BR112018010358A2 - composição de xampu que compreende pelo menos um sal de amônio de oligoéster - Google Patents

composição de xampu que compreende pelo menos um sal de amônio de oligoéster

Info

Publication number
BR112018010358A2
BR112018010358A2 BR112018010358A BR112018010358A BR112018010358A2 BR 112018010358 A2 BR112018010358 A2 BR 112018010358A2 BR 112018010358 A BR112018010358 A BR 112018010358A BR 112018010358 A BR112018010358 A BR 112018010358A BR 112018010358 A2 BR112018010358 A2 BR 112018010358A2
Authority
BR
Brazil
Prior art keywords
ammonium salt
oligoester
certain
shampoo composition
oas
Prior art date
Application number
BR112018010358A
Other languages
English (en)
Inventor
Leinweber Dirk
Kita-Tokarczyk Katarzyna
Zoumpoulakis Nadine
Romanski Steffen
Platen Tobias
Original Assignee
Clariant Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR1657859A external-priority patent/FR3038835B3/fr
Priority claimed from FR1657858A external-priority patent/FR3038834B3/fr
Application filed by Clariant Int Ltd filed Critical Clariant Int Ltd
Publication of BR112018010358A2 publication Critical patent/BR112018010358A2/pt

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67—Vitamins
    • A61K8/678—Tocopherol, i.e. vitamin E
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/06—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having the hydroxy groups esterified by carboxylic acids having the esterifying carboxyl groups bound to hydrogen atoms or to acyclic carbon atoms of an acyclic saturated carbon skeleton

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

a presente invenção se refere, inter alia, às composições de xampu compreendendo um sal de amônio de oligoéster (oas) e um componente coméstico (f), onde o oas é obtido por: (i) aquecimento de uma mistura dos seguintes componentes (a) a (d) sob remoção contínua de água de reação: (a) um certo composto de dietanolamínio; (b) um certo ácido dicarboxílico; (c) um certo triol orgânico; e um ácido monocarboxílico de fórmula r1-cooh (d), em que r1 é c12-c24-alquila linear ou ramificada; (ii) reação do oligoéster de etapa (i) com um agente de quarternização.
BR112018010358A 2015-12-08 2016-12-07 composição de xampu que compreende pelo menos um sal de amônio de oligoéster BR112018010358A2 (pt)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP15198427 2015-12-08
EP16182521 2016-08-03
EP16182522 2016-08-03
FR1657859A FR3038835B3 (fr) 2015-12-08 2016-08-23 Composition de shampoing comprenant au moins un sel d'ammonium d'oligoester
FR1657858A FR3038834B3 (fr) 2015-12-08 2016-08-23 Sels d'ammonium d'oligoester et leur utilisation dans des compositions pour le conditionnement des cheveux
EP16198041 2016-11-09
PCT/EP2016/080031 WO2017097817A1 (en) 2015-12-08 2016-12-07 A shampoo composition comprising at least one oligoester ammonium salt

Publications (1)

Publication Number Publication Date
BR112018010358A2 true BR112018010358A2 (pt) 2018-12-04

Family

ID=59012657

Family Applications (3)

Application Number Title Priority Date Filing Date
BR112018010272-5A BR112018010272B1 (pt) 2015-12-08 2016-12-07 Método de preparação de uma composição cosmética, composição cosmética, composição de xampu, uso de um sal de amônio de oligoéster (oas) em composições cosméticas e método de tratamento de cabelo
BR112018010433A BR112018010433A8 (pt) 2015-12-08 2016-12-07 sais oligoéster de amônio e seu uso em composições para condicionamento dos cabelos
BR112018010358A BR112018010358A2 (pt) 2015-12-08 2016-12-07 composição de xampu que compreende pelo menos um sal de amônio de oligoéster

Family Applications Before (2)

Application Number Title Priority Date Filing Date
BR112018010272-5A BR112018010272B1 (pt) 2015-12-08 2016-12-07 Método de preparação de uma composição cosmética, composição cosmética, composição de xampu, uso de um sal de amônio de oligoéster (oas) em composições cosméticas e método de tratamento de cabelo
BR112018010433A BR112018010433A8 (pt) 2015-12-08 2016-12-07 sais oligoéster de amônio e seu uso em composições para condicionamento dos cabelos

Country Status (6)

