BR112018067886A2 - processo de adsorção com modulação de temperatura - Google Patents

processo de adsorção com modulação de temperatura

Info

Publication number
BR112018067886A2
BR112018067886A2 BR112018067886A BR112018067886A BR112018067886A2 BR 112018067886 A2 BR112018067886 A2 BR 112018067886A2 BR 112018067886 A BR112018067886 A BR 112018067886A BR 112018067886 A BR112018067886 A BR 112018067886A BR 112018067886 A2 BR112018067886 A2 BR 112018067886A2
Authority
BR
Brazil
Prior art keywords
target component
adsorbent
stream
adsorption
produced
Prior art date
Application number
BR112018067886A
Other languages
English (en)
Other versions
BR112018067886B1 (pt
Inventor
Joss Lisa
Mazzotti Marco
Gazzani Matteo
Original Assignee
Casale Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Casale Sa filed Critical Casale Sa
Publication of BR112018067886A2 publication Critical patent/BR112018067886A2/pt
Publication of BR112018067886B1 publication Critical patent/BR112018067886B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/0462—Temperature swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/104—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/40045—Purging with two sub-steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40043—Purging
    • B01D2259/4005—Nature of purge gas
    • B01D2259/40052—Recycled product or process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
    • B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
    • B01D2259/40064—Five
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/403—Further details for adsorption processes and devices using three beds
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Treating Waste Gases (AREA)

Abstract

a invenção refere-se a um processo de adsorção com modulação de temperatura (tsa) para remover um componente alvo de uma mistura de gás (111), sendo o referido processo implementado numa pluralidade de reatores (101, 102, 103), em que cada um dos reatores (101) executa as seguintes etapas: uma etapa de adsorção (a) em que uma corrente de entrada (111) da referida mistura gasosa é colocada em contato com um adsorvente sólido seletivo para o dito componente alvo, de modo a produzir uma primeira corrente de resíduos (112) desprovida do componente alvo; uma etapa de aquecimento (b) para a regeneração do adsorvente introduzido, de modo a produzir uma primeira corrente de saída (115) que contém o componente alvo; uma etapa de resfriamento (c) do adsorvente regenerado, o referido método de tsa compreendendo ainda: i) uma etapa de pré-resfriamento (b1) antes da dita etapa de resfriamento (c), em que o adsorvente regenerado é colocado em contato com uma corrente de resíduos (137), que é produzida pela etapa de adsorção (a) de outro reator (103), e uma segunda corrente de saída (116) do componente alvo é produzida; ii) uma etapa de pré-aquecimento (a1) após a referida etapa de adsorção (a) e antes da dita etapa de aquecimento (b), em que o adsorvente introduzido é colocado em contato com uma corrente de lavagem (126), que é produzida pela etapa de pré-resfriamento de outro reator (102).
BR112018067886-4A 2016-03-08 2017-03-07 Processo de adsorção com modulação de temperatura BR112018067886B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP16159248.0 2016-03-08
EP16159248.0A EP3216511A1 (en) 2016-03-08 2016-03-08 A temperature-swing adsorption process
EP16171370.6 2016-05-25
EP16171370.6A EP3216513A1 (en) 2016-03-08 2016-05-25 A temperature-swing adsorption process
PCT/EP2017/055285 WO2017153385A1 (en) 2016-03-08 2017-03-07 A temperature-swing adsorption process

Publications (2)

Publication Number Publication Date
BR112018067886A2 true BR112018067886A2 (pt) 2019-01-08
BR112018067886B1 BR112018067886B1 (pt) 2022-12-06

Family

ID=55527321

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112018067886-4A BR112018067886B1 (pt) 2016-03-08 2017-03-07 Processo de adsorção com modulação de temperatura

Country Status (11)

Country Link
US (1) US10874974B2 (pt)
EP (3) EP3216511A1 (pt)
JP (1) JP6763979B2 (pt)
CN (1) CN108367230B (pt)
AU (1) AU2017229270B2 (pt)
BR (1) BR112018067886B1 (pt)
CA (1) CA3004186C (pt)
CL (1) CL2018002551A1 (pt)
RU (1) RU2737887C2 (pt)
SA (1) SA518391719B1 (pt)
WO (1) WO2017153385A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3216512A1 (en) * 2016-03-08 2017-09-13 Casale SA A temperature-swing adsorption process
EP3449997A1 (en) * 2017-08-28 2019-03-06 Casale Sa A temperature-swing adsorption process
EP3449996A1 (en) * 2017-08-28 2019-03-06 Casale Sa A temperature-swing adsorption process

Family Cites Families (24)

