BR112015030282A2 - método de recuperação de cobre e de metais preciosos - Google Patents
método de recuperação de cobre e de metais preciososInfo
- Publication number
- BR112015030282A2 BR112015030282A2 BR112015030282A BR112015030282A BR112015030282A2 BR 112015030282 A2 BR112015030282 A2 BR 112015030282A2 BR 112015030282 A BR112015030282 A BR 112015030282A BR 112015030282 A BR112015030282 A BR 112015030282A BR 112015030282 A2 BR112015030282 A2 BR 112015030282A2
- Authority
- BR
- Brazil
- Prior art keywords
- copper
- solution
- lye
- precious metals
- recovering
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/02—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/04—Halides
- C01G3/05—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/04—Halides
- C01G3/06—Oxychlorides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/04—Obtaining noble metals by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0086—Treating solutions by physical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0091—Treating solutions by chemical methods by cementation
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/40—Mixtures
- C22B3/408—Mixtures using a mixture of phosphorus-based acid derivatives of different types
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
- C22B3/46—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes by substitution, e.g. by cementation
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/20—Electrolytic production, recovery or refining of metals by electrolysis of solutions of noble metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
1/1 resumo método de recuperação de cobre e de metais preciosos a presente invenção refere-se a um método de recuperação de cobre e de um ou mais metais preciosos, a partir de um minério ou concentrado de sulfeto contendo cobre, compreendendo a lixiviação do minério e/ou concentrado contendo cobre sob condições atmosféricas ou ligeiramente pressurizadas, a uma temperatura abaixo do ponto de ebulição da solução de lixívia, em uma solução de ácido sulfúrico na presença de um ou mais halogenetos de metal alcalino ou metal alcalino terroso, em que a concentração total do halogeneto é de 30 a 115 g/l, para dissolver o cobre e obter um licor de lixiviação compreendendo cobre, espécies de enxofre e halogenetos na solução. o licor de lixiviação é depois submetido a uma separação do tipo sólido-líquido, após o que uma primeira solução aquosa impregnada de lixívia e um resíduo de lixiviação exaurido de cobre são obtidos. o cobre é purificado por extração por solvente da primeira solução aquosa impregnada de lixívia, para se obter uma primeira solução orgânica enriquecida contendo cobre e um primeiro refinado aquoso. a solução orgânica enriquecida contendo cobre é extraída e o cobre é recuperado de uma solução de extração que contém quantidades de traços de cloretos.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI20135630 | 2013-06-07 | ||
| FI20135630A FI125388B (en) | 2013-06-07 | 2013-06-07 | Method for the recovery of copper and precious metals |
| PCT/FI2014/050461 WO2014195586A1 (en) | 2013-06-07 | 2014-06-06 | Method of recovering copper and precious metals |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BR112015030282A2 true BR112015030282A2 (pt) | 2017-07-25 |
| BR112015030282B1 BR112015030282B1 (pt) | 2020-06-02 |
| BR112015030282B8 BR112015030282B8 (pt) | 2023-02-07 |
Family
ID=51205413
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015030282A BR112015030282B8 (pt) | 2013-06-07 | 2014-06-06 | Método de recuperação de cobre e de metais preciosos |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US10023936B2 (pt) |
| EP (1) | EP3004405B1 (pt) |
| CN (1) | CN105339511B (pt) |
| AP (2) | AP2015008909A0 (pt) |
| AU (1) | AU2014276702B2 (pt) |
| BR (1) | BR112015030282B8 (pt) |
| CA (1) | CA2914142C (pt) |
| CL (1) | CL2015003524A1 (pt) |
| EA (1) | EA026943B1 (pt) |
| ES (1) | ES2649477T3 (pt) |
| FI (1) | FI125388B (pt) |
| PE (1) | PE20160569A1 (pt) |
| PL (1) | PL3004405T3 (pt) |
| PT (1) | PT3004405T (pt) |
| WO (1) | WO2014195586A1 (pt) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11408053B2 (en) | 2015-04-21 | 2022-08-09 | Excir Works Corp. | Methods for selective leaching and extraction of precious metals in organic solvents |
| US10167202B2 (en) | 2016-02-23 | 2019-01-01 | King Abdullah University Of Science And Technology | Enhanced metal recovery through oxidation in liquid and/or supercritical carbon dioxide |
| CN106521163B (zh) * | 2016-11-05 | 2018-08-21 | 北京工业大学 | 一种含铜废料氯化液贵金属富集的方法 |