Country Link
US (3) US20180360714A1 (pt)
EP (3) EP3386473B1 (pt)
JP (3) JP7144323B2 (pt)
CN (3) CN108391419A (pt)
BR (3) BR112018010272B1 (pt)
WO (3) WO2017097816A1 (pt)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11266587B2 (en) 2015-12-08 2022-03-08 Clariant International Ltd. Oligoester ammonium salts and their use in compositions for conditioning hair

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10543164B2 (en) 2017-06-30 2020-01-28 The Procter & Gamble Company Deodorant compositions
US11529299B2 (en) * 2017-06-30 2022-12-20 The Procter & Gamble Company Hair care compositions comprising a 2-pyridinol-n-oxide material and an iron chelator
EP3492068A1 (en) * 2017-12-01 2019-06-05 NCP NewCare Products GmbH Composition for treating onychomycosis
JP7358398B2 (ja) 2018-06-21 2023-10-10 ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ パーソナルクレンジング組成物
DE102018127280A1 (de) * 2018-10-31 2020-04-30 Henkel Ag & Co. Kgaa Wirkstoffzusammensetzung zur Depositionssteigerung von Antioxidantien
CN109575260B (zh) * 2018-11-30 2021-12-14 中建西部建设股份有限公司 一种季铵盐型混凝土抗泥剂及其制备方法
CN110368329B (zh) * 2019-08-22 2022-08-30 广州亦妆生物科技有限公司 一种不含硅油的均相护理组合物
GB2587402B (en) * 2019-09-27 2023-05-10 Hewlett Healthcare Ltd Formulation
WO2021101946A1 (en) * 2019-11-18 2021-05-27 Actera Ingredients, Inc. Hair treatments
US11273120B2 (en) 2019-11-18 2022-03-15 Actera Ingredients, Inc. Hair treatments
US11458084B2 (en) * 2020-02-28 2022-10-04 L'oreal Hair cleansing composition
WO2022040975A1 (en) * 2020-08-26 2022-03-03 Henkel Ag & Co. Kgaa Use of amido-tertiary amine in self-warming hair conditioner for improving conditioning effects, and self-warming hair conditioners
CN116322636A (zh) * 2020-09-30 2023-06-23 莱雅公司 用于调理和/或染色角蛋白纤维的组合物
EP4008406A1 (en) * 2020-12-07 2022-06-08 Clariant International Ltd Cosmetic composition based on acroyl taurate type polymers
US20230083646A1 (en) * 2021-08-25 2023-03-16 L'oreal Sulfate-free cleansing composition that confers high salicylic acid deposition
EP4144339A3 (en) 2021-09-03 2023-03-15 Clariant International Ltd Combinations of amido amine compounds and oligoester ammonium salts

