BR112022018748A2 - Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas - Google Patents
Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticasInfo
- Publication number
- BR112022018748A2 BR112022018748A2 BR112022018748A BR112022018748A BR112022018748A2 BR 112022018748 A2 BR112022018748 A2 BR 112022018748A2 BR 112022018748 A BR112022018748 A BR 112022018748A BR 112022018748 A BR112022018748 A BR 112022018748A BR 112022018748 A2 BR112022018748 A2 BR 112022018748A2
- Authority
- BR
- Brazil
- Prior art keywords
- polymeric microspheres
- thermoplastic polymeric
- alkyl
- halogen
- thermoplastic polymer
- Prior art date
Links
- 229920001169 thermoplastic Polymers 0.000 title abstract 8
- 239000004005 microsphere Substances 0.000 title abstract 5
- 239000004416 thermosoftening plastic Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 2
- 238000000034 method Methods 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
- 239000000178 monomer Substances 0.000 abstract 3
- 125000001424 substituent group Chemical group 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 150000002825 nitriles Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 125000005647 linker group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B16/00—Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B16/04—Macromolecular compounds
- C04B16/08—Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
- C04B16/082—Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons other than polystyrene based, e.g. polyurethane foam
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/06—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
- C04B38/0615—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/18—Making expandable particles by impregnating polymer particles with the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/10—Encapsulated ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/22—Expandable microspheres, e.g. Expancel®
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2343/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
A invenção refere-se a microesferas poliméricas termoplásticas que compreendem uma casca de polímero termoplástico em torno de um núcleo oco, em que a casca de polímero termoplástico compreende um copolímero de um monômero da Fórmula 1, em que: cada um dentre A1 a A11 é independentemente selecionado dentre H e C1 a C4 alquil, em que cada grupo C1-4 alquil pode opcionalmente ser substituído por um ou mais substituintes selecionados dentre halogênio, hidróxi e C1-4 alcóxi; A12 é selecionado dentre C1 a C4 alquil, em que o grupo C1-4 alquil pode opcionalmente ser substituído por um ou mais substituintes selecionados dentre halogênio, hidróxi e C1-4 alcóxi; X é um grupo de ligação selecionado dentre -O-, -NR-, -S-, -OC(O)-, -NRC(O)-, -SC(O)-, -C(O)O-, -C(O)NR- e -C(O)S-; e R é H ou C1-2 alquil opcionalmente substituído por um ou mais substituintes selecionados dentre halogênio e hidroxila; em que a casca do polímero termoplástico compreende um ou mais outros co-monômeros etilenicamente insaturados não da Fórmula 1 tendo não mais que uma ligação dupla C=C não aromática, pelo menos um dos quais é um monômero contendo nitrila; o teor do monômero contendo nitrila no copolímero sendo maior que 20% em peso.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20168101 | 2020-04-03 | ||
PCT/EP2021/058762 WO2021198492A1 (en) | 2020-04-03 | 2021-04-01 | Thermally expandable microspheres prepared from bio-based monomers |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112022018748A2 true BR112022018748A2 (pt) | 2022-11-01 |
Family
ID=70285426
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112022018748A BR112022018748A2 (pt) | 2020-04-03 | 2021-04-01 | Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas |
