BR9915600A - Processo de polimerização em lama, usando um catalizador de fosfinimina sem suporte - Google Patents

Processo de polimerização em lama, usando um catalizador de fosfinimina sem suporte

Info

Publication number
BR9915600A
BR9915600A BR9915600-8A BR9915600A BR9915600A BR 9915600 A BR9915600 A BR 9915600A BR 9915600 A BR9915600 A BR 9915600A BR 9915600 A BR9915600 A BR 9915600A
Authority
BR
Brazil
Prior art keywords
unsupported
polymerization process
phosphinimine catalyst
catalyst component
mud
Prior art date
Application number
BR9915600-8A
Other languages
English (en)
Other versions
BR9915600B1 (pt
Inventor
Ian Mckay
Dusan Jeremic
Qinyan Wang
Scott P Chisholm
Original Assignee
Nova Chemicals Internat S A
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nova Chemicals Internat S A filed Critical Nova Chemicals Internat S A
Publication of BR9915600A publication Critical patent/BR9915600A/pt
Publication of BR9915600B1 publication Critical patent/BR9915600B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polyethers (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

"PROCESSO DE POLIMERIZAçãO EM LAMA, USANDO UM CATALISADOR DE FOSFINIMINA SEM SUPORTE" Descreve-se um processo de polimerização em lama que usa um coponente catalítico sem suporte, o qual é um complexo organo-metálico que tem um ligante de fosfinimina e um ligante do tipo ciclo-pentadienila. O uso do componente catalítico sem suporte permite técnicas simples e baratas de adição do catalisador, a serem usadas em um processo de polimerização em lama. O componente catalítico é altamente ativo para polimerização ou copolimerização de etileno no processo desta invenção.
BRPI9915600-8A 1998-11-25 1999-11-09 processo de polimerizaÇço em lama para copolimerizaÇço de etileno. BR9915600B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002254512A CA2254512C (en) 1998-11-25 1998-11-25 Slurry polymerization process using an unsupported phosphinimine catalyst
PCT/CA1999/001063 WO2000031155A1 (en) 1998-11-25 1999-11-09 Slurry polymerization process using an unsupported phosphinimine catalyst

Publications (2)

Publication Number Publication Date
BR9915600A true BR9915600A (pt) 2001-08-07
BR9915600B1 BR9915600B1 (pt) 2008-11-18

Family

ID=4163047

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9915600-8A BR9915600B1 (pt) 1998-11-25 1999-11-09 processo de polimerizaÇço em lama para copolimerizaÇço de etileno.

Country Status (12)

Country Link
US (1) US6235853B1 (pt)
EP (1) EP1141046B1 (pt)
JP (1) JP4410941B2 (pt)
KR (1) KR100564267B1 (pt)
CN (1) CN1134464C (pt)
AT (1) ATE260944T1 (pt)
AU (1) AU1143000A (pt)
BR (1) BR9915600B1 (pt)
CA (1) CA2254512C (pt)
DE (1) DE69915352T2 (pt)
ES (1) ES2216643T3 (pt)
WO (1) WO2000031155A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6664358B2 (en) * 2001-06-28 2003-12-16 Nova Chemicals (International) S.A. Highly alternating ethylene styrene interpolymers
EP2261269B1 (en) 2003-07-09 2016-11-09 Arlanxeo Netherlands B.V. Process for the production of a polymer comprising monomeric units of ethylene, an alpha-olefin and a vinyl norbornene
EP2186832B1 (en) * 2008-11-10 2012-09-12 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
EP2186831B1 (en) * 2008-11-10 2013-01-02 Borealis AG Process for the preparation of an unsupported, solid olefin polymerisation catalyst and use in polymerisation of olefins
CA2857456C (en) * 2014-07-22 2022-05-03 Nova Chemicals Corporation Improved control over particulate feed
CN114933665B (zh) * 2022-06-06 2023-11-21 中国科学院长春应用化学研究所 一种异金属双核催化剂及其制法和组合物及应用
CN115043965B (zh) * 2022-07-27 2023-04-21 中国科学技术大学 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4242241A (en) 1977-10-31 1980-12-30 The Celotex Corporation Method for making a slurry containing particulate matter and fibers for a preformed insulation product
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FI96216C (fi) 1994-12-16 1996-05-27 Borealis Polymers Oy Prosessi polyeteenin valmistamiseksi
BR9609604A (pt) * 1995-07-10 1999-05-25 Borealis Polymers Oy ComposiçÃo de revestimento
CA2206944C (en) * 1997-05-30 2006-08-29 Douglas W. Stephan High temperature solution polymerization process
CA2210131C (en) * 1997-07-09 2005-08-02 Douglas W. Stephan Supported phosphinimine-cp catalysts
US6013745A (en) * 1997-08-04 2000-01-11 The Governors Of The University Of Alberta Phosphorus based catalysts for the polymerization of olefins
CA2243775C (en) * 1998-07-21 2007-06-12 Nova Chemicals Ltd. Phosphinimine/heteroatom catalyst component
US6133387A (en) * 1998-11-17 2000-10-17 Nova Chemicals (International) S.A. Group 8, 9 or 10 olefin copolymerization catalyst

