BR9807794A - tiouréia - Google Patents
tiouréiaInfo
- Publication number
- BR9807794A BR9807794A BR9807794A BR9807794A BR9807794A BR 9807794 A BR9807794 A BR 9807794A BR 9807794 A BR9807794 A BR 9807794A BR 9807794 A BR9807794 A BR 9807794A BR 9807794 A BR9807794 A BR 9807794A
- Authority
- BR
- Brazil
- Prior art keywords
- latex
- thiourea
- urea
- emulsion
- polyurethane
- Prior art date
Links
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title abstract 7
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 title abstract 6
- 239000004816 latex Substances 0.000 abstract 3
- 239000004202 carbamide Substances 0.000 abstract 2
- 239000000839 emulsion Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 239000004970 Chain extender Substances 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0838—Manufacture of polymers in the presence of non-reactive compounds
- C08G18/0842—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
- C08G18/0861—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
- C08G18/0866—Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3225—Polyamines
- C08G18/3246—Polyamines heterocyclic, the heteroatom being oxygen or nitrogen in the form of an amino group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US3919497P | 1997-03-17 | 1997-03-17 | |
| PCT/US1998/005141 WO1998041552A1 (en) | 1997-03-17 | 1998-03-17 | Continuous process for preparing a polyurethane latex |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9807794A true BR9807794A (pt) | 2000-03-21 |
Family
ID=21904172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9807794A BR9807794A (pt) | 1997-03-17 | 1998-03-17 | tiouréia |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US5959027A (enExample) |
| EP (1) | EP0968239B1 (enExample) |
| JP (1) | JP2001515537A (enExample) |
| KR (1) | KR100505909B1 (enExample) |
| CN (1) | CN1125101C (enExample) |
| AR (1) | AR012083A1 (enExample) |
| AT (1) | ATE282053T1 (enExample) |
| AU (1) | AU745491B2 (enExample) |
| BR (1) | BR9807794A (enExample) |
| CA (1) | CA2283285A1 (enExample) |
| CO (1) | CO5031271A1 (enExample) |
| DE (1) | DE69827477T2 (enExample) |
| ES (1) | ES2227816T3 (enExample) |
| ID (1) | ID22522A (enExample) |
| MY (1) | MY116728A (enExample) |
| TW (1) | TW419490B (enExample) |
| WO (1) | WO1998041552A1 (enExample) |
| ZA (1) | ZA981836B (enExample) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100576536B1 (ko) * | 1998-04-01 | 2006-05-08 | 다우 글로벌 테크놀로지스 인크. | 극성 표면을 갖는 기판을 폴리우레탄 라텍스로 도포하는방법 |
| DE19833819B4 (de) * | 1998-07-28 | 2008-04-10 | Conica Technik Ag | Verwendung von wäßrigen Polyurethan-Dispersionen in Formulierungen für Sportbodenbeläge |
| US6743844B1 (en) | 1998-08-17 | 2004-06-01 | Dow Global Technologies Inc. | Spill resistant carpet backing |
| US7195726B1 (en) | 1998-08-26 | 2007-03-27 | Dow Global Technologies Inc. | Internal mold release for low density reaction injection molded polyurethane foam |
| JP2002530448A (ja) * | 1998-11-16 | 2002-09-17 | マックス−プランク−ゲゼルシャフト・ツア・フェルデルング・デア・ヴィッセンシャフテン・エー・ファオ | 水性および非水性ミニエマルション中の重付加 |
