BR8203690A - Processo para a obtencao de acroleina respectivamente metacroleina por oxidacao catalitica do propileno respectivamente iso-butileno ou butanol-terciario em misturas de gases contendo oxigenio - Google Patents

Processo para a obtencao de acroleina respectivamente metacroleina por oxidacao catalitica do propileno respectivamente iso-butileno ou butanol-terciario em misturas de gases contendo oxigenio

Info

Publication number
BR8203690A
BR8203690A BR8203690A BR8203690A BR8203690A BR 8203690 A BR8203690 A BR 8203690A BR 8203690 A BR8203690 A BR 8203690A BR 8203690 A BR8203690 A BR 8203690A BR 8203690 A BR8203690 A BR 8203690A
Authority
BR
Brazil
Prior art keywords
metachrolein
butylene
butanol
tertiary
catalytic oxidation
Prior art date
Application number
BR8203690A
Other languages
English (en)
Inventor
Dietrich Arntz
Gunter Prescher
Johannes Heilos
Original Assignee
Degussa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Degussa filed Critical Degussa
Publication of BR8203690A publication Critical patent/BR8203690A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BR8203690A 1981-06-26 1982-06-24 Processo para a obtencao de acroleina respectivamente metacroleina por oxidacao catalitica do propileno respectivamente iso-butileno ou butanol-terciario em misturas de gases contendo oxigenio BR8203690A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3125061A DE3125061C2 (de) 1981-06-26 1981-06-26 Verfahren zur Herstellung von Acrolein bzw. Methacrolein durch katalytische Oxidation von Propylen bzw. Isobutylen oder tertiär-Butanol in sauerstoffhaltigen Gasgemischen

Publications (1)

Publication Number Publication Date
BR8203690A true BR8203690A (pt) 1983-06-21

Family

ID=6135390

Family Applications (1)

Application Number Title Priority Date Filing Date
BR8203690A BR8203690A (pt) 1981-06-26 1982-06-24 Processo para a obtencao de acroleina respectivamente metacroleina por oxidacao catalitica do propileno respectivamente iso-butileno ou butanol-terciario em misturas de gases contendo oxigenio

Country Status (8)

