BR9901177A - Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa. - Google Patents

Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa.

Info

Publication number
BR9901177A
BR9901177A BR9901177A BR9901177A BR9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A BR 9901177 A BR9901177 A BR 9901177A
Authority
BR
Brazil
Prior art keywords
polymers
molecular weight
rubber
diene
gas phase
Prior art date
Application number
BR9901177A
Other languages
English (en)
Inventor
William M Cole
William L Hergenrother
Theodore J Knutson
Georg G A Boehm
Original Assignee
Bridgestone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bridgestone Corp filed Critical Bridgestone Corp
Publication of BR9901177A publication Critical patent/BR9901177A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S152/00Resilient tires and wheels
    • Y10S152/905Tread composition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerization Catalysts (AREA)
  • Tires In General (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

ELASTÈMEROS DE DIENO EM FASE GASOSA"<D>. A invençmonómeros de dieno conjugados, que são úteis para produzir anionicamente polímeros de dieno ramificaha de estireno butadieno, borracha de poibutadienoadores compreendem uma partícula metalatável, tal como uma borracha ligada, um polímero termoplástico ou um elastómero curado, que é metalatado multiplamente com átomos de metal alcalino do Grupo IA. Os polímeros de dieno multi-ramificados obtidos po os catalisadores exibem propriedades desejáveis, tais como um peso molecular extremamente alto, uma distribuição de peso molecular, Tg e teor de vinila controlados, e a capacidade de absorver prontamente solventes de hidrocarboneto e óleos. Os polímeros são facilmente misturados para formar compostos elastoméricos vulcanizáveis e artigos, tais como pneus, que têm excelente resistência ao desgaste e à ruptura e exibem propriedades de histerese reduzida.
BR9901177A 1998-03-13 1999-03-15 Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa. BR9901177A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/041,719 US6071847A (en) 1998-03-13 1998-03-13 Gas phase anionic polymerization of diene elastomers

Publications (1)

Publication Number Publication Date
BR9901177A true BR9901177A (pt) 2000-03-21

Family

ID=21917976

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9901177A BR9901177A (pt) 1998-03-13 1999-03-15 Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa.

Country Status (8)

Country Link
US (4) US6071847A (pt)
EP (1) EP0942005B1 (pt)
JP (1) JPH11310616A (pt)
AR (1) AR018160A1 (pt)
BR (1) BR9901177A (pt)
CA (1) CA2265387A1 (pt)
DE (1) DE69920785T2 (pt)
ES (1) ES2230755T3 (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6071847A (en) * 1998-03-13 2000-06-06 Bridgestone Corporation Gas phase anionic polymerization of diene elastomers
US6136914A (en) 1998-03-13 2000-10-24 Bridgestone Corporation Anionic polymerization initiators for preparing macro-branched diene rubbers
US7408005B2 (en) * 2004-03-12 2008-08-05 The Goodyear Tire & Rubber Company Hairy polymeric nanoparticles
US20070280141A1 (en) * 2006-05-01 2007-12-06 Seagate Technology, Llc Hardware implementation of loop initialization protocol
KR101457981B1 (ko) 2006-10-06 2014-11-05 가부시키가이샤 브리지스톤 분지화 중합체 및 그의 합성 방법 및 용도
US8362150B2 (en) * 2008-02-20 2013-01-29 Bridgestone Corporation Gas-phase anionic polymerization
PL2516410T3 (pl) 2009-12-22 2014-10-31 Bridgestone Corp Udoskonalona kompozycja modyfikatora winylu oraz procesy zastosowania takiej kompozycji
JP6557812B2 (ja) * 2014-05-08 2019-08-14 熊本県 複合粒子およびその製造方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1311856A (en) 1969-08-07 1973-03-28 Int Synthetic Rubber Graft copolymerisation process
GB1451280A (en) * 1973-06-20 1976-09-29 Mobil Oil Corp Organic reinforcing fillers for rubber
CA1053846A (en) * 1974-12-16 1979-05-01 The Standard Oil Company Horizontal reactor for the vapor phase polymerization of monomers
US4297451A (en) * 1979-07-10 1981-10-27 Phillips Petroleum Company Dienyllithium initiated polymers
US4476240A (en) * 1982-07-01 1984-10-09 The Firestone Tire & Rubber Company Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier
US4429091A (en) * 1983-03-09 1984-01-31 The Firestone Tire & Rubber Company Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators
US4520123A (en) * 1984-07-02 1985-05-28 The Firestone Tire & Rubber Company Catalyst system and process for polymerizing conjugated dienes
US4761456A (en) 1985-06-17 1988-08-02 The Dow Chemical Company Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom
JPH0755964B2 (ja) * 1985-12-28 1995-06-14 旭化成工業株式会社 改良されたゴム状重合体の製造方法
US4707521A (en) 1986-03-12 1987-11-17 The Dow Chemical Company Process for metallating crystalline ethylene-nonconjugated diene polymers and graft polymers prepared therefrom
DE3729144A1 (de) * 1987-09-01 1989-03-09 Basf Ag Bifunktionelle alkaliverbindungen, verfahren zu ihrer herstellung und verwendung als polymerisationsinitiatoren
US5208303A (en) * 1989-08-08 1993-05-04 Bp Chemicals Limited Process for preparing a vanadium-based catalyst suitable for olefin polymerization
US5252688A (en) * 1990-01-03 1993-10-12 Bp Chemicals Limited Process for preparing a Ziegler-Natta type catalyst
US5221716A (en) 1990-03-26 1993-06-22 The Goodyear Tire & Rubber Company Comb polymers having a halobutyl rubber backbone
US5153159A (en) * 1990-04-09 1992-10-06 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
US5268413A (en) * 1990-04-09 1993-12-07 Bridgestone/Firestone, Inc. Elastomers and products having reduced hysteresis
FR2666338B1 (fr) * 1990-08-31 1994-04-08 Bp Chemicals Snc Procede regule de polymerisation d'olefine en phase gazeuse effectue a l'aide d'un catalyseur a base d'oxyde de chrome.
US5268439A (en) * 1991-01-02 1993-12-07 Bridgestone/Firestone, Inc. Tin containing elastomers and products having reduced hysteresis properties
US5238893A (en) * 1991-12-30 1993-08-24 Bridgestone Corporation Method of preparing an anionic polymerization initiator
US5332810A (en) * 1992-10-02 1994-07-26 Bridgestone Corporation Solubilized anionic polymerization initiator and preparation thereof
US5329005A (en) * 1992-10-02 1994-07-12 Bridgestone Corporation Soluble anionic polymerization initiators and preparation thereof
US5317036A (en) * 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
US5264506A (en) * 1992-12-30 1993-11-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing sticky polymers
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
FR2717797B1 (fr) * 1994-03-24 1996-04-26 Atochem Elf Sa Dérivés du 1, 5-diéthényl-naphtalène, leur procédé de fabrication, et leur utilisation comme précurseurs d'amorceurs difonctionnels en polymérisation anionique.
US5453471B1 (en) * 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
FR2723953B1 (fr) * 1994-08-25 1996-09-20 Atochem Elf Sa Amorceur multifonctionnel pour l'obtention de polymeres en etoile par voie anionique, son procede de fabrication, et polymeres en etoile correspondants, leur procede de fabrication et leurs applications
US5623035A (en) * 1995-07-21 1997-04-22 The Goodyear Tire & Rubber Company Process for the synthesis of rubbery polymers
US5652304A (en) * 1995-08-31 1997-07-29 The Goodyear Tire & Rubber Company Vapor phase synthesis of rubbery polymers
US6136914A (en) * 1998-03-13 2000-10-24 Bridgestone Corporation Anionic polymerization initiators for preparing macro-branched diene rubbers
US6071847A (en) * 1998-03-13 2000-06-06 Bridgestone Corporation Gas phase anionic polymerization of diene elastomers