| DE19959916A1 (de) * | 1998-12-30 | 2000-07-20 | Henkel Chile Sa | Füllstoffhaltige Polymerdispersion, Verfahren zu deren Herstellung und deren Verwendung |
| US6087440A (en) * | 1999-02-16 | 2000-07-11 | The Dow Chemical Company | Continuous process for preparing a polyurethane latex |
| DE19913042C2 (de) * | 1999-03-23 | 2001-05-03 | Inventa Ag | Haftvermittler für textile Verstärkungseinlagen, Verfahren zur Herstellung und dessen Verwendung |
| NO20001902L (no) * | 1999-04-14 | 2000-10-16 | Dow Chemical Co | Polyuretanfilmer og dispersjoner for fremstilling derav |
| US6518348B1 (en) | 1999-12-14 | 2003-02-11 | Dow Global Technologies Inc. | Carpet backing compounds thickened by hydrophobically-modified ethylene-oxide-based urethane block copolymers |
| WO2001088007A1 (en) * | 2000-05-16 | 2001-11-22 | Dow Global Technologies Inc. | Polyurethane dispersions and films produced therewith |
| US20020147254A1 (en) | 2000-09-29 | 2002-10-10 | Chan Han | Stable aqueous dispersion of a preformed polymer in concrete and cementatious composites |
| US6911487B2 (en) * | 2000-11-02 | 2005-06-28 | Dow Global Technologies Inc. | Process for preparing aqueous dispersions of hybrid polyurethane particles |
| DE10107494A1 (de) * | 2001-02-15 | 2002-08-22 | Basf Ag | Wäßrige Polyurethandispersion |
| DE10161326A1 (de) * | 2001-12-13 | 2003-06-26 | Max Planck Gesellschaft | Nanostrukturierte Schichten aus Nanopartikeln organischer Halbleiter |
| CN1257929C (zh) * | 2002-03-28 | 2006-05-31 | 大日本油墨化学工业株式会社 | 聚氨酯乳剂的生产方法 |
| JP2005526889A (ja) * | 2002-05-24 | 2005-09-08 | クロンプトン コーポレーション | ポリウレタン分散物 |
| US20040116594A1 (en) * | 2002-12-11 | 2004-06-17 | Debkumar Bhattacharjee | Polyurethane prepolymer, stable aqueous dispersions with high solids containing the same and method of using and preparing the aqueous dispersions |
| EP1581690B1 (en) * | 2002-12-20 | 2012-04-25 | Dow Global Technologies LLC | Process to make synthetic leather and synthetic leather made therefrom |
| DE10322266A1 (de) * | 2003-05-16 | 2004-12-02 | Basf Ag | Selbstemulgierende wäßrige Polyurethandispersion |
| US20050182187A1 (en) * | 2004-02-12 | 2005-08-18 | Koonce William A. | Polyurethane dispersions and coatings made therefrom |
| DE102004017436A1 (de) * | 2004-04-08 | 2005-10-27 | Bayer Materialscience Ag | Verfahren zur kontinuierlichen Herstellung einer wässrigen Polyurethandispersion |
| US20060111506A1 (en) * | 2004-11-22 | 2006-05-25 | Bedri Erdem | Filled polyurethane dispersions |
| US20060116454A1 (en) * | 2004-12-01 | 2006-06-01 | Bedri Erdem | Stable thermally coaguable polyurethane dispersions |
| US7435787B2 (en) * | 2005-09-14 | 2008-10-14 | Momentive Performance Materials Inc. | Process for the continuous production of silylated resin |
| US8022138B2 (en) | 2006-05-18 | 2011-09-20 | Dow Global Technologies Llc | Polyurethane-urea polymers derived from cyclohexane dimethanol |
| CN101610832B (zh) * | 2006-12-19 | 2015-01-21 | 陶氏环球技术有限责任公司 | 制备分散体的设备和制备分散体的方法 |
| US8362142B2 (en) | 2007-12-26 | 2013-01-29 | Dow Global Technologies Llc | Polyurethane dispersions and coatings produced therefrom |