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US5298054A (en) * 1990-10-01 1994-03-29 Fmc Corporation Pressure and temperature swing adsorption system
ATE139460T1 (de) * 1990-10-01 1996-07-15 Fmc Corp Druck- und temperaturwechseladsorptionsvorrichtung
US6592836B2 (en) * 2001-02-02 2003-07-15 Jeffrey Raymond Hufton Production of carbon monoxide
US20030037672A1 (en) * 2001-08-27 2003-02-27 Shivaji Sircar Rapid thermal swing adsorption
GB0216914D0 (en) 2002-07-19 2002-08-28 Air Prod & Chem Process and apparatus for treating a feed gas
DE102005032025A1 (de) 2005-07-08 2007-01-18 Linde Ag Verfahren zur adsorptiven Entfernung von Spurenkomponenten
US7744677B2 (en) * 2007-05-25 2010-06-29 Prometheus Technologies, Llc Systems and methods for processing methane and other gases
RU2363523C2 (ru) 2007-07-06 2009-08-10 Вячеслав Викторович Самонин Сорбирующая система, включающая теплопроводящий элемент
EA016640B1 (ru) * 2008-02-04 2012-06-29 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ регенерации слоев адсорбента
CN101530718A (zh) * 2008-03-13 2009-09-16 郭永义 变温变压吸附分离f-t合成循环气中轻烃工艺
CA2726383C (en) * 2008-04-06 2015-08-25 Innosepra Llc Carbon dioxide recovery
US9295939B2 (en) * 2008-04-06 2016-03-29 Innosepra Llc Carbon dioxide recovery
CN100595263C (zh) 2008-04-22 2010-03-24 成都五环新锐化工有限公司 从富含甲烷的混合气体中生产液化天然气的前端组合净化工艺
US8936727B2 (en) * 2009-03-06 2015-01-20 Uop Llc Multiple bed temperature controlled adsorption
DE102008062387A1 (de) 2008-12-17 2010-07-01 Uhde Gmbh Verfahren zur Reinigung von technischen Gasen und Gewinnung von Sauergasen
BRPI1015533A2 (pt) * 2009-04-24 2018-01-16 Univation Tech Llc regeneração de leitos de purificação com um compressor a jato em um ciclo de laço aberto
JP5904420B2 (ja) * 2010-08-27 2016-04-13 インヴェンティス サーマル テクノロジーズ インコーポレイテッド 熱伝導性接触器構造を用いる吸着ガス分離の方法
JP2013132582A (ja) * 2011-12-26 2013-07-08 Toyobo Co Ltd 有機溶剤含有ガス処理システム
US8778050B2 (en) * 2012-02-01 2014-07-15 Basf Corporation Heavy hydrocarbon removal process
EP2638949A1 (en) 2012-03-13 2013-09-18 Ammonia Casale S.A. Process for removing carbon dioxide from a gas stream
US8936669B2 (en) * 2013-05-06 2015-01-20 Uop Llc Temperature swing adsorption systems and methods for purifying fluids using the same
WO2015117738A1 (de) * 2014-02-04 2015-08-13 Linde Aktiengesellschaft Verfahren zur herstellung höhermolekularer verbindungen aus synthesegas unter verwendung eines indirekt beheizten co2-tsa
EP3216512A1 (en) * 2016-03-08 2017-09-13 Casale SA A temperature-swing adsorption process
US10765991B2 (en) 2017-08-10 2020-09-08 Air Products And Chemicals, Inc. Rapid cycle pressure swing adsorption process and adsorbent laminates for use therein

Also Published As

Publication number Publication date
RU2737887C2 (ru) 2020-12-04
CA3004186C (en) 2023-10-03
US20190030479A1 (en) 2019-01-31
JP6763979B2 (ja) 2020-09-30
WO2017153385A1 (en) 2017-09-14
EP3426383B1 (en) 2019-11-13
CN108367230B (zh) 2021-02-19
RU2018134599A (ru) 2020-04-08
EP3216513A1 (en) 2017-09-13
CA3004186A1 (en) 2017-09-14
AU2017229270B2 (en) 2022-06-23
RU2018134599A3 (pt) 2020-04-08
CL2018002551A1 (es) 2018-12-07
EP3426383A1 (en) 2019-01-16
BR112018067886B1 (pt) 2022-12-06
US10874974B2 (en) 2020-12-29
SA518391719B1 (ar) 2021-07-28
EP3216511A1 (en) 2017-09-13
AU2017229270A1 (en) 2018-05-10
JP2019512390A (ja) 2019-05-16
CN108367230A (zh) 2018-08-03

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Legal Events

Date Code Title Description
B06W Patent application suspended after preliminary examination (for patents with searches from other patent authorities) chapter 6.23 patent gazette]
B350 Update of information on the portal [chapter 15.35 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 07/03/2017, OBSERVADAS AS CONDICOES LEGAIS