BR9915634A - Método para converter gás natural em hidrocarbonetos lìquidos - Google Patents

Método para converter gás natural em hidrocarbonetos lìquidos

Info

Publication number
BR9915634A
BR9915634A BR9915634-2A BR9915634A BR9915634A BR 9915634 A BR9915634 A BR 9915634A BR 9915634 A BR9915634 A BR 9915634A BR 9915634 A BR9915634 A BR 9915634A
Authority
BR
Brazil
Prior art keywords
natural gas
hydrogen
converting natural
liquid hydrocarbons
gas
Prior art date
Application number
BR9915634-2A
Other languages
English (en)
Other versions
BR9915634B1 (pt
Inventor
Kenneth R Hall
Jerry A Bullin
Philip T Eubank
Aydin Akgerman
Rayford G Anthony
Original Assignee
Texas A & M Univ Sys
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Texas A & M Univ Sys filed Critical Texas A & M Univ Sys
Publication of BR9915634A publication Critical patent/BR9915634A/pt
Publication of BR9915634B1 publication Critical patent/BR9915634B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/002—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor carried out in the plasma state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0873—Materials to be treated
    • B01J2219/0881—Two or more materials
    • B01J2219/0883—Gas-gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894—Processes carried out in the presence of a plasma
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

"MéTODO PARA CONVERTER GáS NATURAL EM HIDROCARBONETOS LìQUIDOS". Um processo para converter gás natural em um líquido inclui aquecer o gás até uma faixa de temperatura selecionada, para converter uma fração da corrente de gás em hidrocarbonetos reativos, principalmente acetileno, e reagir metano e os hidrocarbonetos reativos na presença de um catalisador acídico para produzir um líquido, predominantemente pentano. O hidrogênio resultante das reações é utilizado para aquecer o gás natural entrante, ou com um forno a hidrogênio ou com energia elétrica gerada a partir do hidrogênio. Pouco ou nenhum uso do metano é necessário para fornecer energia ao processo.
BRPI9915634-2A 1998-11-25 1999-11-23 método para converter gás natural em hidrocarbonetos lìquidos. BR9915634B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/199.502 1998-11-25
US09/199,502 US6130260A (en) 1998-11-25 1998-11-25 Method for converting natural gas to liquid hydrocarbons
PCT/US1999/028005 WO2000031004A1 (en) 1998-11-25 1999-11-23 Method for converting natural gas to liquid hydrocarons

Publications (2)

Publication Number Publication Date
BR9915634A true BR9915634A (pt) 2001-11-06
BR9915634B1 BR9915634B1 (pt) 2011-06-28

Family

ID=22737801

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9915634-2A BR9915634B1 (pt) 1998-11-25 1999-11-23 método para converter gás natural em hidrocarbonetos lìquidos.

Country Status (11)

