CA1040703A - Sodium-mixture of metal halides, sulfur battery - Google Patents
Sodium-mixture of metal halides, sulfur batteryInfo
- Publication number
- CA1040703A CA1040703A CA249,143A CA249143A CA1040703A CA 1040703 A CA1040703 A CA 1040703A CA 249143 A CA249143 A CA 249143A CA 1040703 A CA1040703 A CA 1040703A
- Authority
- CA
- Canada
- Prior art keywords
- halide
- positive
- sodium
- aluminum
- reactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011593 sulfur Substances 0.000 title claims abstract description 32
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 32
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 229910001507 metal halide Inorganic materials 0.000 title claims abstract description 12
- 150000005309 metal halides Chemical class 0.000 title claims abstract description 12
- 239000000376 reactant Substances 0.000 claims abstract description 51
- 239000011734 sodium Substances 0.000 claims abstract description 29
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 29
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003792 electrolyte Substances 0.000 claims abstract description 12
- -1 sodium cations Chemical class 0.000 claims description 15
- 229910052782 aluminium Inorganic materials 0.000 claims description 13
- 150000004820 halides Chemical class 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 13
- 229910052787 antimony Inorganic materials 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 11
- 239000002184 metal Substances 0.000 claims description 11
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 8
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 5
- 150000001649 bromium compounds Chemical class 0.000 claims description 5
- 150000001805 chlorine compounds Chemical class 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 2
- 229910052714 tellurium Inorganic materials 0.000 claims description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000000155 melt Substances 0.000 abstract description 2
- 229910052799 carbon Inorganic materials 0.000 description 8
- 239000011521 glass Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 5
- 235000002639 sodium chloride Nutrition 0.000 description 5
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000005297 pyrex Substances 0.000 description 4
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910000792 Monel Inorganic materials 0.000 description 2
- 229910020275 Na2Sx Inorganic materials 0.000 description 2
- 239000004809 Teflon Substances 0.000 description 2
- 229920006362 Teflon® Polymers 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- XXBNLUKLCXTTPH-LECHCGJUSA-N (2S,3R,4S,5R)-2,3,4,5,6-pentahydroxyhexanoyl chloride Chemical compound ClC(=O)[C@@H](O)[C@H](O)[C@@H](O)[C@H](O)CO XXBNLUKLCXTTPH-LECHCGJUSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- 241000689227 Cora <basidiomycete fungus> Species 0.000 description 1
- 208000032139 Halitosis Diseases 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical group Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 241001296096 Probles Species 0.000 description 1
- 101100176490 Rhizobium sp. (strain MTP-10005) graD gene Proteins 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- COOGPNLGKIHLSK-UHFFFAOYSA-N aluminium sulfide Chemical compound [Al+3].[Al+3].[S-2].[S-2].[S-2] COOGPNLGKIHLSK-UHFFFAOYSA-N 0.000 description 1
- BBNUKMKBNHKOES-UHFFFAOYSA-K antimony(3+) trichlorite Chemical compound [Sb+3].[O-][Cl]=O.[O-][Cl]=O.[O-][Cl]=O BBNUKMKBNHKOES-UHFFFAOYSA-K 0.000 description 1
- RPJGYLSSECYURW-UHFFFAOYSA-K antimony(3+);tribromide Chemical compound Br[Sb](Br)Br RPJGYLSSECYURW-UHFFFAOYSA-K 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229940000425 combination drug Drugs 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- QYQIKTBQNRWCEW-UHFFFAOYSA-K dichlorosyloxyalumanyl chlorite Chemical compound [Al+3].[O-]Cl=O.[O-]Cl=O.[O-]Cl=O QYQIKTBQNRWCEW-UHFFFAOYSA-K 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010442 halite Substances 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 239000011669 selenium Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/584,987 US3988163A (en) | 1975-06-09 | 1975-06-09 | Sodium-mixture of metal halides, sulfur battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1040703A true CA1040703A (en) | 1978-10-17 |