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2809971A (en) 1955-11-22 1957-10-15 Olin Mathieson Heavy-metal derivatives of 1-hydroxy-2-pyridinethiones and method of preparing same
US3236733A (en) 1963-09-05 1966-02-22 Vanderbilt Co R T Method of combatting dandruff with pyridinethiones metal salts detergent compositions
US3761418A (en) 1967-09-27 1973-09-25 Procter & Gamble Detergent compositions containing particle deposition enhancing agents
US3753196A (en) 1971-10-05 1973-08-14 Kulite Semiconductor Products Transducers employing integral protective coatings and supports
US3958581A (en) 1972-05-17 1976-05-25 L'oreal Cosmetic composition containing a cationic polymer and divalent metal salt for strengthening the hair
CA1018893A (en) 1972-12-11 1977-10-11 Roger C. Birkofer Mild thickened shampoo compositions with conditioning properties
US4009256A (en) 1973-11-19 1977-02-22 National Starch And Chemical Corporation Novel shampoo composition containing a water-soluble cationic polymer
US4323683A (en) 1980-02-07 1982-04-06 The Procter & Gamble Company Process for making pyridinethione salts
US4379753A (en) 1980-02-07 1983-04-12 The Procter & Gamble Company Hair care compositions
US4345080A (en) 1980-02-07 1982-08-17 The Procter & Gamble Company Pyridinethione salts and hair care compositions
US4470982A (en) 1980-12-22 1984-09-11 The Procter & Gamble Company Shampoo compositions
US4529773A (en) 1982-03-17 1985-07-16 David Witiak Alkali-soluble emulsion polymers in acidic surfactant compositions
CA1224154A (en) 1983-01-25 1987-07-14 Henry Petrow Hair treating solution and method
SK46293A3 (en) 1990-09-28 1994-01-12 Procter & Gamble Polyhydroxy fatty acid amide surfactants to enhance enzyme performance
US5194639A (en) 1990-09-28 1993-03-16 The Procter & Gamble Company Preparation of polyhydroxy fatty acid amides in the presence of solvents
GB9116871D0 (en) 1991-08-05 1991-09-18 Unilever Plc Hair care composition
ES2153026T5 (es) 1994-02-18 2004-05-16 Unilever N.V. Composiciones de lavado personal.
GB9507130D0 (en) 1995-04-06 1995-05-31 Unilever Plc Hair treatment composition
DE19539846C1 (de) * 1995-10-26 1996-11-21 Henkel Kgaa Esterquats
DE19642038C1 (de) 1996-10-11 1997-12-11 Henkel Kgaa Esterquats
US5997854A (en) * 1996-12-10 1999-12-07 Henkel Corporation Conditioning shampoo formulation
DE19710155A1 (de) 1997-03-12 1998-09-17 Henkel Kgaa Kationische Mikroemulsionen
DE19715835C1 (de) * 1997-04-16 1998-11-26 Henkel Kgaa Esterquats
ES2130993B1 (es) 1997-04-30 2000-03-01 Kao Corp Sa Nueva materia activa suavizante para textiles, procedimiento para su obtencion y composiciones suavizantes para textiles que la contienen.
DE19743687C1 (de) * 1997-10-06 1998-11-26 Henkel Kgaa Detergensgemische und deren Verwendung
DE19962874A1 (de) * 1999-12-24 2001-06-28 Cognis Deutschland Gmbh Transparente Avivagemittel
ES2180372B1 (es) * 2000-03-22 2003-10-16 Kao Corp Sa Esteres derivados de alcanolaminas, acidos dicarboxilicos y alcoholes grasos, y los tensioactivos cationicos obtenibles a partir de los mismos.
EP1160238A1 (en) * 2000-06-01 2001-12-05 Goldschmidt Chemical Company Polyquaternaries from methyldiethanolamine using dibasic acids and fatty acids
US6562780B2 (en) * 2001-06-07 2003-05-13 Kao Corporation Esters derived from alkanolamines, dicarboxylic acids and fatty alcohols and the cationic surfactants obtainable therefrom
AU2002301801B2 (en) * 2001-11-08 2004-09-30 L'oreal Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof
JP2005516045A (ja) 2002-01-31 2005-06-02 クローダ，インコーポレイテッド オリゴエステルを含む添加剤および生成物
US7101538B1 (en) * 2002-12-30 2006-09-05 Avon Products, Inc. Polyesteramine ingredient and use of same
DE10313172B4 (de) 2003-03-25 2007-08-09 Henkel Kgaa Gestaltsoptimierte Reinigungsmitteltabletten
DE602004027363D1 (de) * 2003-04-17 2010-07-08 Croda Inc Körperpflegeprodukt mit einem diester-quat
US6737392B1 (en) 2003-06-11 2004-05-18 Goldschmidt Chemical Corporation MDEA ester quats with high content of monoester in blends with tea ester quats
ES2386978T3 (es) * 2007-03-02 2012-09-10 Cognis Ip Management Gmbh Esterquats poliméricos con cadenas laterales asimétricas
EP1964833B1 (en) 2007-03-02 2012-08-08 Cognis IP Management GmbH Asymmetric cationic surfactants
KR100992594B1 (ko) 2009-12-23 2010-11-08 주식회사 에스이비 양이온성 계면활성제 및 그의 제조방법
IN2014DN09936A (pt) 2012-05-30 2015-08-14 Clariant Int Ltd
JP6018523B2 (ja) 2013-02-28 2016-11-02 花王株式会社 液体柔軟剤組成物
NO3083553T3 (pt) 2013-12-18 2018-03-17
ES2690981T3 (es) 2014-01-23 2018-11-23 Clariant International Ltd. Ésteres de ácidos grasos de alquilalquilendiaminas oxalquiladas y sus sales y composiciones para el acondicionamiento del cabello
FR3038834B3 (fr) 2015-12-08 2017-08-18 Clariant Int Ltd Sels d'ammonium d'oligoester et leur utilisation dans des compositions pour le conditionnement des cheveux
BR112018010272B1 (pt) 2015-12-08 2021-12-14 Clariant International Ltd Método de preparação de uma composição cosmética, composição cosmética, composição de xampu, uso de um sal de amônio de oligoéster (oas) em composições cosméticas e método de tratamento de cabelo
FR3038835B3 (fr) 2015-12-08 2017-08-18 Clariant Int Ltd Composition de shampoing comprenant au moins un sel d'ammonium d'oligoester
CN106265109A (zh) 2016-08-22 2017-01-04 知识产权全资有限公司 强发成分以及强发并使头发具有极佳手感的方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11266587B2 (en) 2015-12-08 2022-03-08 Clariant International Ltd. Oligoester ammonium salts and their use in compositions for conditioning hair

