BRPI0907758A2 - Catalisador de hidrogenação seletiva e o respectivo processo de preparação - Google Patents
Catalisador de hidrogenação seletiva e o respectivo processo de preparaçãoInfo
- Publication number
- BRPI0907758A2 BRPI0907758A2 BRPI0907758-8A BRPI0907758A BRPI0907758A2 BR PI0907758 A2 BRPI0907758 A2 BR PI0907758A2 BR PI0907758 A BRPI0907758 A BR PI0907758A BR PI0907758 A2 BRPI0907758 A2 BR PI0907758A2
- Authority
- BR
- Brazil
- Prior art keywords
- preparation process
- hydrogenation catalyst
- selective hydrogenation
- aluminum oxide
- oxide support
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract 2
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
- C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
- C10G45/36—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/755—Nickel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0063—Granulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/021—After-treatment of oxides or hydroxides
- C01F7/025—Granulation or agglomeration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
- C01F7/441—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by calcination
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/44—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water
- C01F7/447—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes
- C01F7/448—Dehydration of aluminium oxide or hydroxide, i.e. all conversions of one form into another involving a loss of water by wet processes using superatmospheric pressure, e.g. hydrothermal conversion of gibbsite into boehmite
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
- C01P2006/13—Surface area thermal stability thereof at high temperatures
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
- C10G2300/703—Activation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0800724A FR2927267B1 (fr) | 2008-02-07 | 2008-02-07 | Catalyseur d'hydrogenation selective et son procede de preparation |
FR0800724 | 2008-02-07 | ||
PCT/FR2009/000103 WO2009109722A2 (fr) | 2008-02-07 | 2009-01-30 | Catalyseur d'hydrogenation selective et son procede de preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0907758A2 true BRPI0907758A2 (pt) | 2015-07-21 |
BRPI0907758B1 BRPI0907758B1 (pt) | 2017-12-26 |
Family
ID=39942753
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0907758-8A BRPI0907758B1 (pt) | 2008-02-07 | 2009-01-30 | "catalyst and process of selective hydrogenation, and preparation processes of the catalyst support" |
Country Status (13)
Country | Link |
---|---|
US (1) | US8586808B2 (pt) |
EP (1) | EP2249963B1 (pt) |
JP (1) | JP5364726B2 (pt) |
KR (1) | KR101467016B1 (pt) |
CN (1) | CN101939096B (pt) |
AT (1) | ATE526081T1 (pt) |
BR (1) | BRPI0907758B1 (pt) |
DK (1) | DK2249963T3 (pt) |
FR (1) | FR2927267B1 (pt) |
RU (1) | RU2490060C2 (pt) |
SA (1) | SA109300093B1 (pt) |
TW (1) | TWI405611B (pt) |
WO (1) | WO2009109722A2 (pt) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050124745A1 (en) | 2002-04-19 | 2005-06-09 | Saint-Gobain Ceramics & Plastics, Inc. | Flame retardant composites |
US20060104895A1 (en) | 2004-11-18 | 2006-05-18 | Saint-Gobain Ceramics & Plastics, Inc. | Transitional alumina particulate materials having controlled morphology and processing for forming same |
US7479324B2 (en) | 2005-11-08 | 2009-01-20 | Saint-Gobain Ceramics & Plastics, Inc. | Pigments comprising alumina hydrate and a dye, and polymer composites formed thereof |
US8173099B2 (en) | 2007-12-19 | 2012-05-08 | Saint-Gobain Ceramics & Plastics, Inc. | Method of forming a porous aluminous material |
US8460768B2 (en) | 2008-12-17 | 2013-06-11 | Saint-Gobain Ceramics & Plastics, Inc. | Applications of shaped nano alumina hydrate in inkjet paper |
FR2963344B1 (fr) * | 2010-07-29 | 2012-07-27 | IFP Energies Nouvelles | Procede d'hydrogenation selective en presence d'un catalyseur a base d'un metal du groupe viii prepare au moyen d'au moins un oligosaccharide cyclique |
CN103212417B (zh) * | 2013-04-19 | 2015-04-08 | 陕西科技大学 | 氧化镍/氧化铝和镍/氧化铝纳米复合微球的制备方法 |