Country Link
US (1) US4442308A (pt)
EP (1) EP0068193B1 (pt)
JP (1) JPS58930A (pt)
BR (1) BR8203690A (pt)
CA (1) CA1165779A (pt)
DE (2) DE3125061C2 (pt)
ES (1) ES512340A0 (pt)
SU (1) SU1604154A3 (pt)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3125062C2 (de) * 1981-06-26 1984-11-22 Degussa Ag, 6000 Frankfurt Verfahren zur Herstellung von abriebfesten Schalenkatalysatoren und Verwendung eines so erhaltenen Katalysators
DE3562482D1 (en) * 1984-07-18 1988-06-09 Mitsubishi Rayon Co Process for producing methacrolein and methacrylic acid
US5198578A (en) * 1986-07-17 1993-03-30 Union Carbide Chemicals Anhydrous diluents for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
US5183936A (en) * 1986-08-21 1993-02-02 Union Carbide Chemicals & Plastics Technology Corporation Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
CA1305178C (en) * 1986-08-21 1992-07-14 Gordon Gene Harkreader Anhydrous diluent process for the propylene oxidation reaction to acrolein and acrolein oxidation to acrylic acid
BR8800627A (pt) * 1987-02-17 1988-09-27 Nippon Catalytic Chem Ind Catalisador usado para producao por oxidacao catalitica em fase gasosa,de uma olefina ou alcool terciario c3-5,processo para preparar um catalisador,catalisador para oxidacao de uma olefina c3-5 e catalisador para oxidacao de isobutileno ou butenol terciario
US4999452A (en) * 1989-05-15 1991-03-12 Union Carbide Chemicals And Plastics Company Inc. Process for producing acrylic ester
DE3930533C1 (pt) * 1989-09-13 1991-05-08 Degussa Ag, 6000 Frankfurt, De
DE3930534A1 (de) * 1989-09-13 1991-03-21 Degussa Verfahren zur herstellung von acrolein durch katalytische gasphasenoxidation von propen
FR2670686B1 (fr) * 1990-12-20 1994-08-12 Rhone Poulenc Chimie Composition catalytique pour la preparation d'aldehydes alpha,beta-insatures par oxydation d'olefines en phase gazeuse et procede d'oxydation.
JP3272745B2 (ja) * 1991-06-06 2002-04-08 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造法
US6437193B1 (en) 1997-07-15 2002-08-20 E. I. Du Pont De Nemours And Company Vapor phase oxidation of propylene to acrolein
CN1108865C (zh) * 1997-09-03 2003-05-21 中国石油化工集团公司 生产丙烯腈的催化剂
US6281384B1 (en) 1998-06-26 2001-08-28 E. I. Du Pont Nemours And Company Vapor phase catalytic oxidation of propylene to acrylic acid
US6337424B1 (en) 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
FR2826959B1 (fr) * 2001-07-06 2003-09-05 Atofina Procede de fabrication d'acroleine a partir du propylene par reaction redox en reacteur a lit entraine et utilisation d'une composition solide d'oxydes mixtes comme systeme redox dans ladite reaction
KR100513664B1 (ko) * 2002-05-16 2005-09-07 주식회사 엘지화학 프로필렌의 부분 산화 반응용 촉매의 제조 방법
US20040038820A1 (en) * 2002-08-20 2004-02-26 Nippon Shokubai Co., Ltd. Production process for catalyst
US20060205978A1 (en) * 2002-08-20 2006-09-14 Nippon Shokubai Co., Ltd. Production process for catalyst
US7022643B2 (en) 2002-08-20 2006-04-04 Nippon Shokubai Co., Ltd. Production process for catalyst
JP4295521B2 (ja) * 2003-02-13 2009-07-15 株式会社日本触媒 アクリル酸製造用触媒およびアクリル酸の製造方法
US20070275849A1 (en) * 2003-10-14 2007-11-29 Shin Hyun J Catalyst For Gaseous Partial Oxidation Of Propylene And Method For Preparing The Same
DE102004037739A1 (de) 2004-08-04 2006-03-16 Degussa Ag Wolframat enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung
DE102004061016A1 (de) 2004-12-18 2006-06-22 Degussa Ag Halogenidhaltige Alkaliwolframate enthaltende Katalysatoren zur Synthese von Alkylmercaptan und Verfahren zu ihrer Herstellung
US7649111B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7649112B2 (en) * 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7851397B2 (en) * 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7732367B2 (en) * 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
DE102006032635A1 (de) 2006-07-13 2008-01-17 Evonik Degussa Gmbh Verfahren zur Herstellung von Alkylmercaptanen in einem Mehrzonenfestbettreaktor
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
EP1987877A3 (en) 2007-03-29 2010-10-13 Nippon Shokubai Co., Ltd. Oxide catalyst, process for producing acrolein or acrylic acid and process for producing water-absorbent resin
JP2008264766A (ja) * 2007-03-29 2008-11-06 Nippon Shokubai Co Ltd 酸化物触媒および該触媒を用いたアクロレインまたはアクリル酸の製造方法ならびに当該アクリル酸を用いた吸水性樹脂の製造方法
KR101086731B1 (ko) * 2008-10-17 2011-11-25 금호석유화학 주식회사 1-부텐의 산화/탈수소화 반응에서 1,3-부타디엔 제조용 비스무스 몰리브덴 철 복합 산화물 촉매 및 제조방법
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
US9115067B1 (en) 2014-12-22 2015-08-25 Novus International, Inc. Process for the manufacture of acrolein
CA3065752A1 (en) 2018-03-23 2019-09-26 Mitsubishi Chemical Corporation Catalyst