Country Link
US (2) US6130260A (pt)
EP (1) EP1140738B1 (pt)
AT (1) ATE252528T1 (pt)
AU (1) AU769580B2 (pt)
BR (1) BR9915634B1 (pt)
CA (1) CA2352243C (pt)
DE (1) DE69912312T2 (pt)
ES (1) ES2212665T3 (pt)
ID (1) ID29855A (pt)
MX (1) MXPA01005265A (pt)
WO (1) WO2000031004A1 (pt)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6793899B2 (en) * 1998-10-29 2004-09-21 Massachusetts Institute Of Technology Plasmatron-catalyst system
US6602920B2 (en) 1998-11-25 2003-08-05 The Texas A&M University System Method for converting natural gas to liquid hydrocarbons
US6433235B1 (en) 2000-06-09 2002-08-13 Bryan Research & Engineering, Inc. Method for converting methane-containing gaseous hydrocarbon mixtures to liquid hydrocarbons
US6282900B1 (en) * 2000-06-27 2001-09-04 Ealious D. Bell Calcium carbide power system with waste energy recovery
US6518321B1 (en) * 2000-11-08 2003-02-11 Chevron U.S.A. Inc. Method for transporting Fischer-Tropsch products
US6541524B2 (en) * 2000-11-08 2003-04-01 Chevron U.S.A. Inc. Method for transporting Fischer-Tropsch products
GB2386607B (en) * 2000-11-08 2004-09-08 Chevron Usa Inc Method for transporting fischer-tropsch products
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
US20030047146A1 (en) * 2001-09-10 2003-03-13 Daniel Michael J. Plasmatron-internal combustion engine system having an independent electrical power source
NZ532638A (en) * 2001-10-18 2006-12-22 Bryan Res & Engineering Inc High temperature hydrocarbon cracking process for converting natural gas to a liquid hydrocarbon
EP1306632A1 (en) * 2001-10-25 2003-05-02 Shell Internationale Researchmaatschappij B.V. Process for liquefying natural gas and producing liquid hydrocarbons
US7021048B2 (en) * 2002-01-25 2006-04-04 Arvin Technologies, Inc. Combination emission abatement assembly and method of operating the same
US7014930B2 (en) * 2002-01-25 2006-03-21 Arvin Technologies, Inc. Apparatus and method for operating a fuel reformer to generate multiple reformate gases
US6976353B2 (en) 2002-01-25 2005-12-20 Arvin Technologies, Inc. Apparatus and method for operating a fuel reformer to provide reformate gas to both a fuel cell and an emission abatement device
US6651597B2 (en) * 2002-04-23 2003-11-25 Arvin Technologies, Inc. Plasmatron having an air jacket and method for operating the same
AU2003245333B2 (en) * 2002-05-28 2009-07-23 Compactgtl Plc Portable gas-to-liquids unit and method for capturing natural gas at remote locations
EP1532228B1 (en) * 2002-06-14 2011-12-14 Bryan Research & Engineering, Inc. Method for converting methane-containing gaseous hydrocarbon mixtures to liquid hydrocarbons
US20040050345A1 (en) * 2002-09-17 2004-03-18 Bauer Shawn D. Fuel reformer control system and method
US6758035B2 (en) * 2002-09-18 2004-07-06 Arvin Technologies, Inc. Method and apparatus for purging SOX from a NOX trap
US20040052693A1 (en) * 2002-09-18 2004-03-18 Crane Samuel N. Apparatus and method for removing NOx from the exhaust gas of an internal combustion engine
US6702991B1 (en) 2002-11-12 2004-03-09 Arvin Technologies, Inc. Apparatus and method for reducing power consumption of a plasma fuel reformer
US6715452B1 (en) 2002-11-13 2004-04-06 Arvin Technologies, Inc. Method and apparatus for shutting down a fuel reformer
US6903259B2 (en) * 2002-12-06 2005-06-07 Arvin Technologies, Inc. Thermoelectric device for use with fuel reformer and associated method
US6843054B2 (en) * 2003-01-16 2005-01-18 Arvin Technologies, Inc. Method and apparatus for removing NOx and soot from engine exhaust gas
US20040139730A1 (en) * 2003-01-16 2004-07-22 William Taylor Method and apparatus for directing exhaust gas and reductant fluid in an emission abatement system
