BR112021018201A2 - Sistema catalisador para produzir polímeros de olefina sem sólidos finos - Google Patents

Sistema catalisador para produzir polímeros de olefina sem sólidos finos

Info

Publication number
BR112021018201A2
BR112021018201A2 BR112021018201A BR112021018201A BR112021018201A2 BR 112021018201 A2 BR112021018201 A2 BR 112021018201A2 BR 112021018201 A BR112021018201 A BR 112021018201A BR 112021018201 A BR112021018201 A BR 112021018201A BR 112021018201 A2 BR112021018201 A2 BR 112021018201A2
Authority
BR
Brazil
Prior art keywords
catalyst system
olefin polymers
fine solids
produce olefin
polymers
Prior art date
Application number
BR112021018201A
Other languages
English (en)
Inventor
Van Egmond Jan
Lee VAN PELT Stephen
Original Assignee
Grace W R & Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Grace W R & Co filed Critical Grace W R & Co
Publication of BR112021018201A2 publication Critical patent/BR112021018201A2/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/646Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
    • C08F4/6465Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/04Dual catalyst, i.e. use of two different catalysts, where none of the catalysts is a metallocene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/647Catalysts containing a specific non-metal or metal-free compound
    • C08F4/649Catalysts containing a specific non-metal or metal-free compound organic
    • C08F4/6494Catalysts containing a specific non-metal or metal-free compound organic containing oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

sistema catalisador para produzir polímeros de olefina sem sólidos finos. os polímeros de olefina são produzidos tendo uma densidade aparente relativamente alta e uma quantidade dramaticamente reduzida de sólidos finos. os polímeros são produzidos com o uso de um sistema catalisador contendo um agente controlador de seletividade. em uma modalidade, o agente controlador de seletividade é di-isobutildimetoxissilano.
BR112021018201A 2019-03-15 2020-03-13 Sistema catalisador para produzir polímeros de olefina sem sólidos finos BR112021018201A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201962818925P 2019-03-15 2019-03-15
PCT/US2020/022556 WO2020190681A1 (en) 2019-03-15 2020-03-13 Catalyst system for producing olefin polymers with no fines

Publications (1)

Publication Number Publication Date
BR112021018201A2 true BR112021018201A2 (pt) 2021-11-16

Family

ID=72520427

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112021018201A BR112021018201A2 (pt) 2019-03-15 2020-03-13 Sistema catalisador para produzir polímeros de olefina sem sólidos finos

Country Status (9)

Country Link
US (1) US20220144975A1 (pt)
EP (1) EP3938097A4 (pt)
JP (1) JP2022525628A (pt)
KR (1) KR20210135291A (pt)
CN (1) CN113573806A (pt)
BR (1) BR112021018201A2 (pt)
CA (1) CA3132862A1 (pt)
CO (1) CO2021012664A2 (pt)
WO (1) WO2020190681A1 (pt)

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1097596C (zh) * 1998-12-30 2003-01-01 中国石油化工集团公司 一种使聚丙烯等规度易调的催化剂及其活性组份的制法和该催化剂的应用
US7491670B2 (en) * 2003-09-23 2009-02-17 Dow Global Technologies Inc. Self limiting catalyst composition and propylene polymerization process
MX2010002118A (es) * 2007-08-24 2010-08-09 Dow Global Technologies Inc Sistema de catalizador auto-limitante con proporcion de aluminio a sca controlada y metodo.
BR112014011600A2 (pt) * 2011-11-15 2017-05-30 W R Grace & Co -Conn método para polimerização de polipropileno
CN104558312B (zh) * 2013-10-25 2017-07-28 中国石油化工股份有限公司 一种烯烃聚合物的制备方法及其聚合物
CN106459285B (zh) * 2014-06-20 2019-05-21 Sabic环球技术有限责任公司 用于聚合丙烯的方法
US9714302B2 (en) * 2014-10-10 2017-07-25 W. R. Grace & Co.—Conn. Process for preparing spherical polymerization catalyst components for use in olefin polymerizations
CN107698698B (zh) 2017-09-30 2020-02-07 营口市向阳催化剂有限责任公司 一种用于α-烯烃聚合含自调节活性的外给电子体的催化剂及其应用

Also Published As

Publication number Publication date
CO2021012664A2 (es) 2021-10-20
CN113573806A (zh) 2021-10-29
JP2022525628A (ja) 2022-05-18
EP3938097A4 (en) 2022-11-30
US20220144975A1 (en) 2022-05-12
WO2020190681A1 (en) 2020-09-24
KR20210135291A (ko) 2021-11-12
EP3938097A1 (en) 2022-01-19
CA3132862A1 (en) 2020-09-24

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