BR9807844A - Processo e catalisador para a preparação de poliolefinas com peso molecular médio até ultra-alto - Google Patents
Processo e catalisador para a preparação de poliolefinas com peso molecular médio até ultra-altoInfo
- Publication number
- BR9807844A BR9807844A BR9807844-5A BR9807844A BR9807844A BR 9807844 A BR9807844 A BR 9807844A BR 9807844 A BR9807844 A BR 9807844A BR 9807844 A BR9807844 A BR 9807844A
- Authority
- BR
- Brazil
- Prior art keywords
- molecular weight
- catalyst
- ultra
- polyolefins
- subgroup
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
Patente de Invenção: <B>"PROCESSO E CATALISADOR PARA A PREPARAçãO DE POLIOLEFINAS COM PESO MOLECULAR MéDIO ATé ULTRA-ALTO"<D>. A invenção refere-se a um processo para a preparação de poliolefinas com peso molecular médio até ultralato mediana homo- ou copolimerização de olefinas, especialmente etileno com outras alfa-olefinas na presença de um catalisador misto de Ziegler-Natta do tipo metaloceno suportado sobre um material polímero orgânico para o acabamento de artigos moldados, por exemplo, mediante extrusão, fundição por injeção, insuflação de folhas, prensagem por sinterização ou extrusão Ram. O catalisador de acordo com a invenção contém como material polímero orgânico um copolímero de estireno-divinilbenzeno parcialmente clorometilado, um composto complexo suportado sobre o mesmo, que contém Mg, Al e metais de transição do IV° subgrupo, bem como produtos de reação do último com outros compostos orgânicos e metais de transição do IV° subgrupo.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19706409A DE19706409A1 (de) | 1997-02-19 | 1997-02-19 | Verfahren und Katalysator zur Herstellung von mittel- bis ultrahochmolekularen Polyolefinen |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9807844A true BR9807844A (pt) | 2000-10-31 |
Family
ID=7820737
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9807844-5A BR9807844A (pt) | 1997-02-19 | 1998-02-13 | Processo e catalisador para a preparação de poliolefinas com peso molecular médio até ultra-alto |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0961791B1 (pt) |
JP (1) | JP2001511842A (pt) |
CN (1) | CN1248269A (pt) |
BR (1) | BR9807844A (pt) |
CA (1) | CA2281559A1 (pt) |
DE (2) | DE19706409A1 (pt) |
WO (1) | WO1998037108A1 (pt) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GC0000293A (en) | 2000-10-10 | 2006-11-01 | Saudi Basic Ind Corp | Catalyst composition and process for olfin polymerization and copolymerization using supported metallocene catalyst systems |
KR100443383B1 (ko) * | 2001-07-09 | 2004-08-09 | 한국과학기술원 | 올레핀 중합용 고활성 고분자 담지 메탈로센 촉매의제조방법 |
EP1302480B1 (en) * | 2001-10-15 | 2004-08-11 | Saudi Basic Industries Corporation (Sabic) | Catalyst percursor for homo-or copolymerization of olefins and polymerization process using that catalyst precursor |
EP1380601B1 (en) * | 2002-07-12 | 2005-05-25 | Saudi Basic Industries Corporation | Supported Ziegler - metallocene catalyst composition and process for olefin polymerization and olefin copolymerization with alpha olefins using novel catalyst systems |
US6861487B2 (en) | 2003-04-15 | 2005-03-01 | Saudi Basic Industries Corporation | Catalyst precursor for the polymerization of olefins and polymerization process using the same |
DE102004035308A1 (de) * | 2004-07-21 | 2006-02-09 | Ticona Gmbh | Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von unverbrückten Metallocen-Katalysatoren |
US6995235B1 (en) * | 2005-05-02 | 2006-02-07 | Univation Technologies, Llc | Methods of producing polyolefins and films therefrom |
EP1878755A1 (en) | 2006-07-14 | 2008-01-16 | Borealis Technology Oy | Ligand-modified ziegler-natta catalyst for olefin (co) polymerisation |
CN102294233B (zh) | 2011-07-21 | 2013-06-12 | 南京大学 | 一种调控纳米复合吸附剂结构与性能的方法 |
CN115340619B (zh) * | 2021-05-12 | 2023-11-28 | 中国石油天然气股份有限公司 | 低灰分超高分子量聚乙烯树脂及其制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DD257431A1 (de) * | 1982-11-26 | 1988-06-15 | Buna Chem Werke Veb | Verfahren zur herstellung von olefinpolymeren |
DD275693A1 (de) * | 1984-08-15 | 1990-01-31 | Buna Chem Werke Veb | Verfahren zur herstellung von olefinpolymeren |
DD254942A1 (de) * | 1986-12-17 | 1988-03-16 | Akad Wissenschaften Ddr | Verfahren zur herstellung hochaktiver katalysatoren fuer die olefinpolymerisation |
DD255352A1 (de) * | 1986-12-22 | 1988-03-30 | Buna Chem Werke Veb | Verfahren zur herstellung hochaktiver katalysatoren fuer die olefinpolymerisation |
DE3714258A1 (de) * | 1987-04-29 | 1988-11-10 | Bayer Ernst Prof Dr | Verfahren zur darstellung monodisperser, vernetzter polymerkuegelchen |
DD282013A5 (de) * | 1989-02-13 | 1990-08-29 | Buna Chem Werke Veb | Verfahren zur herstellung hochaktiver katalysatoren fuer die ethylenpolymerisation zu ultrahochmolekularem polyethylen |
US5032562A (en) * | 1989-12-27 | 1991-07-16 | Mobil Oil Corporation | Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution |
US5473020A (en) * | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
-
1997
- 1997-02-19 DE DE19706409A patent/DE19706409A1/de not_active Withdrawn
-
1998
- 1998-02-13 WO PCT/DE1998/000420 patent/WO1998037108A1/de active IP Right Grant
- 1998-02-13 CA CA002281559A patent/CA2281559A1/en not_active Abandoned
- 1998-02-13 EP EP98912217A patent/EP0961791B1/de not_active Expired - Lifetime
- 1998-02-13 DE DE59804058T patent/DE59804058D1/de not_active Expired - Fee Related
- 1998-02-13 JP JP53614498A patent/JP2001511842A/ja active Pending
- 1998-02-13 CN CN98802587A patent/CN1248269A/zh active Pending
- 1998-02-13 BR BR9807844-5A patent/BR9807844A/pt unknown
Also Published As
Publication number | Publication date |
---|---|
DE59804058D1 (de) | 2002-06-13 |
WO1998037108A1 (de) | 1998-08-27 |
CA2281559A1 (en) | 1998-08-27 |
EP0961791A1 (de) | 1999-12-08 |
DE19706409A1 (de) | 1998-08-20 |
EP0961791B1 (de) | 2002-05-08 |
JP2001511842A (ja) | 2001-08-14 |
CN1248269A (zh) | 2000-03-22 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application fees: dismissal - article 86 of industrial property law |