| DE102008020429B4 (de) * | 2008-04-24 | 2012-02-02 | Südzucker AG Mannheim/Ochsenfurt | Verfahren zur Elektroporation von Rübenschnitzeln und Vorrichtung zur Durchführung dieses Verfahrens |
| EP2450389B1 (de) | 2010-11-08 | 2015-03-18 | EMS-Patent AG | Haftvermittler für textile Verstärkungseinlagen und dessen Verwendung |
| EP2649115B2 (de) * | 2010-12-07 | 2018-07-04 | Basf Se | Polyurethan-verbundmaterial |
| EP2730563B1 (de) | 2012-11-13 | 2017-01-11 | Ems-Patent Ag | Verfahren zur Herstellung von MDI-Dimer |
| US9963822B2 (en) | 2013-01-11 | 2018-05-08 | Dow Global Technologies Llc | Polyurethane dispersion based synthetic leathers |
| CN103254414B (zh) * | 2013-05-02 | 2015-09-16 | 广东银洋树脂有限公司 | 磺酸型聚酯多元醇、磺酸型水性聚氨酯及其制备方法 |
| EP2837643B1 (de) | 2013-08-16 | 2018-10-10 | Ems-Patent Ag | Pulverförmiger, in wasser dispergierbarer haftvermittler |
| EP3650502A4 (en) * | 2017-07-04 | 2020-07-22 | Denka Company Limited | COMPOSITION OF POLYMERIC LATEX AND ITS USE |
| US11746465B2 (en) | 2018-08-21 | 2023-09-05 | The Dow Chemical Company | Process for forming a synthetic leather |
| CN112585316B (zh) | 2018-08-21 | 2023-01-17 | 陶氏环球技术有限责任公司 | 形成合成皮革的方法 |
| EP4161974A1 (en) | 2020-06-04 | 2023-04-12 | Rohm and Haas Company | Aqueous dispersion of single phase crosslinked microspheres and film-forming polyurethane particles |
| WO2021247342A1 (en) | 2020-06-04 | 2021-12-09 | Rohm And Haas Company | Coated leather article |
| WO2023117854A1 (en) | 2021-12-20 | 2023-06-29 | Basf Se | Process for the continuous production of aqueous polyurethane dispersions |
| CN120981626A (zh) | 2023-10-27 | 2025-11-18 | 美国陶氏有机硅公司 | 硅酮-(甲基)丙烯酸酯共聚物乳液及其制备以及乳液赋予纺织品拒油性的用途 |
| WO2025106268A1 (en) | 2023-11-16 | 2025-05-22 | Dow Global Technologies Llc | Aqueous coating composition containing an aminosiloxane ester copolymer, method for preparation of the aqueous coating composition, and use for treating leather |
| WO2025106269A1 (en) | 2023-11-16 | 2025-05-22 | Dow Global Technologies Llc | Aqueous coating composition containing an aminosiloxane ester copolymer and a polyurethane binder, and methods for preparation and use thereof |
| WO2025216964A1 (en) | 2024-04-11 | 2025-10-16 | Dow Silicones Corporation | Aqueous coating composition containing a hydroxyl – functional aminosiloxane ester copolymer, method for preparation thereof, and use for leather treatment |
Family Cites Families (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3178310A (en) * | 1962-03-01 | 1965-04-13 | Du Pont | Aqueous polyurethane coating emulsions |
| US3294724A (en) * | 1964-11-23 | 1966-12-27 | Wyandotte Chemicals Corp | Film-forming urethane latices, and preparation by chain extending a prepolymer of anorganic dhsocyanate and a polymeric diol with a piperazine compound |
| US3410817A (en) * | 1965-04-29 | 1968-11-12 | Wyandotte Chemicals Corp | Polyurethane latices |
| US3852224A (en) * | 1972-09-14 | 1974-12-03 | Tee Pak Inc | Microporous films |
| US3895149A (en) * | 1973-07-05 | 1975-07-15 | Atlantic Richfield Co | Carpet backed with thixotropic polyurethane adhesive |
| US3919173A (en) * | 1973-11-23 | 1975-11-11 | Contech Inc | Moisture curable polyurethane systems |