Family
ID=24339595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA249,143A Expired CA1040703A (en) | 1975-06-09 | 1976-03-30 | Sodium-mixture of metal halides, sulfur battery |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3988163A (enExample) |
| JP (1) | JPS51150029A (enExample) |
| BR (1) | BR7603200A (enExample) |
| CA (1) | CA1040703A (enExample) |
| DE (1) | DE2613903A1 (enExample) |
| FR (1) | FR2314588A1 (enExample) |
| GB (1) | GB1496648A (enExample) |
| SE (1) | SE7602995L (enExample) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4117207A (en) * | 1977-10-14 | 1978-09-26 | Nardi John C | Molybdenum chloride-tetrachloroaluminate thermal battery |
| CA1149865A (en) * | 1979-08-22 | 1983-07-12 | Margaretha J. Nolte | Electrolyte for an electrochemical cell, and an electrochemical cell including the electrolyte |
| AU566856B2 (en) * | 1984-05-28 | 1987-10-29 | Lilliwyte Societe Anonyme | Electrochemcial cell with fluoride in electrolyte |
| GB8423961D0 (en) * | 1984-09-21 | 1984-10-31 | Lilliwyte Sa | Electrochemical cells |
| GB8523444D0 (en) * | 1985-09-23 | 1985-10-30 | Lilliwyte Sa | Electrochemical cell |
| US6815105B2 (en) * | 2000-10-23 | 2004-11-09 | The Regents Of The University Of California | Fuel cell apparatus and method thereof |
| US20130171487A1 (en) * | 2011-12-30 | 2013-07-04 | Roger Bull | Rechargeable battery and method |
| US8980459B1 (en) | 2014-01-02 | 2015-03-17 | Dynantis Corporation | Secondary metal chalcogenide batteries |
| WO2016089902A1 (en) * | 2014-12-04 | 2016-06-09 | Ceramatec, Inc. | Sodium-halogen secondary cell |
| US10601062B2 (en) | 2015-10-01 | 2020-03-24 | Dynantis Corp. | Sodium metal batteries with intercalating cathode |
| KR102011367B1 (ko) * | 2016-05-17 | 2019-08-16 | 인더스트리얼 테크놀로지 리서치 인스티튜트 | 금속-이온 배터리 및 이의 제조 방법 |
| CN106711464B (zh) * | 2017-01-20 | 2023-07-21 | 江南山 | 一种多管式钠硫电池 |
| CN110911690B (zh) * | 2019-12-06 | 2023-05-30 | 武汉大学 | 一种具有碳化物涂层的液态金属电池正极集流体 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3463670A (en) * | 1967-05-26 | 1969-08-26 | Mallory & Co Inc P R | High energy density thermal cell |
| US3716403A (en) * | 1969-10-20 | 1973-02-13 | Molecular Energy Corp | A method of making semi-conductive cathodes |
| US3635765A (en) * | 1970-06-05 | 1972-01-18 | Nasa | Method of making e m f cell |
| US3751298A (en) * | 1971-05-21 | 1973-08-07 | Union Carbide Corp | Thermal, rechargeable electrochemical cell having lithium monoaluminide electrode and lithium tetrachloroaluminate electrolyte |
| US3879224A (en) * | 1974-04-05 | 1975-04-22 | Gen Electric | Sealed primary sodium-halogen cell |
| US3877984A (en) * | 1974-04-24 | 1975-04-15 | Esb Inc | Alkali metal-metal chloride battery |
-
1975
- 1975-06-09 US US05/584,987 patent/US3988163A/en not_active Expired - Lifetime
-
1976
- 1976-03-03 SE SE7602995A patent/SE7602995L/xx unknown
- 1976-03-11 JP JP51026586A patent/JPS51150029A/ja active Pending
- 1976-03-30 CA CA249,143A patent/CA1040703A/en not_active Expired
- 1976-03-31 DE DE19762613903 patent/DE2613903A1/de not_active Withdrawn
- 1976-04-28 FR FR7612590A patent/FR2314588A1/fr active Granted
- 1976-05-20 BR BR7603200A patent/BR7603200A/pt unknown
- 1976-06-09 GB GB23798/76A patent/GB1496648A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2314588A1 (fr) | 1977-01-07 |
| DE2613903A1 (de) | 1976-12-23 |
| FR2314588B1 (enExample) | 1981-06-19 |
| JPS51150029A (en) | 1976-12-23 |
| SE7602995L (sv) | 1976-12-10 |
| BR7603200A (pt) | 1977-02-15 |
| GB1496648A (en) | 1977-12-30 |
| US3988163A (en) | 1976-10-26 |
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