BR112017015571A2 - valorização de produtos nobres em um processo de produção do éster (met) acrílico - Google Patents

valorização de produtos nobres em um processo de produção do éster (met) acrílico

Info

Publication number
BR112017015571A2
BR112017015571A2 BR112017015571-0A BR112017015571A BR112017015571A2 BR 112017015571 A2 BR112017015571 A2 BR 112017015571A2 BR 112017015571 A BR112017015571 A BR 112017015571A BR 112017015571 A2 BR112017015571 A2 BR 112017015571A2
Authority
BR
Brazil
Prior art keywords
meth
acrylate
acrylic ester
valorization
production process
Prior art date
Application number
BR112017015571-0A
Other languages
English (en)
Other versions
BR112017015571B1 (pt
Inventor
Cabon Yves
Dubut Fanny
Riflade Benoit
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BR112017015571A2 publication Critical patent/BR112017015571A2/pt
Publication of BR112017015571B1 publication Critical patent/BR112017015571B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/06—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton from hydroxy amines by reactions involving the etherification or esterification of hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C213/10—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C219/00—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton
    • C07C219/02—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C219/04—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated
    • C07C219/08—Compounds containing amino and esterified hydroxy groups bound to the same carbon skeleton having esterified hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and saturated having at least one of the hydroxy groups esterified by a carboxylic acid having the esterifying carboxyl group bound to an acyclic carbon atom of an acyclic unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/02—Preparation of carboxylic acid esters by interreacting ester groups, i.e. transesterification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/62—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C08F20/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F20/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

a presente invenção refere-se a um processo para a produção de um éster (met)acrílico com uma produtividade melhorada por transesterificação de um (met)acrilato de alquila leve, com um álcool pesado. o processo da invenção inclui a reciclagem de produtos nobres recuperados após um tratamento térmico de frações pesadas geradas durante a síntese, o referido tratamento térmico sendo realizado na presença de um ftalato de dialquila, cuja cadeia alquila corresponde àquela do (met)acrilato de alquila leve. a presente invenção se aplica vantajosamente à fabricação de acrilato de n,n-dimetil aminoetila a partir do acrilato de etila.
BR112017015571-0A 2015-02-04 2016-01-28 Processo de produção do éster (meta) acrílico e processo de recuperação de reagentes não reagidos e produtos de éster (meta) acrílico BR112017015571B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1550844A FR3032198B1 (fr) 2015-02-04 2015-02-04 Valorisation de produits nobles dans un procede de production d'ester (meth)acrylique.
FR1550844 2015-02-04
PCT/FR2016/050177 WO2016124837A1 (fr) 2015-02-04 2016-01-28 Valorisation de produits nobles dans un procede de production d'ester (meth)acrylique

Publications (2)

Publication Number Publication Date
BR112017015571A2 true BR112017015571A2 (pt) 2018-03-13
BR112017015571B1 BR112017015571B1 (pt) 2022-09-27

Family

ID=52824482

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112017015571-0A BR112017015571B1 (pt) 2015-02-04 2016-01-28 Processo de produção do éster (meta) acrílico e processo de recuperação de reagentes não reagidos e produtos de éster (meta) acrílico

Country Status (8)

Country Link
US (1) US10457630B2 (pt)
EP (1) EP3253731B1 (pt)
JP (1) JP6731414B2 (pt)
KR (1) KR102415174B1 (pt)
CN (1) CN107207409B (pt)
BR (1) BR112017015571B1 (pt)
FR (1) FR3032198B1 (pt)
WO (1) WO2016124837A1 (pt)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3060001B1 (fr) * 2016-12-08 2020-05-01 Arkema France Procede de fabrication d'esters (meth)acryliques
CN109942424A (zh) * 2019-04-19 2019-06-28 泰兴金江化学工业有限公司 一种丙烯酸正丁酯重组分回收工艺及装置
FR3126416B1 (fr) 2021-08-25 2023-07-14 Arkema France Procede perfectionne de fabrication d’acrylate de butyle de purete elevee

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63174009A (ja) * 1987-01-14 1988-07-18 Idemitsu Petrochem Co Ltd 顕微鏡用液浸油
JP2576749B2 (ja) * 1991-11-28 1997-01-29 日本軽金属株式会社 固結性が改善されたパラジクロルベンゼン組成物及びパラジクロルベンゼンの固結防止方法
US5534652A (en) * 1994-10-18 1996-07-09 Exxon Chemical Patents Inc. (Ecpi) Preparation of plasticizer esters from phthalic anhydride residue
DE10127939A1 (de) * 2001-06-08 2002-05-29 Basf Ag Verfahren zur Herstellung von (Meth)acrylsäureestern
JP2005015398A (ja) * 2003-06-26 2005-01-20 Mitsubishi Rayon Co Ltd （メタ）アクリル酸エステルの製造方法
FR2980476B1 (fr) * 2011-09-27 2013-08-30 Arkema France Procede de valorisation de produits nobles dans un procede de production de (meth)acrylates de dialkylaminoalkyle
FR2985999B1 (fr) * 2012-01-23 2014-01-31 Arkema France Procede de production d'acrylate de 2-octyle par transesterification

Also Published As

Publication number Publication date
EP3253731A1 (fr) 2017-12-13
BR112017015571B1 (pt) 2022-09-27
FR3032198B1 (fr) 2017-01-13
EP3253731B1 (fr) 2018-12-26
WO2016124837A1 (fr) 2016-08-11
KR102415174B1 (ko) 2022-06-29
JP6731414B2 (ja) 2020-07-29
US10457630B2 (en) 2019-10-29
US20180009736A1 (en) 2018-01-11
KR20170115068A (ko) 2017-10-16
CN107207409B (zh) 2020-03-27
CN107207409A (zh) 2017-09-26
JP2018504425A (ja) 2018-02-15
FR3032198A1 (fr) 2016-08-05

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Legal Events

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B06U Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 28/01/2016, OBSERVADAS AS CONDICOES LEGAIS