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL135123C (pt) * 1964-10-06
US3761424A (en) * 1968-08-31 1973-09-25 Degussa Catalysts for the oxidation of alkenes
FR2016707A1 (pt) * 1968-08-31 1970-05-08 Degussa
IN142430B (pt) * 1975-04-21 1977-07-09 Standard Oil Co
DE2531770C3 (de) * 1975-07-16 1979-04-26 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt Verfahren zum Aufbringen eines katalytisch aktiven Überzugs auf Katalysatorträger
DE2805801A1 (de) * 1978-02-11 1979-08-16 Driam Metallprodukt Gmbh & Co Vorrichtung zum beschichten von granulaten wie drageekerne mit einer huelle und zum antrocknen der huelle durch trocknungsluft
US4267386A (en) * 1978-11-13 1981-05-12 Celanese Corporation Olefin oxidation catalyst
DE2909670A1 (de) * 1979-03-12 1980-10-02 Basf Ag Verfahren zur herstellung von schalenkatalysatoren
DE2909597A1 (de) * 1979-03-12 1980-09-25 Basf Ag Verfahren zur herstellung von 3 bis 4 c-atome enthaltenden alpha , beta -olefinisch ungesaettigten aldehyden

Also Published As

Publication number Publication date
ES8307700A1 (es) 1983-07-01
CA1165779A (en) 1984-04-17
JPS58930A (ja) 1983-01-06
DE3125061C2 (de) 1984-03-15
DE3260134D1 (en) 1984-06-07
US4442308A (en) 1984-04-10
EP0068193B1 (de) 1984-05-02
DE3125061A1 (de) 1983-01-13
SU1604154A3 (ru) 1990-10-30
ES512340A0 (es) 1983-07-01
JPH0427973B2 (pt) 1992-05-13
EP0068193A1 (de) 1983-01-05

Similar Documents

Publication Publication Date Title
BR8203690A (pt) Processo para a obtencao de acroleina respectivamente metacroleina por oxidacao catalitica do propileno respectivamente iso-butileno ou butanol-terciario em misturas de gases contendo oxigenio
JPS5656225A (en) Reactor for catalytic gas reaction
GB2070959B (en) Catalyst for purifying exhaust gases and method for manufacturing same
PL202570A1 (pl) Urzadzenie do katalitycznego oczyszczania gazow spalinowych
FR2496629B1 (fr) Procede et catalyseur de decomposition catalytique de l'ozone
BE883332A (fr) Procede et catalyseurs de desulfuration selective de coupes olefiniques
NO160491C (no) Fremgangsmaate for katalytisk desulfurering av en sur gasssom inneholder h2s.
DE2963035D1 (en) Catalyst, method of manufacture, and method of catalytic oxidation of ethylene
GB2021967B (en) Catalytic converter for purifying exhaust gases
AT379760B (de) Reaktor zur durchfuehrung katalytischer reaktionen
DE3069919D1 (en) Liquid-gas catalytic reaction process
GB1545525A (en) Method for purifying industrial exhaust gases
FR2351702A1 (fr) Catalyseur pour reactions d'oxydation et procede pour sa preparation
BE857710A (fr) Procede d'oxydation catalytique d'hydrocarbures halogenes en c2-c4'
BR7800381A (pt) Processo aperfeicoado para a conversao de um material de alimentacao carbonaceo solido na presenca de um catalisador contendo metal alcalino em liquidos e/ou gases
ES523059A0 (es) Procedimiento para la obtencion de un catalizador para la transformacion de gases que contienen azufre
BR8101348A (pt) Catalisador de oxidacao para uso em unidade de purificacao catalitico de gas de exaustao
PL209332A1 (pl) Sposob oczyszczania i chlodzenia gazow po czesciowym utlenieniu,zawierajacych zanieczyszczenie pyliste
IT7927030A0 (it) Processo per la purificazione di gas di rifiuto contenenti gasnitrosi.
BR8400538A (pt) Composicao catalitica de oxido de metal e processo para sua preparacao processo para a oxidacao em fase gasosa de propileno para acroleina e processo para a amoxidacao em fase gasosa de propileno para acrilonitrila
IT1061036B (it) Reattore per la trasformazione catalitica di idrocarburi con un gas contenente ossigeno
FR2337707A1 (fr) Procede d'oxydation catalytique d'hydrocarbures halogenes en c2-c4
JPS5495992A (en) Catalyst for catalytic decomposition of hydrocarbons
IT1098284B (it) Processo continuo per la depurazione di gas industriali di scarico,contenenti formaldeide
JPS5544331A (en) Continuous purifying method of industrial waste gas containing formaldehyde