US6851398B2 (en) * 2003-02-13 2005-02-08 Arvin Technologies, Inc. Method and apparatus for controlling a fuel reformer by use of existing vehicle control signals
CA2427722C (en) 2003-04-29 2007-11-13 Ebrahim Bagherzadeh Preparation of catalyst and use for high yield conversion of methane to ethylene
US20040247953A1 (en) * 2003-06-05 2004-12-09 Vasilios Dossas System and method for managing water generated by fuel cells
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US7919431B2 (en) 2003-09-03 2011-04-05 Synfuels International, Inc. Catalyst formulation for hydrogenation
US7045670B2 (en) * 2003-09-03 2006-05-16 Synfuels International, Inc. Process for liquid phase hydrogenation
US7208647B2 (en) * 2003-09-23 2007-04-24 Synfuels International, Inc. Process for the conversion of natural gas to reactive gaseous products comprising ethylene
US7183451B2 (en) * 2003-09-23 2007-02-27 Synfuels International, Inc. Process for the conversion of natural gas to hydrocarbon liquids
US7141709B2 (en) * 2003-11-13 2006-11-28 Chevron Phillips Chemical Company Lp Methods and systems of producing monoolefins by the extraction-hydrogenation of highly unsaturated hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8013197B2 (en) * 2005-02-18 2011-09-06 Synfuels International, Inc. Absorption and conversion of acetylenic compounds
US7776280B2 (en) 2005-05-10 2010-08-17 Emcon Technologies Llc Method and apparatus for selective catalytic reduction of NOx
CN102728352A (zh) * 2005-07-27 2012-10-17 切夫里昂菲利普化学有限责任公司 选择性加氢催化剂及其制备和使用方法
CN101395088B (zh) 2006-02-03 2012-04-04 Grt公司 轻气体与卤素的分离方法
EA020442B1 (ru) 2006-02-03 2014-11-28 ДжиАрТи, ИНК. Способ превращения углеводородного сырья (варианты) и система для его осуществления
AU2007313481A1 (en) * 2006-04-13 2008-04-24 Dow Global Technologies Inc. Mixed alcohol synthesis with enhanced carbon value use
US8153850B2 (en) * 2007-05-11 2012-04-10 The Texas A&M University System Integrated biofuel production system
JP2010528054A (ja) 2007-05-24 2010-08-19 ジーアールティー インコーポレイテッド 可逆的なハロゲン化水素の捕捉及び放出を組み込んだ領域反応器
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8415517B2 (en) 2008-07-18 2013-04-09 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
SG173521A1 (en) * 2009-03-13 2011-09-29 Exxonmobil Chem Patents Inc Process for methane conversion
US8445739B2 (en) * 2009-08-27 2013-05-21 Synfuels International, Inc. Process for the conversion of natural gas to acetylene and liquid fuels with externally derived hydrogen
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
CN103842487A (zh) 2011-03-29 2014-06-04 富林纳技术有限公司 混合燃料及其制备方法
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
EA201691184A1 (ru) 2013-12-06 2016-09-30 Эксонмобил Апстрим Рисерч Компани Способ и система для получения жидких углеводородов
US10099972B2 (en) 2013-12-06 2018-10-16 Exxonmobil Upstream Research Company Methods and systems for producing liquid hydrocarbons
DK3137585T3 (da) 2014-05-01 2020-09-28 Ark Power Dynamics Llc Apparat omdannelse af fast affald til syntetisk olie, gas og gødning
CN107250324B (zh) 2014-12-03 2019-11-15 德雷塞尔大学 将天然气直接并入烃液体燃料
WO2018128982A1 (en) * 2017-01-04 2018-07-12 Sabic Global Technologies, B.V. An integrated process for conversion of methane to ethylene and benzene
WO2023200609A1 (en) * 2022-04-14 2023-10-19 The Texas A&M University System Conductive liquid hydrocarbon gas plasma for material and chemical synthesis and transformation
US11958745B1 (en) 2023-03-07 2024-04-16 Chevron Phillips Chemical Company Lp Use of methane pyrolysis to decarbonize a hydrocarbon cracking system
US11955674B1 (en) 2023-03-07 2024-04-09 Chevron Phillips Chemical Company Lp Use of a fuel cell to decarbonize a hydrocarbon cracking system