FR3051684B1 (fr) * | 2016-05-30 | 2020-09-04 | Ifp Energies Now | Catalyseur d'hydrogenation selective comprenant un support extrude |
FR3068983B1 (fr) * | 2017-07-13 | 2019-07-12 | IFP Energies Nouvelles | Procede d'hydrogenation selective mettant en œuvre un catalyseur obtenu par impregnation comprenant un support specifique |
FR3069244B1 (fr) | 2017-07-20 | 2020-03-06 | IFP Energies Nouvelles | Procede d’hydrogenolyse pour une production amelioree de paraxylene |
CN107954817B (zh) * | 2017-12-04 | 2021-02-02 | 万华化学集团股份有限公司 | 一种制备无气味异构十二烷的方法 |
FR3099387B1 (fr) * | 2019-07-31 | 2021-10-29 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel repartie en croute |
FR3099390B1 (fr) * | 2019-07-31 | 2021-10-29 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel sous forme de petites particules et un alliage nickel cuivre |
FR3099388B1 (fr) | 2019-07-31 | 2021-07-16 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute et un alliage nickel cuivre |
FR3099391B1 (fr) * | 2019-07-31 | 2021-10-29 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel sous forme de petites particules repartie en croute |
FR3099389B1 (fr) * | 2019-07-31 | 2021-07-16 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel soufre repartie en croute |
FR3099386B1 (fr) * | 2019-07-31 | 2021-07-16 | Ifp Energies Now | Catalyseur comprenant une phase active de nickel repartie en croute et un alliage nickel cuivre |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3031418A (en) * | 1959-11-30 | 1962-04-24 | Du Pont | Chemically modified alumina monohydrate, dispersions thereof and processes for their preparation |
US3268295A (en) * | 1961-10-06 | 1966-08-23 | Reynolds Metals Co | Alumina hydrate and its method of preparation |
US3879310A (en) * | 1973-03-26 | 1975-04-22 | Kaiser Aluminium Chem Corp | Surface stabilized active alumina |
US4012337A (en) * | 1974-03-13 | 1977-03-15 | Exxon Research And Engineering Company | High surface area alpha aluminas |
US4179408A (en) * | 1977-03-25 | 1979-12-18 | W. R. Grace & Co. | Process for preparing spheroidal alumina particles |
US4371513A (en) * | 1977-03-25 | 1983-02-01 | W. R. Grace & Co. | Alumina compositions |
FR2431993A1 (fr) * | 1978-07-26 | 1980-02-22 | Rhone Poulenc Ind | Nouvelle alumine hautement reactive, son procede de preparation et son application a la preparation d'hydroxychlorure d'aluminium |
US4390456A (en) * | 1979-08-08 | 1983-06-28 | W. R. Grace & Co. | Spheroidal alumina particles and catalysts employing the particles as a support |
US4301037A (en) * | 1980-04-01 | 1981-11-17 | W. R. Grace & Co. | Extruded alumina catalyst support having controlled distribution of pore sizes |
DE4221139A1 (de) * | 1992-06-27 | 1994-01-05 | Huels Chemische Werke Ag | Katalysator und Verfahren zur selektiven Hydrierung ungesättigter Verbindungen sowie Verfahren zur Herstellung des Katalysators |
US5389589A (en) * | 1992-12-22 | 1995-02-14 | Allied-Signal Inc. | Barium-containing alumina |
ZA945342B (en) * | 1993-12-08 | 1995-03-01 | Chemical Res & Licensin | Selective hydrogenation of highly unsaturated compounds in hydrocarbon streams |
US5877106A (en) * | 1997-01-03 | 1999-03-02 | Asec Manufacturing | Stabilized crystalline alumina compositions |
FR2764208B1 (fr) * | 1997-06-10 | 1999-07-16 | Rhodia Chimie Sa | Extrudes d'alumine, leurs procedes de preparation et leur utilisation comme catalyseurs ou supports de catalyseurs |
FR2764213B1 (fr) | 1997-06-10 | 1999-07-16 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe |
US6162350A (en) * | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
DE19836821A1 (de) * | 1998-08-14 | 2000-02-24 | Rwe Dea Ag | Böhmitische Tonerden und aus diesen erhältliche phasenreine, hochtemperaturstabile und hochporöse Aluminiumoxide |
DE19839459A1 (de) * | 1998-08-29 | 2000-03-02 | Basf Ag | Katalysator und Verfahren zur Selektivhydrierung ungesättigter Verbindungen in Kohlenwasserstoffströmen |
