BR112022018748A2 - Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas - Google Patents

Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas

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Publication number
BR112022018748A2
BR112022018748A2 BR112022018748A BR112022018748A BR112022018748A2 BR 112022018748 A2 BR112022018748 A2 BR 112022018748A2 BR 112022018748 A BR112022018748 A BR 112022018748A BR 112022018748 A BR112022018748 A BR 112022018748A BR 112022018748 A2 BR112022018748 A2 BR 112022018748A2
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BR
Brazil
Prior art keywords
polymeric microspheres
thermoplastic polymeric
alkyl
halogen
thermoplastic polymer
Prior art date
Application number
BR112022018748A
Other languages
English (en)
Inventor
Larsson-Kron Anna
Zasadowski Dariusz
Original Assignee
Nouryon Chemicals Int Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nouryon Chemicals Int Bv filed Critical Nouryon Chemicals Int Bv
Publication of BR112022018748A2 publication Critical patent/BR112022018748A2/pt

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02Making microcapsules or microballoons
    • B01J13/06Making microcapsules or microballoons by phase separation
    • B01J13/14Polymerisation; cross-linking
    • B01J13/16Interfacial polymerisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B16/00Use of organic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of organic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B16/04Macromolecular compounds
    • C04B16/08Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons
    • C04B16/082Macromolecular compounds porous, e.g. expanded polystyrene beads or microballoons other than polystyrene based, e.g. polyurethane foam
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • C04B38/0615Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances the burned-out substance being a monolitic element having approximately the same dimensions as the final article, e.g. a porous polyurethane sheet or a prepreg obtained by bonding together resin particles
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • C08J3/03Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • C08J9/18Making expandable particles by impregnating polymer particles with the blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/32Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00Use of pretreated ingredients
    • C08K9/10Encapsulated ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/22Expandable microspheres, e.g. Expancel®
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2343/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Structural Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

A invenção refere-se a microesferas poliméricas termoplásticas que compreendem uma casca de polímero termoplástico em torno de um núcleo oco, em que a casca de polímero termoplástico compreende um copolímero de um monômero da Fórmula 1, em que: cada um dentre A1 a A11 é independentemente selecionado dentre H e C1 a C4 alquil, em que cada grupo C1-4 alquil pode opcionalmente ser substituído por um ou mais substituintes selecionados dentre halogênio, hidróxi e C1-4 alcóxi; A12 é selecionado dentre C1 a C4 alquil, em que o grupo C1-4 alquil pode opcionalmente ser substituído por um ou mais substituintes selecionados dentre halogênio, hidróxi e C1-4 alcóxi; X é um grupo de ligação selecionado dentre -O-, -NR-, -S-, -OC(O)-, -NRC(O)-, -SC(O)-, -C(O)O-, -C(O)NR- e -C(O)S-; e R é H ou C1-2 alquil opcionalmente substituído por um ou mais substituintes selecionados dentre halogênio e hidroxila; em que a casca do polímero termoplástico compreende um ou mais outros co-monômeros etilenicamente insaturados não da Fórmula 1 tendo não mais que uma ligação dupla C=C não aromática, pelo menos um dos quais é um monômero contendo nitrila; o teor do monômero contendo nitrila no copolímero sendo maior que 20% em peso.
BR112022018748A 2020-04-03 2021-04-01 Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas BR112022018748A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP20168101 2020-04-03
PCT/EP2021/058762 WO2021198492A1 (en) 2020-04-03 2021-04-01 Thermally expandable microspheres prepared from bio-based monomers

Publications (1)

Publication Number Publication Date
BR112022018748A2 true BR112022018748A2 (pt) 2022-11-01

Family

ID=70285426

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112022018748A BR112022018748A2 (pt) 2020-04-03 2021-04-01 Microesferas poliméricas termoplásticas, processo para preparar microesferas poliméricas termoplásticas, método para produção de microesferas poliméricas termoplásticas expandidas, e uso das microesferas poliméricas termoplásticas

Country Status (7)

Country Link
US (1) US20230174734A1 (pt)
EP (1) EP4126334A1 (pt)
JP (1) JP2023519741A (pt)
KR (1) KR20220136467A (pt)
CN (1) CN115297959A (pt)
BR (1) BR112022018748A2 (pt)
WO (1) WO2021198492A1 (pt)

