BR9901177A - Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa. - Google Patents
Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa.Info
- Publication number
- BR9901177A BR9901177A BR9901177A BR9901177A BR9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A
- Authority
- BR
- Brazil
- Prior art keywords
- polymers
- molecular weight
- rubber
- diene
- gas phase
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S152/00—Resilient tires and wheels
- Y10S152/905—Tread composition
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
- Tires In General (AREA)
- Polymerisation Methods In General (AREA)
Abstract
ELASTÈMEROS DE DIENO EM FASE GASOSA"<D>. A invençmonómeros de dieno conjugados, que são úteis para produzir anionicamente polímeros de dieno ramificaha de estireno butadieno, borracha de poibutadienoadores compreendem uma partícula metalatável, tal como uma borracha ligada, um polímero termoplástico ou um elastómero curado, que é metalatado multiplamente com átomos de metal alcalino do Grupo IA. Os polímeros de dieno multi-ramificados obtidos po os catalisadores exibem propriedades desejáveis, tais como um peso molecular extremamente alto, uma distribuição de peso molecular, Tg e teor de vinila controlados, e a capacidade de absorver prontamente solventes de hidrocarboneto e óleos. Os polímeros são facilmente misturados para formar compostos elastoméricos vulcanizáveis e artigos, tais como pneus, que têm excelente resistência ao desgaste e à ruptura e exibem propriedades de histerese reduzida.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/041,719 US6071847A (en) | 1998-03-13 | 1998-03-13 | Gas phase anionic polymerization of diene elastomers |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9901177A true BR9901177A (pt) | 2000-03-21 |
Family
ID=21917976
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9901177A BR9901177A (pt) | 1998-03-13 | 1999-03-15 | Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa. |
Country Status (8)
Country | Link |
---|---|
US (4) | US6071847A (pt) |
EP (1) | EP0942005B1 (pt) |
JP (1) | JPH11310616A (pt) |
AR (1) | AR018160A1 (pt) |
BR (1) | BR9901177A (pt) |
CA (1) | CA2265387A1 (pt) |
DE (1) | DE69920785T2 (pt) |
ES (1) | ES2230755T3 (pt) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6071847A (en) * | 1998-03-13 | 2000-06-06 | Bridgestone Corporation | Gas phase anionic polymerization of diene elastomers |
US6136914A (en) | 1998-03-13 | 2000-10-24 | Bridgestone Corporation | Anionic polymerization initiators for preparing macro-branched diene rubbers |
US7408005B2 (en) * | 2004-03-12 | 2008-08-05 | The Goodyear Tire & Rubber Company | Hairy polymeric nanoparticles |
US20070280141A1 (en) * | 2006-05-01 | 2007-12-06 | Seagate Technology, Llc | Hardware implementation of loop initialization protocol |
KR101457981B1 (ko) | 2006-10-06 | 2014-11-05 | 가부시키가이샤 브리지스톤 | 분지화 중합체 및 그의 합성 방법 및 용도 |
US8362150B2 (en) * | 2008-02-20 | 2013-01-29 | Bridgestone Corporation | Gas-phase anionic polymerization |
PL2516410T3 (pl) | 2009-12-22 | 2014-10-31 | Bridgestone Corp | Udoskonalona kompozycja modyfikatora winylu oraz procesy zastosowania takiej kompozycji |
JP6557812B2 (ja) * | 2014-05-08 | 2019-08-14 | 熊本県 | 複合粒子およびその製造方法 |
Family Cites Families (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1311856A (en) | 1969-08-07 | 1973-03-28 | Int Synthetic Rubber | Graft copolymerisation process |
GB1451280A (en) * | 1973-06-20 | 1976-09-29 | Mobil Oil Corp | Organic reinforcing fillers for rubber |
CA1053846A (en) * | 1974-12-16 | 1979-05-01 | The Standard Oil Company | Horizontal reactor for the vapor phase polymerization of monomers |
US4297451A (en) * | 1979-07-10 | 1981-10-27 | Phillips Petroleum Company | Dienyllithium initiated polymers |
US4476240A (en) * | 1982-07-01 | 1984-10-09 | The Firestone Tire & Rubber Company | Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier |
US4429091A (en) * | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
US4520123A (en) * | 1984-07-02 | 1985-05-28 | The Firestone Tire & Rubber Company | Catalyst system and process for polymerizing conjugated dienes |
US4761456A (en) | 1985-06-17 | 1988-08-02 | The Dow Chemical Company | Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom |
JPH0755964B2 (ja) * | 1985-12-28 | 1995-06-14 | 旭化成工業株式会社 | 改良されたゴム状重合体の製造方法 |
