BR112015000990B1 - Método para a síntese de um ácido aminoalquilenofosfônico ouseus ésteres fosfatos - Google Patents
Método para a síntese de um ácido aminoalquilenofosfônico ouseus ésteres fosfatos Download PDFInfo
- Publication number
- BR112015000990B1 BR112015000990B1 BR112015000990A BR112015000990A BR112015000990B1 BR 112015000990 B1 BR112015000990 B1 BR 112015000990B1 BR 112015000990 A BR112015000990 A BR 112015000990A BR 112015000990 A BR112015000990 A BR 112015000990A BR 112015000990 B1 BR112015000990 B1 BR 112015000990B1
- Authority
- BR
- Brazil
- Prior art keywords
- phosphate esters
- synthesis
- phosphonic acid
- compound
- ouseus
- Prior art date
Links
- 150000003014 phosphoric acid esters Chemical class 0.000 title abstract 4
- -1 AMINO Chemical class 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 title 1
- 239000000126 substance Substances 0.000 abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 4
- 150000001299 aldehydes Chemical class 0.000 abstract 2
- 150000008064 anhydrides Chemical class 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3839—Polyphosphonic acids
- C07F9/3873—Polyphosphonic acids containing nitrogen substituent, e.g. N.....H or N-hydrocarbon group which can be substituted by halogen or nitro(so), N.....O, N.....S, N.....C(=X)- (X =O, S), N.....N, N...C(=X)...N (X =O, S)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
- C07F9/5728—Five-membered rings condensed with carbocyclic rings or carbocyclic ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/645—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having two nitrogen atoms as the only ring hetero atoms
- C07F9/6503—Five-membered rings
- C07F9/6506—Five-membered rings having the nitrogen atoms in positions 1 and 3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/653—Five-membered rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12176753 | 2012-07-17 | ||
| PCT/EP2013/065121 WO2014012987A1 (en) | 2012-07-17 | 2013-07-17 | Method for the synthesis of aminoalkylenephosphonic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR112015000990A2 BR112015000990A2 (pt) | 2017-06-27 |
| BR112015000990B1 true BR112015000990B1 (pt) | 2020-04-28 |
Family
ID=49003748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112015000990A BR112015000990B1 (pt) | 2012-07-17 | 2013-07-17 | Método para a síntese de um ácido aminoalquilenofosfônico ouseus ésteres fosfatos |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US10280189B2 (enExample) |
| EP (1) | EP2875036A1 (enExample) |
| CN (1) | CN104812766B (enExample) |
| BR (1) | BR112015000990B1 (enExample) |
| IN (1) | IN2015DN01079A (enExample) |
| RU (1) | RU2694047C2 (enExample) |
| WO (1) | WO2014012987A1 (enExample) |
Family Cites Families (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH275435A (de) | 1949-06-30 | 1951-05-31 | Cilag Ag | Verfahren zur Herstellung einer Phosphonsäure. |
| NL285361A (enExample) | 1961-11-13 | 1900-01-01 | ||
| US3400148A (en) | 1965-09-23 | 1968-09-03 | Procter & Gamble | Phosphonate compounds |
| GB1142294A (en) | 1966-02-08 | 1969-02-05 | Albright & Wilson Mfg Ltd | Improvements in production of amino alkylene phosphonic acids |
| GB1230121A (enExample) | 1967-01-27 | 1971-04-28 | ||
| US3455675A (en) | 1968-06-25 | 1969-07-15 | Monsanto Co | Aminophosphonate herbicides |