| DE2551094A1 (de) * | 1975-11-14 | 1977-05-26 | Bayer Ag | Verfahren zur herstellung von in wasser dispergierbaren polyurethanen |
| DE2811148A1 (de) * | 1978-03-15 | 1979-09-20 | Bayer Ag | Verfahren zur herstellung von waessrigen polyurethan-dispersionen und -loesungen |
| GB2044125A (en) * | 1979-03-09 | 1980-10-15 | Ici Ltd | Isocyanate-containing emulsions, their manufacture and use as binding agents |
| US4263748A (en) * | 1979-07-12 | 1981-04-28 | General Motors Corporation | Automotive tape drive window regulator |
| US4442259A (en) * | 1982-04-26 | 1984-04-10 | W. R. Grace & Co. | Aqueous-based polyurethane compositions and method of preparation |
| US4444976A (en) * | 1982-12-20 | 1984-04-24 | The Goodyear Tire & Rubber Company | Sag resistant two component adhesive and sealant |
| US4507426A (en) * | 1983-01-03 | 1985-03-26 | The Dow Chemical Company | Synergistic mixture of polyurethane and emulsion polymers useful as thickeners for aqueous systems |
| US4742095A (en) * | 1985-07-25 | 1988-05-03 | Mobay Corporation | Continuous process for the production of aqueous polyurethane-urea dispersions |
| CA1304869C (en) * | 1986-10-21 | 1992-07-07 | Peter H. Markusch | Continuous process for the production of aqueous polyurethane-urea dispersions |
| DE3727252A1 (de) * | 1987-08-15 | 1989-02-23 | Bayer Ag | Verfahren zur herstellung von waessrigen polyurethandispersionen |
| DE3728140A1 (de) * | 1987-08-22 | 1989-03-02 | Bayer Ag | Waessrige loesungen oder dispersionen von polyisocyanat-polyadditionsprodukten, ein verfahren zur herstellung der waessrigen loesungen oder dispersionen sowie ihre verwendung als klebstoff |
| GB8721533D0 (en) * | 1987-09-14 | 1987-10-21 | Polyvinyl Chemical Ind | Aqueous dispersions |
| DE3905007A1 (de) * | 1989-02-18 | 1990-08-23 | Basf Ag | Kontinuierliches verfahren zur herstellung waessriger nicht selbstemulgierender polymerdispersionen |
| GB8913644D0 (en) * | 1989-06-14 | 1989-08-02 | Ici America Inc | Aqueous dispersions |
| CA2020629C (en) * | 1989-07-21 | 2000-02-01 | Frank Landy | Shelf stable fast-cure aqueous coating |
| US5041467A (en) * | 1989-09-08 | 1991-08-20 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Method for production of particulate polymers |
| US5389720A (en) * | 1990-05-25 | 1995-02-14 | Miles Inc. | Aqueous polyisocyanate dispersions |
| US5221710A (en) * | 1991-03-28 | 1993-06-22 | Miles Inc. | Process for preparing and optionally chain extending aqueous polyisocyanate dispersions using static mixers |
| US5270430A (en) * | 1991-11-13 | 1993-12-14 | The Dow Chemical Company | Polymers stabilized with 6-chromanol derivatives |
| JPH06166735A (ja) * | 1992-12-01 | 1994-06-14 | Dai Ichi Kogyo Seiyaku Co Ltd | 活性アミノ基含有ポリウレタンエマルジョン組成物 |
| DE4433929A1 (de) * | 1994-09-23 | 1996-03-28 | Basf Ag | Wasseremulgierbare Polyisocyanate |
| US5539021A (en) * | 1995-06-05 | 1996-07-23 | The Dow Chemical Company | Process for preparing high internal phase ratio emulsions and latexes derived thereof |
| JP3452322B2 (ja) * | 1995-06-05 | 2003-09-29 | ザ・ダウ・ケミカル・カンパニー | 内部相の比率が高いエマルジョンの製造方法およびそれから生じさせたラテックス |