| RU2749309C2 (ru) * | 2019-09-05 | 2021-06-08 | Акционерное общество "Иркутский научно-исследовательский институт благородных и редких металлов и алмазов" АО "Иргиредмет" | Способ извлечения золота и меди из сульфидного золотомедного флотоконцентрата |
| CN110527832A (zh) * | 2019-09-20 | 2019-12-03 | 常州工学院 | 一种铜萃取剂 |
| CN110563021B (zh) * | 2019-10-16 | 2023-04-07 | 大冶有色金属有限责任公司 | 一种无害化处理回收碱式氯化铜的方法及装置 |
| CN112941529A (zh) * | 2019-12-11 | 2021-06-11 | 上海旷宇环境科技有限公司 | 一种分离金属离子和用酸的过滤回收系统 |
| EP4100554A4 (en) * | 2020-02-07 | 2024-03-20 | University Of Kentucky Research Foundation | EXTRACTION OF COPPER, GOLD AND OTHER ELEMENTS FROM WASTE |
| CA3173769A1 (en) * | 2020-10-02 | 2022-04-07 | Loghman MORADI | Method for extraction of coinage metals |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR96081E (fr) * | 1968-11-08 | 1972-05-19 | Mayor Yoland Pierre Paul | Procédé de récupération du cuivre. |
| FR2261341A2 (en) * | 1974-02-19 | 1975-09-12 | Weston David | Recovery of copper by leaching - using sulphuric acid at specified temp. and pH |
| CN1045476C (zh) * | 1994-12-20 | 1999-10-06 | 康明柯工程服务有限公司 | 氯化物辅助的湿法冶金铜萃取 |
| ZA987219B (en) * | 1997-08-15 | 2000-02-14 | Cominco Eng Services | Chloride assisted hydrometallurgical extraction of metal. |
| US6451089B1 (en) * | 2001-07-25 | 2002-09-17 | Phelps Dodge Corporation | Process for direct electrowinning of copper |
| FI115534B (fi) | 2002-10-15 | 2005-05-31 | Outokumpu Oy | Menetelmä metallien talteenottamiseksi kloridiliuotuksen ja uuton avulla |
| AU2007249176B2 (en) | 2006-05-12 | 2011-09-08 | Consolidated Nominees (Pty) Ltd | Chloride heap leaching |
| JP4717908B2 (ja) | 2008-08-11 | 2011-07-06 | Ｊｘ日鉱日石金属株式会社 | 銅を含有する塩化物浴からの銅の回収方法 |
| US8968442B2 (en) * | 2009-10-21 | 2015-03-03 | The University Of British Columbia | Leaching process for copper concentrates with a carbon catalyst |
| FI122685B (fi) | 2010-06-09 | 2012-05-31 | Outotec Oyj | Menetelmä kullan ottamiseksi talteen neste-nesteuutolla |
| FI20110279A0 (fi) * | 2011-08-29 | 2011-08-29 | Outotec Oyj | Menetelmä metallien talteenottamiseksi niitä sisältävästä materiaalista |
| US9169533B2 (en) * | 2011-12-20 | 2015-10-27 | Freeport Minerals Corporation | System and method including multi-circuit solution extraction for recovery of metal values from metal-bearing materials |
-
2013
- 2013-06-07 FI FI20135630A patent/FI125388B/en active IP Right Grant
-
2014
- 2014-05-28 AP AP2015008909A patent/AP2015008909A0/xx unknown
- 2014-06-06 AP AP2015008910A patent/AP2015008910A0/xx unknown
- 2014-06-06 PE PE2015002559A patent/PE20160569A1/es unknown
- 2014-06-06 EP EP14739499.3A patent/EP3004405B1/en active Active
- 2014-06-06 AU AU2014276702A patent/AU2014276702B2/en active Active
- 2014-06-06 EA EA201592162A patent/EA026943B1/ru not_active IP Right Cessation
- 2014-06-06 PL PL14739499T patent/PL3004405T3/pl unknown
- 2014-06-06 CN CN201480036875.5A patent/CN105339511B/zh active Active
- 2014-06-06 WO PCT/FI2014/050461 patent/WO2014195586A1/en active Application Filing
- 2014-06-06 BR BR112015030282A patent/BR112015030282B8/pt active IP Right Grant
- 2014-06-06 PT PT147394993T patent/PT3004405T/pt unknown
- 2014-06-06 ES ES14739499.3T patent/ES2649477T3/es active Active
- 2014-06-06 CA CA2914142A patent/CA2914142C/en active Active
- 2014-06-06 US US14/895,740 patent/US10023936B2/en active Active
-
2015
- 2015-12-02 CL CL2015003524A patent/CL2015003524A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015030282B1 (pt) | 2020-06-02 |
| CN105339511B (zh) | 2018-01-23 |
| AP2015008910A0 (en) | 2015-12-31 |
| EA201592162A1 (ru) | 2016-06-30 |
| EA026943B1 (ru) | 2017-06-30 |
| FI20135630A (fi) | 2014-12-08 |
| PE20160569A1 (es) | 2016-06-06 |
| FI125388B (en) | 2015-09-30 |
| CL2015003524A1 (es) | 2016-10-07 |
| CA2914142A1 (en) | 2014-12-11 |
| PT3004405T (pt) | 2017-12-06 |
| CN105339511A (zh) | 2016-02-17 |
| AU2014276702B2 (en) | 2017-02-16 |
| ES2649477T3 (es) | 2018-01-12 |
| EP3004405B1 (en) | 2017-09-27 |
| PL3004405T3 (pl) | 2018-02-28 |
| BR112015030282B8 (pt) | 2023-02-07 |
| US10023936B2 (en) | 2018-07-17 |
| AU2014276702A1 (en) | 2016-01-28 |
| EP3004405A1 (en) | 2016-04-13 |
| US20160115568A1 (en) | 2016-04-28 |
| WO2014195586A1 (en) | 2014-12-11 |
| CA2914142C (en) | 2018-03-06 |
| AP2015008909A0 (en) | 2015-12-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 06/06/2014, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25A | Requested transfer of rights approved |
Owner name: METSO MINERALS OY (FI) |
|
| B25D | Requested change of name of applicant approved |
Owner name: METSO OUTOTEC FINLAND OY (FI) |