BR112015032856B1 - Método para produzir um fio sintético à base de poliamida que tem uma alta capacidade de recuperação de hidratação e fio sintético à base de poliamida obtido pelo mesmo - Google Patents
Método para produzir um fio sintético à base de poliamida que tem uma alta capacidade de recuperação de hidratação e fio sintético à base de poliamida obtido pelo mesmo Download PDFInfo
- Publication number
- BR112015032856B1 BR112015032856B1 BR112015032856-3A BR112015032856A BR112015032856B1 BR 112015032856 B1 BR112015032856 B1 BR 112015032856B1 BR 112015032856 A BR112015032856 A BR 112015032856A BR 112015032856 B1 BR112015032856 B1 BR 112015032856B1
- Authority
- BR
- Brazil
- Prior art keywords
- polyamide
- yarn
- polyether amine
- amine
- polyether
- Prior art date
Links
- 229920002647 polyamide Polymers 0.000 title claims abstract description 146
- 230000036571 hydration Effects 0.000 title claims abstract description 25
- 238000006703 hydration reaction Methods 0.000 title claims abstract description 25
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 23
- 238000011084 recovery Methods 0.000 title claims abstract description 23
- 239000004952 Polyamide Substances 0.000 claims abstract description 142
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 118
- 229920000570 polyether Polymers 0.000 claims abstract description 118
- 150000001412 amines Chemical class 0.000 claims abstract description 95
- 239000000155 melt Substances 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 55
- 229920000642 polymer Polymers 0.000 claims description 39
- 239000000654 additive Substances 0.000 claims description 27
- 150000004985 diamines Chemical class 0.000 claims description 26
- 229920002302 Nylon 6,6 Polymers 0.000 claims description 25
- 230000000996 additive effect Effects 0.000 claims description 25
- 239000004970 Chain extender Substances 0.000 claims description 23
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 17
- 229920002292 Nylon 6 Polymers 0.000 claims description 16
- 125000003277 amino group Chemical group 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000004953 Aliphatic polyamide Substances 0.000 claims 2
- 229920003231 aliphatic polyamide Polymers 0.000 claims 2
- 239000000835 fiber Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 24
- 238000001125 extrusion Methods 0.000 description 22
- 239000004753 textile Substances 0.000 description 16
- 229920002994 synthetic fiber Polymers 0.000 description 10
- 238000002347 injection Methods 0.000 description 9
- 239000007924 injection Substances 0.000 description 9
- 239000012209 synthetic fiber Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 8
- -1 i.e. Polymers 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 238000011144 upstream manufacturing Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 229920005692 JONCRYL® Polymers 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 239000012768 molten material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- 229920006309 Invista Polymers 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- 210000004899 c-terminal region Anatomy 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 229920006161 polyetheramine-modified polyamide Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- GVNWZKBFMFUVNX-UHFFFAOYSA-N Adipamide Chemical compound NC(=O)CCCCC(N)=O GVNWZKBFMFUVNX-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 229920003317 Fusabond® Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000933 poly (ε-caprolactam) Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005606 polypropylene copolymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001073 sample cooling Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/285—Feeding the extrusion material to the extruder
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/49—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using two or more extruders to feed one die or nozzle