Family Cites Families (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US19794A (en) * 1858-03-30 Improvement in railroad-car couplings
US19500A (en) * 1858-03-02 Sunken vessels
USRE19500E (en) 1935-03-12 Natural gas conversion process
USRE19794E (en) 1935-12-24 Preparation of acetylene
US1023783A (en) * 1911-10-05 1912-04-16 United Gas Improvement Co Process of treating natural gas.
US1229886A (en) * 1916-02-21 1917-06-12 Louis Bond Cherry Synthetic production of hydrocarbon compounds.
US1800586A (en) * 1925-05-01 1931-04-14 Malcolm P Youker Natural-gas-conversion process
US1773611A (en) * 1926-03-15 1930-08-19 Banck Martin Preparation of acetylene and hydrogen
US1917627A (en) * 1927-01-11 1933-07-11 Robert G Wulff Process of producing acetylene gas
US1880307A (en) * 1927-12-27 1932-10-04 Robert G Wulff Method of producing acetylene by compression
US1904426A (en) * 1929-01-12 1933-04-18 Ig Farbenindustrie Ag Production of acetylene and hydrogen
US2037056A (en) * 1931-05-09 1936-04-14 Wulff Process Company Process of producing acetylene gas
US1966779A (en) * 1931-05-11 1934-07-17 Wulff Process Company Method of producing acetylene by compression of natural gas
US2028014A (en) * 1933-05-08 1936-01-14 Reinecke Henry Method of treating hydrocarbon fuels
US2160170A (en) * 1935-03-18 1939-05-30 Ruhrchemie Ag Heat treatment of hydrocarbon gases to dehydrogenate the same
US2080931A (en) * 1935-12-20 1937-05-18 Michael L Benedum Process of and apparatus for the treatment of hydrocarbon fluids
US2328864A (en) * 1939-06-21 1943-09-07 Pure Oil Co Method for thermal polymerization of hydrocarbons
US2558861A (en) * 1945-04-30 1951-07-03 Universal Oil Prod Co Apparatus for production of acetylene and other hydrocarbons
US2645673A (en) * 1945-12-08 1953-07-14 Eastman Kodak Co Process of producing acetylene
US2475282A (en) * 1946-01-21 1949-07-05 Tennessee Eastman Corp Process of producing acetylene black
US2714126A (en) * 1946-07-19 1955-07-26 Kellogg M W Co Method of effecting conversion of gaseous hydrocarbons
US2550089A (en) * 1946-08-31 1951-04-24 Socony Vacuum Oil Co Inc Electrochemical conversion of hydrocarbons
US2675294A (en) * 1949-08-16 1954-04-13 Kellogg M W Co Method of effecting chemical conversions
US2751424A (en) * 1950-09-22 1956-06-19 Koppers Co Inc Process of producing acetylene by pyrolytic reaction from a suitable hydrocarbon
US2768223A (en) * 1952-06-19 1956-10-23 Gen Aniline & Film Corp Manufacture of acetylene
US2986505A (en) * 1958-05-12 1961-05-30 Sun Oil Co Production of acetylene
US3156733A (en) * 1960-12-02 1964-11-10 Happel John Selective pyrolysis of methane to acetylene and hydrogen
NL284848A (pt) * 1961-10-31
US3168592A (en) * 1962-07-19 1965-02-02 Du Pont Manufacture of acetylene by two stage pyrolysis under reduced pressure with the first stage pyrolysis conducted in a rotating arc
US3254960A (en) * 1963-11-26 1966-06-07 Sun Oil Co Wave reactor
US3320146A (en) * 1964-04-17 1967-05-16 Du Pont Process of making acetylene in an electric arc
DE1468159A1 (de) * 1964-08-05 1969-05-08 Knapsack Ag Verfahren und Vorrichtung zur Spaltung von Kohlenwasserstoffen mit Hilfe des elektrischen Lichtbogens
US3389189A (en) * 1965-04-06 1968-06-18 Westinghouse Electric Corp Method and equipment for the pyrolysis and synthesis of hydrocarbons and other gasesand arc heater apparatus for use therein
US3622493A (en) * 1968-01-08 1971-11-23 Francois A Crusco Use of plasma torch to promote chemical reactions
US3674668A (en) * 1969-02-24 1972-07-04 Phillips Petroleum Co Electric arc process for making hydrogen cyanide, acetylene and acrylonitrile
US4014947A (en) * 1969-06-03 1977-03-29 Inst Neftechimicheskogo Sintez Method of producing vinyl chloride
US3697612A (en) * 1969-10-24 1972-10-10 Westinghouse Electric Corp Production of acetylene with an arc heater
