BR112019016276A8 - Composição de catalisador de ácido fosfórico sólido e seu método de preparação, bem como método para converter hidrocarbonetos - Google Patents

Composição de catalisador de ácido fosfórico sólido e seu método de preparação, bem como método para converter hidrocarbonetos

Info

Publication number
BR112019016276A8
BR112019016276A8 BR112019016276A BR112019016276A BR112019016276A8 BR 112019016276 A8 BR112019016276 A8 BR 112019016276A8 BR 112019016276 A BR112019016276 A BR 112019016276A BR 112019016276 A BR112019016276 A BR 112019016276A BR 112019016276 A8 BR112019016276 A8 BR 112019016276A8
Authority
BR
Brazil
Prior art keywords
phosphoric acid
source
solid phosphoric
preparation
composition
Prior art date
Application number
BR112019016276A
Other languages
English (en)
Other versions
BR112019016276A2 (pt
Inventor
Turbeville Wayne
Korynta Greg
Hogue Peter
Shen Wenqin
Born Marc
Tolle David
Severance Michael
Dueker Axel
Original Assignee
Clariant Corp
Clariant Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Corp, Clariant Int Ltd filed Critical Clariant Corp
Publication of BR112019016276A2 publication Critical patent/BR112019016276A2/pt
Publication of BR112019016276A8 publication Critical patent/BR112019016276A8/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/16Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14Phosphorus; Compounds thereof
    • B01J27/182Phosphorus; Compounds thereof with silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/37Crush or impact strength
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/34Mechanical properties
    • B01J35/38Abrasion or attrition resistance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/14Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/18Acids of phosphorus; Salts thereof; Phosphorus oxides
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A presente invenção refere-se a composições catalíticas de ácido fosfórico sólido (SPA) úteis na formação de hidrocarbonetos, como na oligomerização de olefinas, preparadas a partir de misturas moldáveis que compreendem uma fonte de fosfato e uma fonte de material - suporte silicioso, por exemplo, de tal forma que a razão da fonte de fosfato e da fonte de material -suporte silicioso fica na faixa de cerca de 2,9: 1 a cerca de 3,4: 1 calculada em base peso como H3PO4: SiO2, e um material particulado seco.
BR112019016276A 2017-03-12 2018-03-09 Composição de catalisador de ácido fosfórico sólido e seu método de preparação, bem como método para converter hidrocarbonetos BR112019016276A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762470313P 2017-03-12 2017-03-12
PCT/US2018/021678 WO2018169774A1 (en) 2017-03-12 2018-03-09 Solid phosphoric acid catalysts

Publications (2)

Publication Number Publication Date
BR112019016276A2 BR112019016276A2 (pt) 2020-04-07
BR112019016276A8 true BR112019016276A8 (pt) 2022-08-30

Family

ID=61827825

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112019016276A BR112019016276A8 (pt) 2017-03-12 2018-03-09 Composição de catalisador de ácido fosfórico sólido e seu método de preparação, bem como método para converter hidrocarbonetos

Country Status (9)

Country Link
US (1) US20190374930A1 (pt)
EP (1) EP3595809A1 (pt)
JP (2) JP7100054B2 (pt)
KR (1) KR20190127680A (pt)
CN (1) CN110382113B (pt)
BR (1) BR112019016276A8 (pt)
CA (1) CA3051454A1 (pt)
WO (1) WO2018169774A1 (pt)
ZA (1) ZA201904802B (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116212906B (zh) * 2022-12-05 2023-12-22 中国人民解放军军事科学院系统工程研究院 一种磷酸化固载二元催化剂、其制备方法和应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2824149A (en) * 1951-07-31 1958-02-18 Exxon Research Engineering Co Olefin polymerization catalyst and process
US5059737A (en) * 1988-12-23 1991-10-22 Uop Catalytic condensation process
JPH0829251B2 (ja) * 1990-03-26 1996-03-27 ユーオーピー 多孔質固体リン酸触媒及びそれを使用する方法
CN1026556C (zh) * 1990-12-21 1994-11-16 齐鲁石油化工公司研究院 废旧烃类蒸汽转化催化剂的回收复用方法
CN1078494C (zh) 1998-01-06 2002-01-30 北京燕山石油化工公司研究院 固体磷酸催化剂的制造方法
JP3763246B2 (ja) * 2000-04-06 2006-04-05 住友化学株式会社 ヘテロポリ酸系触媒の再生方法およびメタクリル酸の製造方法
US7557060B2 (en) 2007-06-29 2009-07-07 Sud-Chemie Inc. Solid phosphoric acid with controlled porosity
US9403149B2 (en) 2011-09-21 2016-08-02 Clariant Corpoation Promoted solid phosphoric acid catalysts and methods of use

Also Published As

Publication number Publication date
JP2020509931A (ja) 2020-04-02
RU2019132127A (ru) 2021-04-14
ZA201904802B (en) 2021-03-31
CA3051454A1 (en) 2018-09-20
JP2022088530A (ja) 2022-06-14
WO2018169774A1 (en) 2018-09-20
KR20190127680A (ko) 2019-11-13
RU2019132127A3 (pt) 2021-05-18
CN110382113B (zh) 2023-03-31
BR112019016276A2 (pt) 2020-04-07
EP3595809A1 (en) 2020-01-22
US20190374930A1 (en) 2019-12-12
JP7100054B2 (ja) 2022-07-12
CN110382113A (zh) 2019-10-25

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Legal Events

Date Code Title Description
B350 Update of information on the portal [chapter 15.35 patent gazette]
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B25A Requested transfer of rights approved

Owner name: CLARIANT INTERNATIONAL LTD (CH)

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]