CA1026763A - Silver catalysts used in ethylene oxide production - Google Patents

Silver catalysts used in ethylene oxide production

Info

Publication number
CA1026763A
CA1026763A CA224,632A CA224632A CA1026763A CA 1026763 A CA1026763 A CA 1026763A CA 224632 A CA224632 A CA 224632A CA 1026763 A CA1026763 A CA 1026763A
Authority
CA
Canada
Prior art keywords
ethylene oxide
catalysts used
oxide production
silver catalysts
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA224,632A
Other languages
English (en)
French (fr)
Inventor
Robert P. Nielsen
John H. La Rochelle
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Canada Ltd
Original Assignee
Shell Canada Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Canada Ltd filed Critical Shell Canada Ltd
Application granted granted Critical
Publication of CA1026763A publication Critical patent/CA1026763A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA224,632A 1974-05-20 1975-04-15 Silver catalysts used in ethylene oxide production Expired CA1026763A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US47139874A 1974-05-20 1974-05-20
US48089674A 1974-06-19 1974-06-19

Publications (1)

Publication Number Publication Date
CA1026763A true CA1026763A (en) 1978-02-21

Family

ID=27043424

Family Applications (1)

Application Number Title Priority Date Filing Date
CA224,632A Expired CA1026763A (en) 1974-05-20 1975-04-15 Silver catalysts used in ethylene oxide production

Country Status (6)

Country Link
JP (1) JPS50160187A (no)
CA (1) CA1026763A (no)
DE (2) DE2521906A1 (no)
FR (1) FR2271869B1 (no)
GB (1) GB1512625A (no)
NL (2) NL182939C (no)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8580982B2 (en) 2009-06-09 2013-11-12 Georg Seeber Use of structured catalyst beds for preparing ethylene oxide
US9714227B2 (en) 2013-12-09 2017-07-25 Basf Se Catalyst for the epoxidation of alkenes
US11400437B2 (en) 2016-08-08 2022-08-02 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1574426A (en) * 1976-03-25 1980-09-10 Shell Int Research Process for preparing modified silver catalysts
DE2704197A1 (de) * 1977-02-02 1978-08-31 Basf Ag Katalysator zur herstellung von aethylenoxid
US4061659A (en) * 1976-06-28 1977-12-06 Shell Oil Company Process for the production of ethylene oxide
DE2636680C3 (de) * 1976-08-14 1979-04-05 Hoechst Ag, 6000 Frankfurt Verfahren zur Verbesserung der Wirksamkeit von Silber-Trägerkatalysatoren
US4097414A (en) * 1976-08-30 1978-06-27 Texaco Development Corp. Modified ethylene oxide catalyst and a process for its preparation
GB1594362A (en) * 1977-05-23 1981-07-30 Ici Ltd Production of alkylene oxides and catalysts therefor
JPS5432408A (en) * 1977-08-13 1979-03-09 Mitsubishi Petrochem Co Ltd Preparation of ethylene oxide and its reaction vessel
DE2861030D1 (en) * 1977-11-19 1981-11-26 Basf Ag Process for preparing an ethylene oxide catalyst
JPS55145677A (en) * 1979-05-02 1980-11-13 Mitsubishi Petrochem Co Ltd Preparation of ethylene oxide
DE2938245A1 (de) * 1979-09-21 1981-04-09 Hoechst Ag, 6000 Frankfurt Verfahren zur verbesserung der wirksamkeit von silber-traegerkatalysatoren
EP0057066B1 (en) * 1981-01-23 1985-03-13 Imperial Chemical Industries Plc Process for the production of ethylene oxide
JPS6110570A (ja) * 1984-06-25 1986-01-18 Mitsui Toatsu Chem Inc エチレンオキシドの製造方法
US5407888A (en) * 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
DE102008011767B4 (de) 2008-02-28 2012-07-26 Basf Se Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen
DE102008014910A1 (de) 2008-03-19 2009-09-24 Basf Se Verwendung eines geträgerten edelmetallhaltigen Katalysators zur oxidativen Dehydrierung
WO2010040688A1 (de) 2008-10-08 2010-04-15 Basf Se Verfahren zur herstellung eines alkylenoxids
US8921587B2 (en) 2011-04-14 2014-12-30 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US8629079B2 (en) 2011-04-14 2014-01-14 Basf Se Process for producing a catalyst for the oxidation of ethylene to ethylene oxide
US8987482B2 (en) 2011-10-28 2015-03-24 Basf Se Process for producing a supported silver catalyst
US9079154B2 (en) 2012-05-04 2015-07-14 Basf Se Catalyst for the epoxidation of alkenes
BR112014026976A2 (pt) 2012-05-04 2017-06-27 Basf Se catalisador sem tungstênio para a epoxidação de alcenos, processo para a produção de catalisadores sem tungstênio para a epoxidação de alcenos e uso de um catalisador
WO2019020793A1 (en) 2017-07-28 2019-01-31 Basf Se PROCESS FOR PRODUCING A MOLDED CATALYST BODY COMPRISING SILVER APPLIED TO AN ALUMINUM CARRIER
TWI808125B (zh) 2018-02-07 2023-07-11 德商巴斯夫歐洲公司 有效地將乙烯氧化轉化為環氧乙烷之催化劑
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
WO2021038027A1 (en) 2019-08-28 2021-03-04 Basf Se Process for preparing an epoxidation catalyst
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
EP4126350B1 (en) 2020-03-27 2024-05-08 Basf Se Process for producing a silver-based epoxidation catalyst
CN115867381A (zh) 2020-06-26 2023-03-28 巴斯夫欧洲公司 多孔催化剂载体成型体
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
WO2021260140A1 (en) 2020-06-26 2021-12-30 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
CN116723893A (zh) 2021-01-26 2023-09-08 巴斯夫欧洲公司 环氧化催化剂
WO2024079247A1 (en) 2022-10-12 2024-04-18 Basf Se Epoxidation catalyst
WO2024089254A1 (en) 2022-10-28 2024-05-02 Basf Se Process for the manufacture of a c4-olefin-derived chemical of interest, in particular citral, from renewably-sourced ethanol

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE793658A (fr) * 1972-01-07 1973-07-04 Shell Int Research Catalyseur utilisable pour la production d'oxyde d'ethylene

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8580982B2 (en) 2009-06-09 2013-11-12 Georg Seeber Use of structured catalyst beds for preparing ethylene oxide
US9714227B2 (en) 2013-12-09 2017-07-25 Basf Se Catalyst for the epoxidation of alkenes
US11400437B2 (en) 2016-08-08 2022-08-02 Basf Se Catalyst for the oxidation of ethylene to ethylene oxide

Also Published As

Publication number Publication date
DE2560684C2 (no) 1989-10-26
GB1512625A (en) 1978-06-01
JPS50160187A (no) 1975-12-25
NL7505705A (nl) 1975-11-24
DE2521906C2 (no) 1989-10-19
NL8800127A (nl) 1988-05-02
NL182939C (nl) 1988-06-16
FR2271869B1 (no) 1980-07-04
AU8124075A (en) 1976-11-18
FR2271869A1 (no) 1975-12-19
DE2521906A1 (de) 1975-12-04
NL182939B (nl) 1988-01-18

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