BR112018076933A2 - processo de oxidação - Google Patents
processo de oxidaçãoInfo
- Publication number
- BR112018076933A2 BR112018076933A2 BR112018076933-9A BR112018076933A BR112018076933A2 BR 112018076933 A2 BR112018076933 A2 BR 112018076933A2 BR 112018076933 A BR112018076933 A BR 112018076933A BR 112018076933 A2 BR112018076933 A2 BR 112018076933A2
- Authority
- BR
- Brazil
- Prior art keywords
- oxidation process
- caustics
- vapor
- maintained
- gas phase
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/10—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of metal-containing organic complexes, e.g. chelates, or cationic ion-exchange resins
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/242—Tubular reactors in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/32—Packing elements in the form of grids or built-up elements for forming a unit or module inside the apparatus for mass or heat transfer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D1/00—Oxides or hydroxides of sodium, potassium or alkali metals in general
- C01D1/04—Hydroxides
- C01D1/28—Purification; Separation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/08—Recovery of used refining agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/06—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen in the presence of alkaline solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/19—Details relating to the geometry of the reactor
- B01J2219/194—Details relating to the geometry of the reactor round
- B01J2219/1941—Details relating to the geometry of the reactor round circular or disk-shaped
- B01J2219/1943—Details relating to the geometry of the reactor round circular or disk-shaped cylindrical
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/24—Stationary reactors without moving elements inside
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4056—Retrofitting operations
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
é revelado um processo para a remoção de compostos de enxofre residuais a partir de produtos cáusticos líquidos ricos, em que uma única coluna contendo duas zonas de reação oxida cataliticamente mercaptanos para óleos de dissulfeto. a segunda zona de reação utiliza um feixe de fibras suspensas verticais e é mantida como uma fase contínua de gás que compreende de cerca de 20% a cerca de 100% em volume de vapor. este processo é especialmente útil como parte de um esquema de fluxo de processo de dessulfurização de hidrocarbonetos.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15/189,154 US10059889B2 (en) | 2016-06-22 | 2016-06-22 | Oxidation process |
US15/189,154 | 2016-06-22 | ||
PCT/US2017/036734 WO2017222830A1 (en) | 2016-06-22 | 2017-06-09 | Oxidation process |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018076933A2 true BR112018076933A2 (pt) | 2019-04-02 |
BR112018076933B1 BR112018076933B1 (pt) | 2022-05-03 |
Family
ID=59091612
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018076933-9A BR112018076933B1 (pt) | 2016-06-22 | 2017-06-09 | Método de oxidação de mercaptanos para óleo de dissulfeto, método para regenerar uma solução cáustica e reator de oxidação |
Country Status (10)
Country | Link |
---|---|
US (2) | US10059889B2 (pt) |
EP (1) | EP3475394B1 (pt) |
JP (2) | JP6748236B2 (pt) |
KR (1) | KR102252216B1 (pt) |
CN (2) | CN113308267B (pt) |
BR (1) | BR112018076933B1 (pt) |
CA (1) | CA3028362C (pt) |
MX (1) | MX2018015901A (pt) |
RU (2) | RU2697871C1 (pt) |
WO (1) | WO2017222830A1 (pt) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10456711B1 (en) | 2018-11-29 | 2019-10-29 | Merichem Company | Liquid-liquid mass transfer process and apparatus |
US10888818B2 (en) * | 2019-01-15 | 2021-01-12 | Honeywell International Inc. | Integrated mercaptan extraction and/or sweetening processes combined with thermal oxidation and flue gas treatment |
CN110387254A (zh) * | 2019-07-08 | 2019-10-29 | 宁波章甫能源科技有限公司 | 一种煤制油脱硫脱臭系统及其方法 |
US11198107B2 (en) | 2019-09-05 | 2021-12-14 | Visionary Fiber Technologies, Inc. | Conduit contactor and method of using the same |
US11826736B2 (en) | 2021-11-29 | 2023-11-28 | Merichem Company | Catalytic carbon fiber preparation methods |