| US5900457A (en) * | 1996-03-05 | 1999-05-04 | H.B. Fuller Licensing & Financing, Inc. | Aqueous polyurethane dispersions formed from polyisocyanates having a methylene bridge |
| US5834554A (en) * | 1996-03-05 | 1998-11-10 | H. B. Fuller Licensing & Financing, Inc. | Laminating adhesives for flexible packaging |
| US5576382A (en) * | 1996-05-05 | 1996-11-19 | Arco Chemical Technology, L.P. | Aqueous polyurethane dispersions based on polyether polyols of low monol content |
| US5859111A (en) * | 1996-12-18 | 1999-01-12 | National Starch And Chemical Investment Holding Corporation | Processes for making nonionic aqueous polyurethane dispersions |
| US6531210B1 (en) * | 1999-12-30 | 2003-03-11 | United States Gypsum Company | Application of methylenediphenyldiisocyanate for producing gypsum/wood fiber board |
-
1998
- 1998-03-04 ZA ZA9801836A patent/ZA981836B/xx unknown
- 1998-03-05 TW TW087103235A patent/TW419490B/zh not_active IP Right Cessation
- 1998-03-16 CO CO98014587A patent/CO5031271A1/es unknown
- 1998-03-16 MY MYPI98001140A patent/MY116728A/en unknown
- 1998-03-16 AR ARP980101182A patent/AR012083A1/es unknown
- 1998-03-17 AU AU65590/98A patent/AU745491B2/en not_active Ceased
- 1998-03-17 DE DE69827477T patent/DE69827477T2/de not_active Expired - Lifetime
- 1998-03-17 ES ES98911693T patent/ES2227816T3/es not_active Expired - Lifetime
- 1998-03-17 EP EP98911693A patent/EP0968239B1/en not_active Expired - Lifetime
- 1998-03-17 CN CN98803451A patent/CN1125101C/zh not_active Expired - Lifetime
- 1998-03-17 ID IDW990992A patent/ID22522A/id unknown
- 1998-03-17 WO PCT/US1998/005141 patent/WO1998041552A1/en not_active Ceased
- 1998-03-17 CA CA002283285A patent/CA2283285A1/en not_active Abandoned
- 1998-03-17 KR KR10-1999-7008462A patent/KR100505909B1/ko not_active Expired - Lifetime
- 1998-03-17 JP JP54068698A patent/JP2001515537A/ja active Pending
- 1998-03-17 US US09/040,027 patent/US5959027A/en not_active Expired - Lifetime
- 1998-03-17 AT AT98911693T patent/ATE282053T1/de not_active IP Right Cessation
- 1998-03-17 BR BR9807794A patent/BR9807794A/pt not_active IP Right Cessation
-
2002
- 2002-02-27 US US10/085,913 patent/US20020082342A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| TW419490B (en) | 2001-01-21 |
| AU6559098A (en) | 1998-10-12 |
| US20020082342A1 (en) | 2002-06-27 |
| WO1998041552A1 (en) | 1998-09-24 |
| ZA981836B (en) | 1999-09-06 |
| AR012083A1 (es) | 2000-09-27 |
| AU745491B2 (en) | 2002-03-21 |
| DE69827477T2 (de) | 2005-10-27 |
| CA2283285A1 (en) | 1998-09-24 |
| KR100505909B1 (ko) | 2005-08-04 |
| CN1125101C (zh) | 2003-10-22 |
| JP2001515537A (ja) | 2001-09-18 |
| CN1250452A (zh) | 2000-04-12 |
| ATE282053T1 (de) | 2004-11-15 |
| MY116728A (en) | 2004-03-31 |
| KR20000076360A (ko) | 2000-12-26 |
| US5959027A (en) | 1999-09-28 |
| ID22522A (id) | 1999-10-28 |
| CO5031271A1 (es) | 2001-04-27 |
| EP0968239A1 (en) | 2000-01-05 |
| DE69827477D1 (de) | 2004-12-16 |
| EP0968239B1 (en) | 2004-11-10 |
| ES2227816T3 (es) | 2005-04-01 |
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