Country Status (7)
Country | Link |
---|---|
US (1) | US20230174734A1 (pt) |
EP (1) | EP4126334A1 (pt) |
JP (1) | JP2023519741A (pt) |
KR (1) | KR20220136467A (pt) |
CN (1) | CN115297959A (pt) |
BR (1) | BR112022018748A2 (pt) |
WO (1) | WO2021198492A1 (pt) |
Family Cites Families (37)
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US475213A (en) | 1892-05-17 | William fraser | ||
US2838523A (en) | 1954-06-10 | 1958-06-10 | Quaker Oats Co | Production of tetrahydrofurfuryl alcohol |
US3007878A (en) | 1956-11-01 | 1961-11-07 | Du Pont | Aquasols of positively-charged coated silica particles and their production |
US3139406A (en) | 1960-10-12 | 1964-06-30 | Nalco Chemical Co | Method of producing hydrous metal oxide sols |
US3252917A (en) | 1962-08-27 | 1966-05-24 | Nalco Chemical Co | Method of producing alumina-coated silica in sol form |
DE1468932B2 (de) | 1965-09-23 | 1976-01-22 | Röhm GmbH, 6100 Darmstadt | Verfahren zur kontinuierlichen herstellung von niedermolekularen aliphatischen acrylsaeureestern |
US3615972A (en) | 1967-04-28 | 1971-10-26 | Dow Chemical Co | Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same |
US3620978A (en) | 1968-07-18 | 1971-11-16 | Du Pont | Process for preparing stable positively charged alumina-coated silica sols |
US3719607A (en) | 1971-01-29 | 1973-03-06 | Du Pont | Stable positively charged alumina coated silica sols and their preparation by postneutralization |
US3745126A (en) | 1971-04-22 | 1973-07-10 | Du Pont | Stable positively charged alumina coated silica sols |
US3864142A (en) | 1971-04-26 | 1975-02-04 | Nalco Chemical Co | Metal oxide sols |
US3956171A (en) | 1973-07-30 | 1976-05-11 | E. I. Du Pont De Nemours And Company | Process for preparing stable positively charged alumina coated silica sols and product thereof |
US3945956A (en) | 1975-06-23 | 1976-03-23 | The Dow Chemical Company | Polymerization of styrene acrylonitrile expandable microspheres |
JPS6021770B2 (ja) | 1980-02-14 | 1985-05-29 | 松本油脂製薬株式会社 | 熱膨張性マイクロカプセルの製造法 |
ATE101823T1 (de) | 1988-06-23 | 1994-03-15 | Casco Nobel Ab | Verfahren und vorrichtung zur herstellung expandierbarer thermoplastischer mikrokugeln. |
JP2727618B2 (ja) | 1989-01-26 | 1998-03-11 | 三菱瓦斯化学株式会社 | 不飽和カルボン酸エステルの製造方法 |
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AU3996800A (en) | 1998-12-10 | 2000-07-12 | Zms, Llc | Expandable polymeric microspheres, their method of production, and uses and products thereof |
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CN1280088C (zh) * | 2000-09-06 | 2006-10-18 | 阿普尔顿纸张公司 | 原位微胶囊化胶粘剂 |
AU2003265192A1 (en) | 2002-10-14 | 2004-05-04 | Akzo Nobel N.V. | Aqueous silica dispersion |
DE60332955D1 (de) | 2002-12-20 | 2010-07-22 | Akzo Nobel Nv | Verfahren und vorrichtung zum vorschäumen von thermoplastischen mikrokugeln |
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2021
- 2021-04-01 BR BR112022018748A patent/BR112022018748A2/pt unknown
- 2021-04-01 US US17/995,157 patent/US20230174734A1/en active Pending
- 2021-04-01 CN CN202180022355.9A patent/CN115297959A/zh active Pending
- 2021-04-01 JP JP2022559798A patent/JP2023519741A/ja active Pending
- 2021-04-01 EP EP21715657.9A patent/EP4126334A1/en active Pending
- 2021-04-01 KR KR1020227032982A patent/KR20220136467A/ko unknown
- 2021-04-01 WO PCT/EP2021/058762 patent/WO2021198492A1/en active Application Filing
Also Published As
Publication number | Publication date |
---|---|
WO2021198492A1 (en) | 2021-10-07 |
CN115297959A (zh) | 2022-11-04 |
EP4126334A1 (en) | 2023-02-08 |
JP2023519741A (ja) | 2023-05-12 |
US20230174734A1 (en) | 2023-06-08 |
KR20220136467A (ko) | 2022-10-07 |
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