CA1053177A - Bipolar system electrolytic cell - Google Patents
Bipolar system electrolytic cellInfo
- Publication number
- CA1053177A CA1053177A CA236,235A CA236235A CA1053177A CA 1053177 A CA1053177 A CA 1053177A CA 236235 A CA236235 A CA 236235A CA 1053177 A CA1053177 A CA 1053177A
- Authority
- CA
- Canada
- Prior art keywords
- anode
- electrolytic cell
- partition wall
- cathode
- titanium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 98
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000010936 titanium Substances 0.000 claims abstract description 63
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 63
- 238000005192 partition Methods 0.000 claims abstract description 54
- 229910052742 iron Inorganic materials 0.000 claims abstract description 49
- 239000000758 substrate Substances 0.000 claims abstract description 11
- 239000012528 membrane Substances 0.000 claims description 10
- 238000005341 cation exchange Methods 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910044991 metal oxide Inorganic materials 0.000 claims description 6
- -1 platinum group metal oxides Chemical class 0.000 claims description 6
- 238000005098 hot rolling Methods 0.000 claims description 4
- 238000005868 electrolysis reaction Methods 0.000 abstract description 13
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 8
- 239000011780 sodium chloride Substances 0.000 abstract description 4
- 210000004027 cell Anatomy 0.000 description 44
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000007789 gas Substances 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 9
- 239000007788 liquid Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229920003023 plastic Polymers 0.000 description 6
- 239000004033 plastic Substances 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 5
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000374 eutectic mixture Substances 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 2
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical group CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- 208000023514 Barrett esophagus Diseases 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- 101100400378 Mus musculus Marveld2 gene Proteins 0.000 description 1
- JQGGAELIYHNDQS-UHFFFAOYSA-N Nic 12 Natural products CC(C=CC(=O)C)c1ccc2C3C4OC4C5(O)CC=CC(=O)C5(C)C3CCc2c1 JQGGAELIYHNDQS-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 210000001744 T-lymphocyte Anatomy 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 210000000188 diaphragm Anatomy 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/70—Assemblies comprising two or more cells
- C25B9/73—Assemblies comprising two or more cells of the filter-press type
- C25B9/77—Assemblies comprising two or more cells of the filter-press type having diaphragms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP49116695A JPS5232866B2 (en, 2012) | 1974-10-09 | 1974-10-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1053177A true CA1053177A (en) | 1979-04-24 |
Family
ID=14693555
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA236,235A Expired CA1053177A (en) | 1974-10-09 | 1975-09-24 | Bipolar system electrolytic cell |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS5232866B2 (en, 2012) |
| BR (1) | BR7506536A (en, 2012) |
| CA (1) | CA1053177A (en, 2012) |
| DE (1) | DE2545339C2 (en, 2012) |
| FR (1) | FR2287528A1 (en, 2012) |
| GB (1) | GB1503799A (en, 2012) |
| IT (1) | IT1042958B (en, 2012) |
| NL (1) | NL165511C (en, 2012) |
| SE (1) | SE7511257L (en, 2012) |
| SU (1) | SU1291029A3 (en, 2012) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5225061A (en) * | 1991-05-24 | 1993-07-06 | Westerlund Goethe O | Bipolar electrode module |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5929677B2 (ja) * | 1976-11-19 | 1984-07-21 | 旭硝子株式会社 | フイルタ−プレス型電解槽 |
| JPS5421641U (en, 2012) * | 1977-07-15 | 1979-02-13 | ||