FR2787041B1 (fr) * | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement de charges hydrocarbonees dans un reacteur a lit fixe |
US6821923B1 (en) * | 1999-04-08 | 2004-11-23 | Dow Global Technologies Inc. | Method of preparing a catalyst containing gold and titanium |
US7208446B2 (en) * | 1999-08-11 | 2007-04-24 | Albemarle Netherlands B. V. | Quasi-crystalline boehmites containing additives |
DE19959064A1 (de) * | 1999-12-08 | 2001-06-13 | Basf Ag | Trägerkatalysator zur Selektivhydrierung von Alkinen und Dienen |
US6627571B1 (en) * | 2000-03-01 | 2003-09-30 | Symyx Technologies, Inc. | Method and system for the situ synthesis of a combinatorial library of supported catalyst materials |
RU2193061C1 (ru) * | 2001-05-04 | 2002-11-20 | Научно-производственное объединение "Питательные среды" | Питательная среда для культивирования микобактерий туберкулеза (мбт-бульон) |
US7090824B2 (en) * | 2001-07-27 | 2006-08-15 | Board Of Trustees Of Michigan State University | Mesostructured transition aluminas |
FR2867988B1 (fr) * | 2004-03-23 | 2007-06-22 | Inst Francais Du Petrole | Catalyseur supporte dope de forme spherique et procede d'hydrotraitement et d'hydroconversion de fractions petrolieres contenant des metaux |
US7538065B2 (en) * | 2004-09-08 | 2009-05-26 | International Business Machines Corporation | Noble metal-containing catalyst containing a specific ratio of silica to aluminum in the framework |
FR2875716B1 (fr) * | 2004-09-28 | 2007-08-03 | Inst Francais Du Petrole | Nouveaux supports composites alumine sur alumine |
DE102004059282A1 (de) | 2004-10-13 | 2006-04-27 | Basf Ag | Selektivhydrierkatalysator |
DE102004049940A1 (de) * | 2004-10-13 | 2006-04-20 | Basf Ag | Verfahren zur Herstellung eines C4-Olefin-Gemisches durch Selektivhydrierung und Metatheseverfahren zur Verwendung dieses Stroms |
WO2006125832A1 (es) * | 2005-05-23 | 2006-11-30 | Repsol Ypf | Catalizador de níquel, procedimiento de obtención del mismo y uso |
US20090166260A1 (en) * | 2005-12-22 | 2009-07-02 | Stephane Kressmann | Irregularly shaped non-spherical supported catalyst, and a process for hydroconverting heavy oil fractions |
FR2895415B1 (fr) * | 2005-12-22 | 2011-07-15 | Inst Francais Du Petrole | Procede d'hydrogenation selective mettant en oeuvre un catalyseur presentant un support specifique |
-
2008
- 2008-02-07 FR FR0800724A patent/FR2927267B1/fr not_active Expired - Fee Related
-
2009
- 2009-01-30 EP EP09716931A patent/EP2249963B1/fr active Active
- 2009-01-30 US US12/866,503 patent/US8586808B2/en active Active
- 2009-01-30 AT AT09716931T patent/ATE526081T1/de not_active IP Right Cessation
- 2009-01-30 CN CN200980104484.1A patent/CN101939096B/zh active Active
- 2009-01-30 WO PCT/FR2009/000103 patent/WO2009109722A2/fr active Application Filing
- 2009-01-30 DK DK09716931.2T patent/DK2249963T3/da active
- 2009-01-30 JP JP2010545520A patent/JP5364726B2/ja active Active
- 2009-01-30 RU RU2010137113/04A patent/RU2490060C2/ru active
- 2009-01-30 KR KR1020107017437A patent/KR101467016B1/ko active IP Right Grant
- 2009-01-30 BR BRPI0907758-8A patent/BRPI0907758B1/pt not_active IP Right Cessation
- 2009-02-04 SA SA109300093A patent/SA109300093B1/ar unknown
- 2009-02-06 TW TW098103963A patent/TWI405611B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TW200948475A (en) | 2009-12-01 |
EP2249963A2 (fr) | 2010-11-17 |
WO2009109722A2 (fr) | 2009-09-11 |
KR101467016B1 (ko) | 2014-12-01 |
US20100324346A1 (en) | 2010-12-23 |
JP5364726B2 (ja) | 2013-12-11 |
SA109300093B1 (ar) | 2012-01-04 |
TWI405611B (zh) | 2013-08-21 |
EP2249963B1 (fr) | 2011-09-28 |
JP2011512247A (ja) | 2011-04-21 |
WO2009109722A3 (fr) | 2009-11-12 |
CN101939096A (zh) | 2011-01-05 |
KR20100114063A (ko) | 2010-10-22 |
FR2927267B1 (fr) | 2010-04-16 |
BRPI0907758B1 (pt) | 2017-12-26 |
US8586808B2 (en) | 2013-11-19 |
CN101939096B (zh) | 2013-03-13 |
DK2249963T3 (da) | 2012-01-16 |
RU2010137113A (ru) | 2012-03-20 |
RU2490060C2 (ru) | 2013-08-20 |
FR2927267A1 (fr) | 2009-08-14 |
ATE526081T1 (de) | 2011-10-15 |
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