US4707521A (en) | 1986-03-12 | 1987-11-17 | The Dow Chemical Company | Process for metallating crystalline ethylene-nonconjugated diene polymers and graft polymers prepared therefrom |
DE3729144A1 (de) * | 1987-09-01 | 1989-03-09 | Basf Ag | Bifunktionelle alkaliverbindungen, verfahren zu ihrer herstellung und verwendung als polymerisationsinitiatoren |
US5208303A (en) * | 1989-08-08 | 1993-05-04 | Bp Chemicals Limited | Process for preparing a vanadium-based catalyst suitable for olefin polymerization |
US5252688A (en) * | 1990-01-03 | 1993-10-12 | Bp Chemicals Limited | Process for preparing a Ziegler-Natta type catalyst |
US5221716A (en) | 1990-03-26 | 1993-06-22 | The Goodyear Tire & Rubber Company | Comb polymers having a halobutyl rubber backbone |
US5153159A (en) * | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
US5268413A (en) * | 1990-04-09 | 1993-12-07 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
FR2666338B1 (fr) * | 1990-08-31 | 1994-04-08 | Bp Chemicals Snc | Procede regule de polymerisation d'olefine en phase gazeuse effectue a l'aide d'un catalyseur a base d'oxyde de chrome. |
US5268439A (en) * | 1991-01-02 | 1993-12-07 | Bridgestone/Firestone, Inc. | Tin containing elastomers and products having reduced hysteresis properties |
US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
US5332810A (en) * | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
US5329005A (en) * | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
US5317036A (en) * | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
US5264506A (en) * | 1992-12-30 | 1993-11-23 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing sticky polymers |
DE4334045A1 (de) * | 1993-10-06 | 1995-04-13 | Bayer Ag | Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen |
FR2717797B1 (fr) * | 1994-03-24 | 1996-04-26 | Atochem Elf Sa | Dérivés du 1, 5-diéthényl-naphtalène, leur procédé de fabrication, et leur utilisation comme précurseurs d'amorceurs difonctionnels en polymérisation anionique. |
US5453471B1 (en) * | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
FR2723953B1 (fr) * | 1994-08-25 | 1996-09-20 | Atochem Elf Sa | Amorceur multifonctionnel pour l'obtention de polymeres en etoile par voie anionique, son procede de fabrication, et polymeres en etoile correspondants, leur procede de fabrication et leurs applications |
US5623035A (en) * | 1995-07-21 | 1997-04-22 | The Goodyear Tire & Rubber Company | Process for the synthesis of rubbery polymers |
US5652304A (en) * | 1995-08-31 | 1997-07-29 | The Goodyear Tire & Rubber Company | Vapor phase synthesis of rubbery polymers |
US6136914A (en) * | 1998-03-13 | 2000-10-24 | Bridgestone Corporation | Anionic polymerization initiators for preparing macro-branched diene rubbers |
US6071847A (en) * | 1998-03-13 | 2000-06-06 | Bridgestone Corporation | Gas phase anionic polymerization of diene elastomers |
-
1998
- 1998-03-13 US US09/041,719 patent/US6071847A/en not_active Expired - Lifetime
-
1999
- 1999-03-09 ES ES99103964T patent/ES2230755T3/es not_active Expired - Lifetime
- 1999-03-09 DE DE69920785T patent/DE69920785T2/de not_active Expired - Lifetime
- 1999-03-09 EP EP99103964A patent/EP0942005B1/en not_active Expired - Lifetime
- 1999-03-11 CA CA002265387A patent/CA2265387A1/en not_active Abandoned
- 1999-03-12 JP JP11067314A patent/JPH11310616A/ja active Pending
- 1999-03-12 AR ARP990101095A patent/AR018160A1/es unknown
- 1999-03-15 BR BR9901177A patent/BR9901177A/pt not_active IP Right Cessation
- 1999-11-23 US US09/448,841 patent/US6359087B1/en not_active Expired - Lifetime
- 1999-11-23 US US09/448,528 patent/US6258886B1/en not_active Expired - Lifetime
- 1999-11-23 US US09/448,842 patent/US6255406B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
US6071847A (en) | 2000-06-06 |
AR018160A1 (es) | 2001-10-31 |
CA2265387A1 (en) | 1999-09-13 |
EP0942005A2 (en) | 1999-09-15 |
US6255406B1 (en) | 2001-07-03 |
DE69920785D1 (de) | 2004-11-11 |
JPH11310616A (ja) | 1999-11-09 |
EP0942005B1 (en) | 2004-10-06 |
US6359087B1 (en) | 2002-03-19 |
DE69920785T2 (de) | 2006-02-23 |
ES2230755T3 (es) | 2005-05-01 |
US6258886B1 (en) | 2001-07-10 |
EP0942005A3 (en) | 2001-11-07 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 7A E 8A ANUIDADES. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1898 DE 22/05/2007. |