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/40—Polyamides containing oxygen in the form of ether groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/48—Polymers modified by chemical after-treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/82—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from polyester amides or polyether amides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2077/00—Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0092—Other properties hydrophilic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/731—Filamentary material, i.e. comprised of a single element, e.g. filaments, strands, threads, fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/06—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyethers
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/02—Moisture-responsive characteristics
- D10B2401/022—Moisture-responsive characteristics hydrophylic
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000162A ITFI20130162A1 (it) | 2013-07-04 | 2013-07-04 | "metodo per la produzione di un filo sintetico ad alta ripresa di umidita' e filo ottenuto" |
| ITFI2013A000162 | 2013-07-04 | ||
| PCT/IB2014/062833 WO2015001515A1 (en) | 2013-07-04 | 2014-07-03 | Method for producing a synthetic yarn with high moisture regain and yarn obtained |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015032856A2 BR112015032856A2 (pt) | 2017-07-25 |
| BR112015032856B1 true BR112015032856B1 (pt) | 2022-02-22 |
Family
ID=49118626
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015032856-3A BR112015032856B1 (pt) | 2013-07-04 | 2014-07-03 | Método para produzir um fio sintético à base de poliamida que tem uma alta capacidade de recuperação de hidratação e fio sintético à base de poliamida obtido pelo mesmo |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US10604869B2 (https=) |
| EP (1) | EP3017096B1 (https=) |
| JP (1) | JP6452683B2 (https=) |
| KR (1) | KR102245107B1 (https=) |
| CN (1) | CN105518193B (https=) |
| AU (1) | AU2014285730B2 (https=) |
| BR (1) | BR112015032856B1 (https=) |
| CA (1) | CA2916979C (https=) |
| ES (1) | ES2927349T3 (https=) |
| HR (1) | HRP20221186T1 (https=) |
| IL (1) | IL243162B (https=) |
| IT (1) | ITFI20130162A1 (https=) |
| PL (1) | PL3017096T3 (https=) |
| RS (1) | RS63701B1 (https=) |
| RU (1) | RU2657911C2 (https=) |
| WO (1) | WO2015001515A1 (https=) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104711700A (zh) * | 2015-03-23 | 2015-06-17 | 无锡阿科力科技股份有限公司 | 聚醚胺改性的半芳香族聚酰胺纤维材料的制备方法 |
| WO2017095608A1 (en) | 2015-12-02 | 2017-06-08 | Invista North America S.A R.L. | Improved polymer preparation |
| EP3400254B1 (en) * | 2016-01-08 | 2021-02-17 | INVISTA Textiles (U.K.) Limited | Process for suppressing foam formation in the manufacture of hydrophilic polyamides |
| IT201700013100A1 (it) * | 2017-02-07 | 2018-08-07 | Golden Lady Co Spa | Uso di una poliammide modificata per la produzione di prodotti tessili anti-batterici |
| IT201700019556A1 (it) | 2017-02-21 | 2018-08-21 | Golden Lady Co Spa | Poliestere modificato con proprieta' anti-batteriche e suoi usi |
| GB201703142D0 (en) * | 2017-02-27 | 2017-04-12 | Colormatrix Holdings Inc | Polymeric materials |
| EP3697949A4 (en) * | 2017-10-18 | 2021-07-14 | University of Central Florida Research Foundation, Inc. | FIBERS WITH ELECTRICALLY CONDUCTIVE CORE AND COLOR CHANGEABLE COATING |
| EP3914438B1 (en) | 2019-01-23 | 2022-11-02 | Golden Lady Company S.p.A. | Method for dyeing a textile article made of modified polyester |
| US11479886B2 (en) | 2020-05-21 | 2022-10-25 | University Of Central Florida Research Foundation, Inc. | Color-changing fabric and applications |
| US11708649B2 (en) | 2020-05-21 | 2023-07-25 | University Of Central Florida Research Foundation, Inc. | Color-changing fabric having printed pattern |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3454534A (en) * | 1964-08-12 | 1969-07-08 | Monsanto Co | Preparation of nylon with polyalkylene glycol diamine as additive |
| JPS457559B1 (https=) * | 1965-07-21 | 1970-03-16 | ||
| JPS4837999B1 (https=) * | 1970-02-04 | 1973-11-14 | ||
| JPS4838339B1 (https=) * | 1970-11-02 | 1973-11-16 | ||
| DE2932234C2 (de) * | 1979-08-09 | 1982-01-28 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur Herstellung von Polyether(ester)amiden |
| JPS5844765B2 (ja) * | 1979-12-13 | 1983-10-05 | 帝人株式会社 | 親水性ポリアミド繊維 |