US3663394A (en) * 1970-06-01 1972-05-16 Dow Chemical Co Process for the vapor phase rearrangement of hydrocarbons utilizing microwave energy
US3703460A (en) * 1970-09-30 1972-11-21 Atomic Energy Commission Non-equilibrium plasma reactor for natural gas processing
GB1595413A (en) * 1976-12-15 1981-08-12 Ici Ltd Engergy recovery from chemical process off-gas
US4128595A (en) * 1977-05-02 1978-12-05 Phillips Petroleum Company Acetylene hydrogenation in liquid phase with a liquid hydrocarbon reaction medium
DE2952519A1 (de) * 1979-12-28 1981-07-02 Bergwerksverband Gmbh, 4300 Essen Verfahren zur herstellung von acetylen aus kohle
US4424401A (en) * 1980-08-12 1984-01-03 The Broken Hill Proprietary Company Limited Aromatization of acetylene
US4367363A (en) * 1980-12-23 1983-01-04 Gaf Corporation Production of acetylene
US4492591A (en) * 1981-05-26 1985-01-08 Air Products And Chemicals, Inc. Method and apparatus for recovering hydrogen from a feed comprising methane, ethylene, hydrogen and acetylene
US4336045A (en) * 1981-06-29 1982-06-22 Union Carbide Corporation Acetylene removal in ethylene and hydrogen separation and recovery process
US4513164A (en) * 1981-09-01 1985-04-23 Olah George A Condensation of natural gas or methane into gasoline range hydrocarbons
IN159676B (pt) * 1982-04-29 1987-05-30 British Petroleum Co Plc
FR2542004B1 (fr) * 1983-03-02 1985-06-21 British Petroleum Co Procede de conversion assistee a l'electricite de produits carbones lourds
DE3330750A1 (de) * 1983-08-26 1985-03-14 Chemische Werke Hüls AG, 4370 Marl Verfahren zur erzeugung von acetylen und synthese- oder reduktionsgas aus kohle in einem lichtbogenprozess
US4575383A (en) * 1984-04-20 1986-03-11 Atlantic Richfield Company Process for producing acetylene using a heterogeneous mixture
DE3579456D1 (de) * 1984-12-05 1990-10-04 Murabito Luigi Verfahren zum betreiben einer brennkraftmaschine und brennkraftmaschine.
US4705908A (en) * 1984-12-31 1987-11-10 Gondouin Oliver M Natural gas conversion process
US4795536A (en) * 1985-07-10 1989-01-03 Allied-Signal Inc. Hydrogen separation and electricity generation using novel three-component membrane
US4797185A (en) * 1985-07-19 1989-01-10 Allied-Signal Inc. Hydrogen separation and electricity generation using novel electrolyte membrane
FR2614615B1 (fr) * 1987-04-28 1989-08-04 Inst Francais Du Petrole Procede de conversion thermique du methane en hydrocarbures de poids moleculaires plus eleves, reacteur pour la mise en oeuvre du procede et procede de realisation du reacteur
GB8529245D0 (en) * 1985-11-27 1986-01-02 British Petroleum Co Plc Chemical process
US4704496A (en) * 1986-03-24 1987-11-03 The Standard Oil Company Process for converting light hydrocarbons to more readily transportable materials
GB8619717D0 (en) * 1986-08-13 1986-09-24 Johnson Matthey Plc Conversion of methane
US4906800A (en) * 1986-11-17 1990-03-06 The Standard Oil Company Procedure for imparting selectivity to hydrogenation catalysts and method for using the same
US4822940A (en) * 1987-08-17 1989-04-18 The Standard Oil Company Process for converting light hydrocarbons and/or natural gas to liquid hydrocarbons
US5019355A (en) * 1987-09-28 1991-05-28 University Of Alaska Electrical device for conversion of molecular weights
US4973786A (en) * 1987-10-19 1990-11-27 Karra Sankaram B Process for the pyrolytic oxidation of methane to higher molecular weight hydrocarbons and synthesis gas
IN170837B (pt) * 1987-11-17 1992-05-30 Council Scient Ind Res
FR2624115B1 (fr) * 1987-12-03 1990-04-13 Gaz De France Procede et appareil pour la conversion des hydrocarbures
FR2639345B1 (fr) * 1988-11-24 1991-03-15 Gaz De France Procede de conversion de gaz naturel ou d'alcanes legers en hydrocarbures insatures
CA1304419C (en) * 1988-12-22 1992-06-30 Raj N. Pandey Conversion of methane to gasoline-range hydrocarbons via isobutene