Also Published As

Publication number Publication date
US6071847A (en) 2000-06-06
AR018160A1 (es) 2001-10-31
CA2265387A1 (en) 1999-09-13
EP0942005A2 (en) 1999-09-15
US6255406B1 (en) 2001-07-03
DE69920785D1 (de) 2004-11-11
JPH11310616A (ja) 1999-11-09
EP0942005B1 (en) 2004-10-06
US6359087B1 (en) 2002-03-19
DE69920785T2 (de) 2006-02-23
ES2230755T3 (es) 2005-05-01
US6258886B1 (en) 2001-07-10
EP0942005A3 (en) 2001-11-07

Similar Documents

Publication Publication Date Title
BR9902331A (pt) Iniciadores de polimerização aniÈnica para a preparação de borrachas diênicas macrorramificados.
CN101939376B (zh) 热塑性弹性体组合物及其制造方法
US8772415B2 (en) Hydrogenated block copolymers and crosslinking compositions containing the same
KR101615832B1 (ko) 가교 조성물, 가교 조성물의 제조 방법, 및 성형체
KR960004433A (ko) 자동차 내장용 폴리프로필렌 수지 조성물
EP1186619A3 (en) Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition contaning the copolymer, and uses thereof
BR9901177A (pt) Polimerização aniÈnica de elastÈmeros de dieno em fase gasosa.
AU598012B2 (en) Abc block copolymers based on butadiene and isoprene, process for their preparation and their use
JPH01229017A (ja) ブタジエン、イソプレンおよびスチレンを基礎とするabc‐ブロック共重合体、その製造方法およびその用途
JP2733267B2 (ja) 制振性能に優れた組成物
EP0394229A1 (en) Block copolymer composition
CN105315601A (zh) 用作等向性薄膜、挤压及模塑制品的聚合物组成及其混合物
EP2010586A1 (en) Improved thermoplastic elastomer composition
US3558575A (en) Process for the production of copolymers free of block polystyrene
IT9021041A1 (it) Copolimero a blocchi ramificato, procedimenti per la sua preparazione e suo impiego
KR900012965A (ko) 랜덤 ab-블럭 공중합체, 이의 제조방법 및 이의 용도
US4332760A (en) Direct production of elastomer compound from reactor solution
US4408006A (en) Star elastomers in footwear compounds
JP5498207B2 (ja) 架橋組成物、架橋組成物の製造方法、成形体
JP2019183124A (ja) アスファルト含有防水シート用添加剤、アスファルト含有防水シートの製造方法、アスファルト組成物、及びアスファルト含有防水シート
JP5543807B2 (ja) 架橋組成物、架橋組成物の製造方法及び成形体
CN116981729A (zh) 橡胶组合物和轮胎
WO2000073381A1 (fr) Composition a base de caoutchouc, modificateur pour resine la contenant et composition de resine
CN116981730A (zh) 橡胶组合物和轮胎
JP2014177513A (ja) タイヤ用ゴム組成物及び空気入りタイヤ

Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 7A E 8A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1898 DE 22/05/2007.