US11517889B2 (en) | 2020-12-21 | 2022-12-06 | Merichem Company | Catalytic carbon fiber contactor |
US11524283B2 (en) | 2020-12-21 | 2022-12-13 | Merichem Company | Catalytic carbon fiber preparation methods |
US11692145B1 (en) | 2022-05-10 | 2023-07-04 | Pall Corporation | Method and system for purifying a caustic fluid including sulfur |
CN116445183A (zh) * | 2023-03-14 | 2023-07-18 | 中国石油化工股份有限公司 | 一种射流混合强化废碱液氧化的反应装置及方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3758404A (en) | 1971-07-09 | 1973-09-11 | Merichem Co | Liquid liquid mass transfer process and apparatus |
US3977829A (en) | 1973-05-18 | 1976-08-31 | Merichem Company | Liquid-liquid mass transfer apparatus |
US3992156A (en) | 1975-07-23 | 1976-11-16 | Merichem Company | Mass transfer apparatus |
US4666689A (en) * | 1984-04-26 | 1987-05-19 | Merichem Company | Process for regenerating an alkaline stream containing mercaptan compounds |
US4675100A (en) * | 1985-05-30 | 1987-06-23 | Merichem Company | Treatment of sour hydrocarbon distillate |
US5935422A (en) | 1997-12-29 | 1999-08-10 | Uop Llc | Removal of organic sulfur compounds from FCC gasoline using regenerable adsorbents |
US7148389B2 (en) | 2001-09-04 | 2006-12-12 | The Regents Of The University Of Michigan | Selective sorbents for purification of hydrocartons |
US7063732B2 (en) | 2003-07-28 | 2006-06-20 | Fuelcell Energy, Inc. | High-capacity sulfur adsorbent bed and gas desulfurization method |
US7093433B2 (en) | 2003-10-24 | 2006-08-22 | Tesmic Spa | Laying apparatus for cables, lines, conductors or suchlike, and relative laying method |
US8308957B2 (en) * | 2007-06-14 | 2012-11-13 | Merichem Company | Process for separating mercaptans from caustic |
CN101928596B (zh) * | 2009-06-20 | 2014-03-26 | 中国石油化工集团公司 | 一种非临氢法生产清洁溶剂油的方法 |
US8900446B2 (en) * | 2009-11-30 | 2014-12-02 | Merichem Company | Hydrocarbon treatment process |
US9656185B2 (en) * | 2012-07-11 | 2017-05-23 | Merichem Company | Contactor and separation apparatus and process of using same |
US9328294B2 (en) * | 2012-09-04 | 2016-05-03 | Uop Llc | Process and apparatus for extracting sulfur compounds in a hydrocarbon stream |
-
2016
- 2016-06-22 US US15/189,154 patent/US10059889B2/en active Active
-
2017
- 2017-06-09 CA CA3028362A patent/CA3028362C/en active Active
- 2017-06-09 RU RU2018146605A patent/RU2697871C1/ru active
- 2017-06-09 CN CN202110609175.2A patent/CN113308267B/zh active Active
- 2017-06-09 BR BR112018076933-9A patent/BR112018076933B1/pt active IP Right Grant
- 2017-06-09 KR KR1020197001323A patent/KR102252216B1/ko active IP Right Grant
- 2017-06-09 EP EP17731716.1A patent/EP3475394B1/en active Active
- 2017-06-09 JP JP2018566277A patent/JP6748236B2/ja active Active
- 2017-06-09 CN CN201780038976.XA patent/CN109415636B/zh active Active
- 2017-06-09 WO PCT/US2017/036734 patent/WO2017222830A1/en unknown
- 2017-06-09 MX MX2018015901A patent/MX2018015901A/es unknown
- 2017-06-09 RU RU2019125695A patent/RU2716259C2/ru active
-
2018
- 2018-07-02 US US16/025,790 patent/US10336949B2/en active Active
-
2020
- 2020-06-26 JP JP2020110218A patent/JP6913214B2/ja active Active
Also Published As
Publication number | Publication date |
---|---|
US20170369790A1 (en) | 2017-12-28 |
CA3028362C (en) | 2023-08-22 |
JP2020180290A (ja) | 2020-11-05 |
RU2019125695A (ru) | 2019-09-03 |
US10059889B2 (en) | 2018-08-28 |
BR112018076933B1 (pt) | 2022-05-03 |
CN109415636B (zh) | 2021-06-08 |
RU2716259C2 (ru) | 2020-03-11 |
WO2017222830A1 (en) | 2017-12-28 |
CN113308267B (zh) | 2022-09-06 |
RU2697871C1 (ru) | 2019-08-21 |
RU2019125695A3 (pt) | 2019-12-04 |
CA3028362A1 (en) | 2017-12-28 |
JP6748236B2 (ja) | 2020-08-26 |
KR102252216B1 (ko) | 2021-05-14 |
CN113308267A (zh) | 2021-08-27 |
JP6913214B2 (ja) | 2021-08-04 |
US20180312762A1 (en) | 2018-11-01 |
JP2019524912A (ja) | 2019-09-05 |
EP3475394A1 (en) | 2019-05-01 |
CN109415636A (zh) | 2019-03-01 |
EP3475394B1 (en) | 2022-09-21 |
US10336949B2 (en) | 2019-07-02 |
KR20190018505A (ko) | 2019-02-22 |
MX2018015901A (es) | 2019-03-28 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B06W | Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/06/2017, OBSERVADAS AS CONDICOES LEGAIS. |