011084 recovery Methods 0.000 title claims abstract description 6
- 229910052783 alkali metal Inorganic materials 0.000 title claims description 11
- 150000001340 alkali metals Chemical class 0.000 title claims description 11
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 69
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 69
- 229910052751 metal Inorganic materials 0.000 claims abstract description 19
- 239000002184 metal Substances 0.000 claims abstract description 19
- 150000004645 aluminates Chemical class 0.000 claims abstract description 17
- 238000000151 deposition Methods 0.000 claims abstract description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 9
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims abstract description 9
- 230000003381 solubilizing effect Effects 0.000 claims abstract description 7
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 230000001172 regenerating effect Effects 0.000 claims abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 12
- 239000010949 copper Substances 0.000 claims description 12
- 229910000497 Amalgam Inorganic materials 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 150000002730 mercury Chemical class 0.000 claims description 2
- 239000012266 salt solution Substances 0.000 claims description 2
- 239000012670 alkaline solution Substances 0.000 claims 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 230000008021 deposition Effects 0.000 description 9
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 230000007928 solubilization Effects 0.000 description 5
- 238000005063 solubilization Methods 0.000 description 5
- 229940083608 sodium hydroxide Drugs 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 102100033740 Tenomodulin Human genes 0.000 description 1
- 101710114852 Tenomodulin Proteins 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001427 coherent effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000009089 cytolysis Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 229910001987 mercury nitrate Inorganic materials 0.000 description 1
- 229910000474 mercury oxide Inorganic materials 0.000 description 1
- MJGFBOZCAJSGQW-UHFFFAOYSA-N mercury sodium Chemical compound [Na].[Hg] MJGFBOZCAJSGQW-UHFFFAOYSA-N 0.000 description 1
- ORMNPSYMZOGSSV-UHFFFAOYSA-N mercury(II) nitrate Inorganic materials [Hg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ORMNPSYMZOGSSV-UHFFFAOYSA-N 0.000 description 1
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical class [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- DRXYRSRECMWYAV-UHFFFAOYSA-N nitrooxymercury Chemical compound [Hg+].[O-][N+]([O-])=O DRXYRSRECMWYAV-UHFFFAOYSA-N 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910001023 sodium amalgam Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/02—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals
- C25C1/04—Electrolytic production, recovery or refining of metals by electrolysis of solutions of light metals in mercury cathode cells
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/22—Electrolytic production, recovery or refining of metals by electrolysis of solutions of metals not provided for in groups C25C1/02 - C25C1/20
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU75AA00000814A HU170923B (hu) | 1975-05-21 | 1975-05-21 | Sposob izgotovlenija rtutnogo katoda s tvjordym nesuhhim ehlektrodom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1055882A true CA1055882A (en) | 1979-06-05 |
Family
ID=10993010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA235,643A Expired CA1055882A (en) | 1975-05-21 | 1975-09-17 | Process for the electrolytic recovery of gallium and/or alkali metals |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4012298A (forum.php) |
| JP (1) | JPS51138508A (forum.php) |
| CA (1) | CA1055882A (forum.php) |
| CH (1) | CH613230A5 (forum.php) |
| CS (1) | CS199597B2 (forum.php) |
| DD (1) | DD120222A1 (forum.php) |
| DE (1) | DE2534272A1 (forum.php) |
| FR (1) | FR2311861A1 (forum.php) |
| HU (1) | HU170923B (forum.php) |
| SU (1) | SU607557A3 (forum.php) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2953689C2 (de) * | 1979-05-29 | 1986-09-04 | Institut chimii Ural'skogo naučnogo centra Akademii Nauk SSSR, Sverdlovsk | Verfahren zur elektrolytischen Abscheidung von Gallium oder Gallium und Vanadium aus alkalischen Lösungen, die bei der Tonerdeproduktion anfallen |
| US4389187A (en) * | 1981-03-16 | 1983-06-21 | Sims Michael H | Extended holder for a lighter |
| US5135388A (en) * | 1991-05-06 | 1992-08-04 | Pettit Frederick M | Extended-handle lighter |
| RU2221902C2 (ru) * | 2002-03-19 | 2004-01-20 | Школьников Михаил Рудольфович | Способ получения галлия из щелочно-алюминатных растворов глиноземного производства |
| US8329541B2 (en) * | 2007-06-15 | 2012-12-11 | Taiwan Semiconductor Manufacturing Company, Ltd. | InP-based transistor fabrication |
| RU2553318C1 (ru) * | 2014-02-26 | 2015-06-10 | Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук | Способ получения галлия из щелочно-алюминатных растворов глиноземного производства |
| RU2636337C2 (ru) * | 2016-04-29 | 2017-11-22 | Федеральное государственное бюджетное учреждение науки "Институт химии твердого тела Уральского Отделения Российской Академии наук" | Способ получения галлия из щелочно-алюминатных растворов глиноземного производства |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2793179A (en) * | 1955-06-13 | 1957-05-21 | Ind De L Aluminium Sa | Method of recovering gallium from an alkali aluminate lye |
| US3677918A (en) * | 1968-10-21 | 1972-07-18 | Chuo Tatemono Co Ltd | Method for directly electrochemically extracting gallium from a circulating aluminate solution in the bayer process by eliminating impurities |
| US3785949A (en) * | 1972-03-08 | 1974-01-15 | Uhde Gmbh Friedrich | Electrolysis cell with liquid electrode |
-
1975
- 1975-05-21 HU HU75AA00000814A patent/HU170923B/hu unknown
- 1975-07-31 DE DE19752534272 patent/DE2534272A1/de not_active Withdrawn
- 1975-08-04 CH CH1012175A patent/CH613230A5/xx not_active IP Right Cessation
- 1975-08-08 FR FR7524805A patent/FR2311861A1/fr active Granted
- 1975-08-19 SU SU752167187A patent/SU607557A3/ru active
- 1975-08-20 DD DD187947A patent/DD120222A1/xx unknown
- 1975-08-25 CS CS755793A patent/CS199597B2/cs unknown
- 1975-09-12 US US05/612,803 patent/US4012298A/en not_active Expired - Lifetime
- 1975-09-17 CA CA235,643A patent/CA1055882A/en not_active Expired
- 1975-09-25 JP JP50114928A patent/JPS51138508A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US4012298A (en) | 1977-03-15 |
| JPS51138508A (en) | 1976-11-30 |
| SU607557A3 (ru) | 1978-05-15 |
| CH613230A5 (forum.php) | 1979-09-14 |
| FR2311861B3 (forum.php) | 1977-09-16 |
| DE2534272A1 (de) | 1976-12-02 |
| CS199597B2 (en) | 1980-07-31 |
| FR2311861A1 (fr) | 1976-12-17 |
| HU170923B (hu) | 1977-10-28 |
| DD120222A1 (forum.php) | 1976-06-05 |
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