US5131993A (en) * 1988-12-23 1992-07-21 The Univeristy Of Connecticut Low power density plasma excitation microwave energy induced chemical reactions
US5015349A (en) * 1988-12-23 1991-05-14 University Of Connecticut Low power density microwave discharge plasma excitation energy induced chemical reactions
US5073666A (en) * 1989-07-14 1991-12-17 Cornell Research Foundation, Inc. Hydrocarbon synthesis from lower alkanes at advanced temperatures and high pressures
US5012029A (en) * 1989-10-16 1991-04-30 Mobil Oil Corp. Conversion of methane
FR2655038B1 (fr) * 1989-11-28 1993-05-14 Inst Francais Du Petrole Procede de production d'hydrocarbures alkylaromatiques a partir de gaz naturel. invention de mm. bernard juguin, jean-claude collin, joseph larue et christian busson.
US5026944A (en) * 1989-12-20 1991-06-25 Energy Mines And Resources Canada Synthesis of isobutene from methane and acetylene
US5277773A (en) * 1989-12-27 1994-01-11 Exxon Research & Engineering Co. Conversion of hydrocarbons using microwave radiation
US5181998A (en) * 1989-12-27 1993-01-26 Exxon Research And Engineering Company Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation
US5205912A (en) * 1989-12-27 1993-04-27 Exxon Research & Engineering Company Conversion of methane using pulsed microwave radiation
US5328577A (en) * 1989-12-27 1994-07-12 Exxon Research & Engineering Co. Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation
US5205915A (en) * 1989-12-27 1993-04-27 Exxon Research & Engineering Company Conversion of methane using continuous microwave radiation (OP-3690)
EP0435591A3 (en) * 1989-12-27 1991-11-06 Exxon Research And Engineering Company Conversion of methane using microwave radiation
US5498278A (en) * 1990-08-10 1996-03-12 Bend Research, Inc. Composite hydrogen separation element and module
US5118893A (en) * 1991-05-24 1992-06-02 Board Of Regents, The University Of Texas System Zeolite catalyzed conversion of acetylene
US5629102A (en) * 1992-04-24 1997-05-13 H Power Corporation Electrical automobile having a fuel cell, and method of powering an electrical automobile with a fuel cell system
US5336825A (en) * 1992-07-10 1994-08-09 Council Of Scientific & Industrial Research Integrated two step process for conversion of methane to liquid hydrocarbons of gasoline range
CA2125599A1 (en) * 1993-06-11 1994-12-12 Jeffrey K. S. Wan Microwave production of c2 hydrocarbons using a carbon catalyst
EP0634211A1 (en) * 1993-07-16 1995-01-18 Texaco Development Corporation Oxidative coupling of methane on manganese oxide octahedral molecular sieve catalyst
JP2991609B2 (ja) * 1993-10-18 1999-12-20 日本碍子株式会社 ガス分離体と金属との接合体および水素ガス分離装置
US5714657A (en) * 1994-03-11 1998-02-03 Devries; Louis Natural gas conversion to higher hydrocarbons
US5488024A (en) * 1994-07-01 1996-01-30 Phillips Petroleum Company Selective acetylene hydrogenation
US5675041A (en) * 1995-01-18 1997-10-07 Exxon Research & Engineering Company Direct hydroformylation of a multi-component synthesis gas containing carbon monoxide, hydrogen, ethylene, and acetylene
US5583274A (en) * 1995-01-20 1996-12-10 Phillips Petroleum Company Alkyne hydrogenation process
US5749937A (en) * 1995-03-14 1998-05-12 Lockheed Idaho Technologies Company Fast quench reactor and method
US5587348A (en) * 1995-04-19 1996-12-24 Phillips Petroleum Company Alkyne hydrogenation catalyst and process

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WO2000031004A1 (en) 2000-06-02
ES2212665T3 (es) 2004-07-16
US6130260A (en) 2000-10-10
US6323247B1 (en) 2001-11-27
ATE252528T1 (de) 2003-11-15
DE69912312T2 (de) 2004-07-29
CA2352243C (en) 2008-05-27
EP1140738B1 (en) 2003-10-22
CA2352243A1 (en) 2000-06-02
DE69912312D1 (de) 2003-11-27
MXPA01005265A (es) 2004-03-10
AU2349000A (en) 2000-06-13
ID29855A (id) 2001-10-18
BR9915634B1 (pt) 2011-06-28
AU769580B2 (en) 2004-01-29
EP1140738A1 (en) 2001-10-10

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