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US475213A (en) 1892-05-17 William fraser
US2838523A (en) 1954-06-10 1958-06-10 Quaker Oats Co Production of tetrahydrofurfuryl alcohol
US3007878A (en) 1956-11-01 1961-11-07 Du Pont Aquasols of positively-charged coated silica particles and their production
US3139406A (en) 1960-10-12 1964-06-30 Nalco Chemical Co Method of producing hydrous metal oxide sols
US3252917A (en) 1962-08-27 1966-05-24 Nalco Chemical Co Method of producing alumina-coated silica in sol form
DE1468932B2 (de) 1965-09-23 1976-01-22 Röhm GmbH, 6100 Darmstadt Verfahren zur kontinuierlichen herstellung von niedermolekularen aliphatischen acrylsaeureestern
US3615972A (en) 1967-04-28 1971-10-26 Dow Chemical Co Expansible thermoplastic polymer particles containing volatile fluid foaming agent and method of foaming the same
US3620978A (en) 1968-07-18 1971-11-16 Du Pont Process for preparing stable positively charged alumina-coated silica sols
US3719607A (en) 1971-01-29 1973-03-06 Du Pont Stable positively charged alumina coated silica sols and their preparation by postneutralization
US3745126A (en) 1971-04-22 1973-07-10 Du Pont Stable positively charged alumina coated silica sols
US3864142A (en) 1971-04-26 1975-02-04 Nalco Chemical Co Metal oxide sols
US3956171A (en) 1973-07-30 1976-05-11 E. I. Du Pont De Nemours And Company Process for preparing stable positively charged alumina coated silica sols and product thereof
US3945956A (en) 1975-06-23 1976-03-23 The Dow Chemical Company Polymerization of styrene acrylonitrile expandable microspheres
JPS6021770B2 (ja) 1980-02-14 1985-05-29 松本油脂製薬株式会社 熱膨張性マイクロカプセルの製造法
ATE101823T1 (de) 1988-06-23 1994-03-15 Casco Nobel Ab Verfahren und vorrichtung zur herstellung expandierbarer thermoplastischer mikrokugeln.
JP2727618B2 (ja) 1989-01-26 1998-03-11 三菱瓦斯化学株式会社 不飽和カルボン酸エステルの製造方法
SE9003600L (sv) 1990-11-12 1992-05-13 Casco Nobel Ab Expanderbara termoplastiska mikrosfaerer samt foerfarande foer framstaellning daerav
JP3659979B2 (ja) 1992-04-15 2005-06-15 松本油脂製薬株式会社 熱膨張性マイクロカプセルとその製法
AU3996800A (en) 1998-12-10 2000-07-12 Zms, Llc Expandable polymeric microspheres, their method of production, and uses and products thereof
US6509384B2 (en) 2000-04-28 2003-01-21 Akzo Nobel N.V. Chemical product and method
CN1280088C (zh) * 2000-09-06 2006-10-18 阿普尔顿纸张公司 原位微胶囊化胶粘剂
AU2003265192A1 (en) 2002-10-14 2004-05-04 Akzo Nobel N.V. Aqueous silica dispersion
DE60332955D1 (de) 2002-12-20 2010-07-22 Akzo Nobel Nv Verfahren und vorrichtung zum vorschäumen von thermoplastischen mikrokugeln
CN100354346C (zh) 2003-02-11 2007-12-12 阿克佐诺贝尔公司 微球体
US20040249005A1 (en) * 2003-02-11 2004-12-09 Anna Kron Microspheres
US7368167B2 (en) 2004-06-17 2008-05-06 Henkel Corporation Ultra low density thermally clad microspheres and method of making same
RU2432201C2 (ru) 2006-02-10 2011-10-27 Акцо Нобель Н.В. Микросферы
FR2914631B1 (fr) 2007-04-06 2009-07-03 Eads Europ Aeronautic Defence Materiau nanostructure particulier, comme revetement protecteur de surfaces metalliques.
PL2686388T3 (pl) 2011-03-14 2017-08-31 Akzo Nobel Chemicals International B.V. Modyfikowane cząstki krzemionki
WO2014152366A1 (en) 2013-03-14 2014-09-25 Pronghorn Renewables Llc Method and catalyst for the production of alcohols, diols, cyclic ethers and other products from pentose and hexose sugars
JP6082848B2 (ja) 2014-05-23 2017-02-15 松本油脂製薬株式会社 熱膨張性微小球、その製造方法および用途
BR112018075607B1 (pt) 2016-07-14 2022-08-30 Akzo Nobel Chemicals International B.V Processo para a fabricação de microesferas termoplásticas termicamente expansíveis, processo para produção de microesferas expandidas, microesferas termoplásticas termicamente expansíveis obteníveis pelo processo, microesferas expandidas, produto fabricado, e uso de uma sílica coloidal que é modificada pela superfície com pelo menos grupos organossilanos hidrofóbicos
WO2018213050A1 (en) 2017-05-15 2018-11-22 Saudi Arabian Oil Company Composition and method for water and gas shut-off in subterranean formations
US11332595B2 (en) 2017-09-04 2022-05-17 Nouryon Chemicals International B.V. Thermally expandable microspheres prepared from bio-based monomers
CN111051462B (zh) * 2017-09-06 2023-02-17 日油株式会社 热膨胀性微胶囊、其制造方法及发泡成型品
CN111315473B (zh) 2017-11-21 2022-01-11 诺力昂化学品国际有限公司 由生物基单体制备的可热膨胀微球
CN108097182B (zh) * 2018-01-05 2021-08-20 三明市锦浪新材料科技有限公司 一种超细环保热膨胀微胶囊及其制备方法

Also Published As

Publication number Publication date
WO2021198492A1 (en) 2021-10-07
CN115297959A (zh) 2022-11-04
EP4126334A1 (en) 2023-02-08
JP2023519741A (ja) 2023-05-12
US20230174734A1 (en) 2023-06-08
KR20220136467A (ko) 2022-10-07

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