BR112017017219A2 - catalisadores de epoxidação com base em suportes pré-tratados de alcóxido metálico - Google Patents

catalisadores de epoxidação com base em suportes pré-tratados de alcóxido metálico

Info

Publication number
BR112017017219A2
BR112017017219A2 BR112017017219A BR112017017219A BR112017017219A2 BR 112017017219 A2 BR112017017219 A2 BR 112017017219A2 BR 112017017219 A BR112017017219 A BR 112017017219A BR 112017017219 A BR112017017219 A BR 112017017219A BR 112017017219 A2 BR112017017219 A2 BR 112017017219A2
Authority
BR
Brazil
Prior art keywords
metal alkoxide
supports
catalysts based
pretreated metal
epoxidation catalysts
Prior art date
Application number
BR112017017219A
Other languages
English (en)
Other versions
BR112017017219B1 (pt
Inventor
A Grey Roger
Nagy Sandor
A Dang Vu
Original Assignee
Lyondell Chemical Tech Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Tech Lp filed Critical Lyondell Chemical Tech Lp
Publication of BR112017017219A2 publication Critical patent/BR112017017219A2/pt
Publication of BR112017017219B1 publication Critical patent/BR112017017219B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
    • B01J31/0274—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255 containing silicon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0217—Pretreatment of the substrate before coating
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

a presente revelação refere-se, em geral, a um catalisador de sílica-titânio preparado reagindo-se primeiro um suporte sólido com um alcóxido metálico e, então, depositando-se titânio sobre o suporte sólido para a epoxidação de alquenos e aralquenos e um método para preparar o catalisador dos mesmos. em algumas modalidades, a presente revelação se refere a métodos para usar o catalisador descrito no presente documento para a produção de epóxidos.
BR112017017219-4A 2015-02-17 2016-02-16 Método de obtenção de um catalisador de epoxidação BR112017017219B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201562117150P 2015-02-17 2015-02-17
US62/117,150 2015-02-17
PCT/US2016/018048 WO2016133891A1 (en) 2015-02-17 2016-02-16 Epoxidation catalysts based on metal alkoxide pretreated supports

Publications (2)

Publication Number Publication Date
BR112017017219A2 true BR112017017219A2 (pt) 2018-04-03
BR112017017219B1 BR112017017219B1 (pt) 2022-05-10

Family

ID=55527633

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017017219-4A BR112017017219B1 (pt) 2015-02-17 2016-02-16 Método de obtenção de um catalisador de epoxidação

Country Status (9)

Country Link
US (1) US9617233B2 (pt)
EP (1) EP3259057B1 (pt)
JP (1) JP6356921B2 (pt)
KR (1) KR101860694B1 (pt)
CN (1) CN107249732A (pt)
BR (1) BR112017017219B1 (pt)
ES (1) ES2885530T3 (pt)
SG (1) SG11201705972RA (pt)
WO (1) WO2016133891A1 (pt)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7337658B2 (ja) * 2019-10-29 2023-09-04 コスモ石油株式会社 金属担持触媒の製造方法

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3923843A (en) * 1972-03-13 1975-12-02 Shell Oil Co Epoxidation process with improved heterogeneous catalyst
JPS5440526A (en) * 1977-09-07 1979-03-30 Toshiba Corp Integrated drawing processor
US5935895A (en) * 1994-09-22 1999-08-10 Roche Vitamins Inc. Heterogeneous catalysts
BR9809020A (pt) * 1997-05-05 2000-08-01 Arco Chem Tech Processo de epoxidação usando composição de catalisador heterogêneo aperfeiçoada
US6114552A (en) 1999-09-28 2000-09-05 Arco Chemical Technology, L.P. Heterogeneous epoxidation catalyst
JP2002320860A (ja) * 2001-04-27 2002-11-05 Toyota Central Res & Dev Lab Inc 部分酸化触媒及びその製造方法
US6872679B2 (en) * 2002-09-20 2005-03-29 Arco Chemical Technology, L.P. Heterogeneous catalyst regeneration
CN102600820A (zh) * 2004-12-06 2012-07-25 住友化学株式会社 含钛氧化硅催化剂的制造方法、该催化剂、以及使用该催化剂的烯化氧化合物的制造方法
JP4834982B2 (ja) * 2004-12-06 2011-12-14 住友化学株式会社 チタン含有珪素酸化物触媒の製造方法及び触媒
JP2006255586A (ja) * 2005-03-17 2006-09-28 Sumitomo Chemical Co Ltd チタン含有珪素酸化物触媒の製造方法及び触媒
AU2007247223A1 (en) * 2006-05-02 2007-11-15 Shell Internationale Research Maatschappij B.V. Titanium catalyst, its preparation and its use in epoxidation reactions
WO2012010491A1 (en) 2010-07-19 2012-01-26 Shell Internationale Research Maatschappij B.V. Epoxidation process
US9175100B2 (en) * 2010-11-26 2015-11-03 Saudi Basic Industries Corporation Process for making a solid catalyst component for ethylene polymerization and copolymerization

Also Published As

Publication number Publication date
KR20170128246A (ko) 2017-11-22
CN107249732A (zh) 2017-10-13
JP2018511462A (ja) 2018-04-26
EP3259057B1 (en) 2021-04-07
US20160237051A1 (en) 2016-08-18
WO2016133891A1 (en) 2016-08-25
BR112017017219B1 (pt) 2022-05-10
SG11201705972RA (en) 2017-08-30
US9617233B2 (en) 2017-04-11
ES2885530T3 (es) 2021-12-14
EP3259057A1 (en) 2017-12-27
KR101860694B1 (ko) 2018-05-23
JP6356921B2 (ja) 2018-07-11

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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