| IT1170089B (it) * | 1983-12-30 | 1987-06-03 | Snia Fibre | Composizione copolimerica atta alla produzione di fibre sintetiche ad elevata idrofilia, procedimento per la sua preparazione, fibre e manufatti relativi |
| CA2053520A1 (en) * | 1990-11-08 | 1992-05-09 | John L. Allan | Meltblown hydrophilic web made from copolymer of an amine-ended polyethylene oxide and a polyamide |
| US5306761A (en) * | 1991-11-25 | 1994-04-26 | Teijin Limited | Hygroscopic polyamide fiber |
| CA2092604A1 (en) * | 1992-11-12 | 1994-05-13 | Richard Swee-Chye Yeo | Hydrophilic, multicomponent polymeric strands and nonwoven fabrics made therewith |
| DE69807871T2 (de) * | 1997-06-06 | 2003-05-08 | Michelin Recherche Et Technique S.A., Granges-Paccot | Monofilament aus aromatischen thermotropen polyester(amide) |
| MXPA02007122A (es) * | 2000-01-20 | 2003-01-28 | Du Pont | Procedimiento de extension de cadenas de poliamida y poliamidas funcionalizadas producidas por este procedimiento. |
| MXPA03006230A (es) * | 2001-01-12 | 2004-12-06 | Dow Global Technologies Inc | Composiciones termoplasticas para la preparacion de fibras y peliculas. |
| FR2826661B1 (fr) * | 2001-06-28 | 2003-08-22 | Rhodianyl | Polymere thermoplastique, son application dans des compositions polyamides a hydrophilie et antistaticite ameliorees |
| CN101287795A (zh) * | 2005-09-06 | 2008-10-15 | 通用纤维公司 | 生产具有改进的湿度管理性能的聚酯和聚酰胺纱线的组合物 |
| EP1783156A1 (en) * | 2005-11-03 | 2007-05-09 | Arkema France | Process to make copolymers having polyamide blocks and polyether blocks |
| ATE506413T1 (de) * | 2007-03-01 | 2011-05-15 | Prs Mediterranean Ltd | Verfahren zur herstellung kompatibilisierter polymermischungen und artikeln |
| FR2941700B1 (fr) * | 2009-02-02 | 2012-03-16 | Arkema France | Procede de synthese d'un alliage de copolymere a blocs presentant des proprietes antistatiques ameliorees. |
| EP2614103B1 (en) | 2010-09-10 | 2015-04-15 | Invista Technologies S.a r.l. | Polyetheramines, compositions including polyetheramines, and methods of making |
| CN102493016B (zh) * | 2011-12-21 | 2014-08-20 | 苏州大学 | 一种多孔超细旦聚酰胺6全拉伸丝、制备方法及其设备 |
| AU2013328392B2 (en) * | 2012-10-10 | 2016-08-04 | Golden Lady Company S.P.A. | Polyamide apparel textile yarns and fabrics and garments made therefrom |
-
2013
- 2013-07-04 IT IT000162A patent/ITFI20130162A1/it unknown
-
2014
- 2014-07-03 JP JP2016522951A patent/JP6452683B2/ja not_active Expired - Fee Related
- 2014-07-03 AU AU2014285730A patent/AU2014285730B2/en active Active
- 2014-07-03 RU RU2016103574A patent/RU2657911C2/ru active
- 2014-07-03 PL PL14755149.3T patent/PL3017096T3/pl unknown
- 2014-07-03 WO PCT/IB2014/062833 patent/WO2015001515A1/en not_active Ceased
- 2014-07-03 CN CN201480041498.4A patent/CN105518193B/zh active Active
- 2014-07-03 RS RS20220891A patent/RS63701B1/sr unknown
- 2014-07-03 ES ES14755149T patent/ES2927349T3/es active Active
- 2014-07-03 HR HRP20221186TT patent/HRP20221186T1/hr unknown
- 2014-07-03 KR KR1020157037267A patent/KR102245107B1/ko active Active
- 2014-07-03 CA CA2916979A patent/CA2916979C/en active Active
- 2014-07-03 EP EP14755149.3A patent/EP3017096B1/en active Active
- 2014-07-03 BR BR112015032856-3A patent/BR112015032856B1/pt active IP Right Grant
- 2014-07-03 US US14/902,730 patent/US10604869B2/en not_active Expired - Fee Related
-
2015
- 2015-12-23 IL IL243162A patent/IL243162B/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015032856A2 (pt) | 2017-07-25 |
| US20160168759A1 (en) | 2016-06-16 |
| KR20160029758A (ko) | 2016-03-15 |
| EP3017096A1 (en) | 2016-05-11 |
| EP3017096B1 (en) | 2022-06-29 |
| KR102245107B1 (ko) | 2021-04-27 |
| US10604869B2 (en) | 2020-03-31 |
| PL3017096T3 (pl) | 2022-12-19 |
| CA2916979C (en) | 2021-03-02 |
| IL243162B (en) | 2018-08-30 |
| HRP20221186T1 (hr) | 2022-12-09 |
| JP2016526618A (ja) | 2016-09-05 |
| CN105518193A (zh) | 2016-04-20 |
| WO2015001515A1 (en) | 2015-01-08 |
| ITFI20130162A1 (it) | 2015-01-05 |
| AU2014285730B2 (en) | 2017-11-16 |
| ES2927349T3 (es) | 2022-11-04 |
| AU2014285730A1 (en) | 2016-01-28 |
| RU2016103574A (ru) | 2017-08-10 |
| RU2657911C2 (ru) | 2018-06-18 |
| CA2916979A1 (en) | 2015-01-08 |
| HK1219988A1 (zh) | 2017-04-21 |
| JP6452683B2 (ja) | 2019-01-16 |
| CN105518193B (zh) | 2017-10-27 |
| RS63701B1 (sr) | 2022-11-30 |
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