| DE2816440A1 (de) * | 1978-04-15 | 1979-10-25 | Uhde Gmbh | Elektrolysezelle |
| JPS5848366Y2 (ja) * | 1978-09-13 | 1983-11-04 | 株式会社トクヤマ | 陽極室 |
| GB2051870B (en) * | 1979-06-07 | 1983-04-20 | Asahi Chemical Ind | Method for electrolysis of aqueous alkali metal chloride solution |
| FR2484464A1 (fr) * | 1980-02-04 | 1981-12-18 | Electricite De France | Electrolyseur sous pression du type filtre presse |
| JPS57137486A (en) * | 1981-02-19 | 1982-08-25 | Tokuyama Soda Co Ltd | Electrolytic cell |
| JPS5732393A (en) * | 1981-06-25 | 1982-02-22 | Asahi Glass Co Ltd | Filter press type electrolytic cell |
| JPS59133384A (ja) * | 1983-01-19 | 1984-07-31 | Toyo Soda Mfg Co Ltd | 電解槽 |
| DE3342449A1 (de) * | 1983-11-24 | 1985-06-05 | Uhde Gmbh, 4600 Dortmund | Elektrolytische zelle fuer die elektrolyse von waessrigem halogenidhaltigem elektrolyt |
| JPS60187688A (ja) * | 1985-01-10 | 1985-09-25 | Kanegafuchi Chem Ind Co Ltd | 高純度なアルカリ金属水酸化物の製法 |
| JPH0674513B2 (ja) * | 1985-10-23 | 1994-09-21 | 旭化成工業株式会社 | 複極式電解槽ユニツト |
| GB8530893D0 (en) * | 1985-12-16 | 1986-01-29 | Ici Plc | Electrode |
| GB8626010D0 (en) * | 1986-10-30 | 1986-12-03 | Ici Plc | Assembling filter press type structure |
| GB8626629D0 (en) * | 1986-11-07 | 1986-12-10 | Ici Plc | Electrolytic cell |
| JPH02130873U (en, 2012) * | 1989-04-05 | 1990-10-30 | ||
| JP3696137B2 (ja) | 2000-09-08 | 2005-09-14 | 株式会社藤田ワークス | 電解槽ユニットの製造方法及び電解槽ユニット |
| TWI255865B (en) | 2002-11-27 | 2006-06-01 | Asahi Kasei Chemicals Corp | Bipolar, zero-gap type electrolytic cell |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3441495A (en) * | 1966-05-20 | 1969-04-29 | Electric Reduction Co | Bipolar electrolytic cell |
| US3451914A (en) * | 1966-08-31 | 1969-06-24 | Electric Reduction Co | Bipolar electrolytic cell |
| GB1348785A (en) * | 1970-05-26 | 1974-03-20 | Ici Ltd | Bipolar cell |
| US3759813A (en) * | 1970-07-17 | 1973-09-18 | Ppg Industries Inc | Electrolytic cell |
| US3755108A (en) * | 1971-08-12 | 1973-08-28 | Ppg Industries Inc | Method of producing uniform anolyte heads in the individual cells of a bipolar electrolyzer |
| JPS509384B2 (en, 2012) * | 1971-09-30 | 1975-04-12 | ||
| BE793045A (fr) * | 1971-12-21 | 1973-06-20 | Rhone Progil | Electrodes bipolaires |
| BE793281A (fr) * | 1971-12-23 | 1973-06-22 | Rhone Progil | Cadres pour cellules electrolytiques du type filtre-presse |
| BE781959A (fr) * | 1972-04-12 | 1972-07-31 | Solvay | Cellule bipolaire, |
-
1974
- 1974-10-09 JP JP49116695A patent/JPS5232866B2/ja not_active Expired
-
1975
- 1975-09-24 GB GB39122/75A patent/GB1503799A/en not_active Expired
- 1975-09-24 CA CA236,235A patent/CA1053177A/en not_active Expired
- 1975-09-29 IT IT27756/75A patent/IT1042958B/it active
- 1975-10-07 BR BR7506536*A patent/BR7506536A/pt unknown
- 1975-10-08 FR FR7530776A patent/FR2287528A1/fr active Granted
- 1975-10-08 SU SU752177557A patent/SU1291029A3/ru active
- 1975-10-08 SE SE7511257A patent/SE7511257L/ unknown
- 1975-10-09 NL NL7511876.A patent/NL165511C/xx not_active IP Right Cessation
- 1975-10-09 DE DE2545339A patent/DE2545339C2/de not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5225061A (en) * | 1991-05-24 | 1993-07-06 | Westerlund Goethe O | Bipolar electrode module |
Also Published As
| Publication number | Publication date |
|---|---|
| NL165511C (nl) | 1981-04-15 |
| DE2545339C2 (de) | 1982-04-01 |
| GB1503799A (en) | 1978-03-15 |
| NL7511876A (nl) | 1976-04-13 |
| JPS5143377A (en, 2012) | 1976-04-14 |
| DE2545339A1 (de) | 1976-04-22 |
| SE7511257L (sv) | 1976-04-12 |
| IT1042958B (it) | 1980-01-30 |
| SU1291029A3 (ru) | 1987-02-15 |
| FR2287528B1 (en, 2012) | 1979-01-19 |
| BR7506536A (pt) | 1976-08-17 |
| JPS5232866B2 (en, 2012) | 1977-08-24 |
| FR2287528A1 (fr) | 1976-05-07 |
| NL165511B (nl) | 1980-11-17 |
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