Also Published As

Publication number Publication date
BR112018010272A2 (pt) 2018-11-27
JP2018536674A (ja) 2018-12-13
EP3386473A1 (en) 2018-10-17
CN108391419A (zh) 2018-08-10
US11266587B2 (en) 2022-03-08
JP7144322B2 (ja) 2022-09-29
JP2018536675A (ja) 2018-12-13
US20180369099A1 (en) 2018-12-27
US20180360714A1 (en) 2018-12-20
JP7144323B2 (ja) 2022-09-29
US20180353410A1 (en) 2018-12-13
EP3386473B1 (en) 2022-04-20
JP7144321B2 (ja) 2022-09-29
EP3386474A1 (en) 2018-10-17
WO2017097816A1 (en) 2017-06-15
WO2017097817A1 (en) 2017-06-15
CN108391417A (zh) 2018-08-10
BR112018010433A2 (pt) 2018-11-21
EP3386472A1 (en) 2018-10-17
BR112018010433A8 (pt) 2019-02-26
JP2018536672A (ja) 2018-12-13
CN108391418A (zh) 2018-08-10
WO2017097819A1 (en) 2017-06-15
BR112018010272B1 (pt) 2021-12-14

Similar Documents

Publication Publication Date Title
BR112018010358A2 (pt) composição de xampu que compreende pelo menos um sal de amônio de oligoéster
BR112017003931A2 (pt) composições de surfactante aquoso
EA201890752A1 (ru) Способ получения противогрибковых соединений
AR091246A1 (es) Procesos para producir 2-(piridin-3-il)tiazoles
PH12016501829A1 (en) Plant disease control composition and method for controlling plant disease by application of same
BR112014013458A2 (pt) microcápsulas, processo de produção de tais microcápsulas e composições utilizando tais microcápsulas
PH12015500008A1 (en) Dimethyl-benzoic acid compounds
EA201990904A1 (ru) 1,3-дизамещенные производные циклобутана или азетидина в качестве ингибиторов гемопоэтической простагландин-d-синтазы
BR112015022765A2 (pt) composição biocida e processo de tratamento da água ou de superfícies em contato com água
BR112018073488A2 (pt) intermediários para a síntese de derivados de ácido biliar, em particular de ácido obeticólico
AR090172A1 (es) Proceso para la preparacion de carboxamidas
BR112013022975A2 (pt) composições contendo copolímeros
BR112017005218A2 (pt) mistura de compostos, processo para fabricar uma mistura, formulação aquosa, e, uso de misturas de compostos.
PE20121155A1 (es) Un aditivo anti-incrustacion y no polimerico novedoso efectivo para inhibir la corrosion de acido naftenico a alta temperatura y metodo para utilizar el mismo
BR112016026310A8 (pt) processo para a reação de compostos químicos
TN2014000329A1 (en) Method for preparing compound by novel michael addition reaction using water or various acids as additive
BR112017013266A2 (pt) processo para preparação de um composto, composto, e, usos de um composto e de uma dispersão.
BR112017002507A2 (pt) processo para a preparação de compostos de isoxazolina opticamente ativos
CR20170295A (es) Metodo para mejorar la proporción de formación del producto de reacción de un ácido carboxílico y una urea vía adición ácida
BR112017003121A2 (pt) método para a síntese de um óxido de fosfina de hidrogênio heterocíclico
PH12019501046A1 (en) Acid composition for the treatment of fatty acids
BR112016012971A2 (pt) Complexo de metal-ligante, catalisador e processo para preparar uma poliolefina
BR112014020610B8 (pt) composto, métodos para produzir e para purificar a forma (z) de um composto, e para produzir a forma (z) de um derivado de tetrazoliloxima
MX2014002048A (es) Surfactante extendido para polimerizacion en emulsion.
BR112017007475A2 (pt) detergente para roupas contendo aditivos de amina

Legal Events

Date Code Title Description
B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.