Also Published As

Publication number Publication date
EP1141046B1 (en) 2004-03-03
EP1141046A1 (en) 2001-10-10
CN1331705A (zh) 2002-01-16
WO2000031155A1 (en) 2000-06-02
BR9915600B1 (pt) 2008-11-18
DE69915352D1 (de) 2004-04-08
CA2254512C (en) 2008-02-12
ES2216643T3 (es) 2004-10-16
CA2254512A1 (en) 2000-05-25
DE69915352T2 (de) 2005-03-17
AU1143000A (en) 2000-06-13
JP2002530492A (ja) 2002-09-17
KR20010080557A (ko) 2001-08-22
ATE260944T1 (de) 2004-03-15
KR100564267B1 (ko) 2006-03-29
JP4410941B2 (ja) 2010-02-10
CN1134464C (zh) 2004-01-14
US6235853B1 (en) 2001-05-22

Similar Documents

Publication Publication Date Title
BR0016197A (pt) Sistema catalisador múltiplo
TR200100010T2 (tr) Bir katalizör terkibi, ve bunu hazırlamak ve bir polimerizasyon işleminde kullanmak için yöntemler
ES2196809T3 (es) Componente catalizador que tiene por lo menos un ligando fosfinimina y un ligando heteroatomo.
FI971823A0 (fi) Katalyyttikoostumus ja olefiinin polymerointiprosessi
DE69903849D1 (de) Polymerisationskatalysator
TW368506B (en) Catalytic solid for the (co)polymerization of ethylene, process for its preparation, catalytic system for the (co)polymerization of ethylene and process
BR0016725A (pt) Sistema catalisador, uso do mesmo, e, processo para preparar poliolefinas
BR9912316B1 (pt) catalisador de ciclopentadienil/fosfinimina com um e somente um ligando ativável.
BR9913144B1 (pt) processo para polimerização de olefinas.
BR9809735A (pt) Catalisador e processo para a polimerização de olefinas
ATE399800T1 (de) Stickstoffsubstituierte phosphiniminligand
BR9915600A (pt) Processo de polimerização em lama, usando um catalizador de fosfinimina sem suporte
DE50010401D1 (de) Verfahren zur polymerisation von olefinen
RO118204B1 (ro) Catalizator şi procedeu pentru (co) polimerizarea alfa -olefinelor
MY124057A (en) Process for preparing a supported polymerization catalyst using reduced amounts of solvent and polymerization process
DE19981705T1 (de) y-Oxo-Bis-Metallocen-Komplexvrbindungen und Katalysatoren, die dieselben für die Polymerisation von Olefinen verwenden, sowie Polymerisationsverfahren
BR9916115A (pt) Composição de catalisador e métodos para sua preparação e uso em um processo de polimerização
BR0108195A (pt) Método de preparação de ligantes de bisciclopentadienila em ponte do grupo 14
PT953581E (pt) Sistemas cataliticos para a polimerizacao e a copolimerizacao de alfa-olefinas
FI990283A (fi) alfa-olefiinin polymerointikatalysattorisysteemi ja sen käyttö alfa -olefiinien polymerointiin
TH18618EX (th) ระบบตัวเร่งปฏิกิริยาซึ่งอาจใช้สำหรับการพอลิเมอไรซ์ของของแอลฟา-โอเลฟิน และกรรมวิธีสำหรับการพอลิเมอไรซ์นี้
TH18618A (th) ระบบตัวเร่งปฏิกิริยาซึ่งอาจใช้สำหรับการพอลิเมอไรซ์ของของแอลฟา-โอเลฟิน และกรรมวิธีสำหรับการพอลิเมอไรซ์นี้

Legal Events

Date Code Title Description
TE Change of address
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/11/1999, OBSERVADAS AS CONDICOES LEGAIS.

B24B Patent annual fee: requirement for complementing annual fee

Free format text: COMPLEMENTAR A RETRIBUICAO DA 14A ANUIDADE, DE ACORDO COM TABELA VIGENTE, REFERENTE A GUIA DE RECOLHIMENTO 92120843036-9.

B24D Patent annual fee: restoration after fee payment
B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 09.11.2019