| DE2132511C3 (de) | 1971-06-30 | 1974-06-27 | Joh. A. Benckiser Gmbh, 6700 Ludwigshafen | Verfahren zur Herstellung von Aminomethylenphosphonsäuren |
| DE2013371B1 (de) | 1970-03-20 | 1971-11-04 | Joh A , Benckiser GmbH, Chemische Fabrik, 6700 Ludwigshafen | Verfahren zur Herstellung von Amino methylenphosphonsauren |
| DE2017974A1 (de) | 1970-04-15 | 1971-11-04 | Joh. A. Benckiser Gmbh Chemische Fabrik, 6700 Ludwigshafen | Verfahren zur Herstellung von Aminoalkylenphosphonsäuren |
| US3799758A (en) | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3969398A (en) | 1974-05-01 | 1976-07-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| HU173170B (hu) | 1974-06-27 | 1979-03-28 | Chinoin Gyogyszer Es Vegyeszet | Sposob poluchenija n-fosfonometil-glicina |
| US3927080A (en) | 1974-09-03 | 1975-12-16 | Monsanto Co | Process for producing N-phosphonomethyl glycine |
| IL48619A (en) | 1974-12-11 | 1978-04-30 | Monsanto Co | Process for the production of n-(phosphonomethyl)-glycine compounds |
| DD123192A1 (enExample) | 1975-01-16 | 1976-12-05 | ||
| CH647528A5 (fr) | 1978-10-27 | 1985-01-31 | Bcap Biolog Chem Act Pat | Procede pour la preparation de n-phosphonomethylglycine. |
| US4211547A (en) | 1978-12-22 | 1980-07-08 | Monsanto Company | N-Phosphonomethyliminodiacetonitrile and certain derivatives thereof |
| DE3016289A1 (de) | 1980-04-28 | 1981-10-29 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung von omega -amino-1-hydroxyalkyliden-1,1-bis-phosphonsaeuren |
| JPS5775990A (en) | 1980-10-27 | 1982-05-12 | Mitsubishi Gas Chem Co Inc | Preparation of n,n,n',n'-tetra(phosphonomethyl) diaminoalkane |
| US4422982A (en) | 1982-06-30 | 1983-12-27 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4400330A (en) | 1982-07-29 | 1983-08-23 | Stauffer Chemical Company | Method for preparation of N-phosphonomethylglycine |
| US4617415A (en) | 1983-12-02 | 1986-10-14 | Monsanto Company | α-Substituted N-phosphonomethyliminodiacetic acid |
| US4654429A (en) | 1983-12-02 | 1987-03-31 | Monsanto Company | Process for the preparation of a glyphosate product |
| GB2154588B (en) | 1984-02-20 | 1987-10-07 | Sunlead Chemical Industry Co L | A process for preparation of n-phosphonomethyl glycine |
| US4724103A (en) | 1984-02-27 | 1988-02-09 | Monsanto Company | Process for preparing N,N-diacetic acid aminomethylenephosphonic acid |
| US4624937A (en) | 1984-05-10 | 1986-11-25 | Monsanto Company | Process for removing surface oxides from activated carbon catalyst |
| US4804499A (en) | 1985-09-23 | 1989-02-14 | Monsanto Company | Process for the preparation of N-substituted aminomethylphosphonic acids |
| US4657705A (en) | 1985-09-23 | 1987-04-14 | Monsanto Company | Process for the preparation of N-substituted aminomethylphosphonic acids |
| HU205944B (en) | 1988-02-08 | 1992-07-28 | Nitrokemia Ipartelepek | Process for producing n-phosphono-methyl-imino-diacetic acid |
| HU200780B (en) | 1988-02-08 | 1990-08-28 | Nitrokemia Ipartelepek | Process for producing n-phosphonomethyl iminodiacetic acid from double salt of iminodiacetic acid |
| RO101476A2 (ro) | 1988-08-11 | 1991-12-09 | Intreprinderea Textila, Timisoara, Judetul Timis, Ro | Procedeu de obtinere a unor dialchil n,n-bis-(2-hidroxietil)-aminometilfosfonati |
| ES2018746A6 (es) | 1989-12-21 | 1991-05-01 | Aragonesas Energ & Ind | Procedimiento para la obtencion del acido n,n-diaceticoaminometilenfosfonico. |
| DE4026026A1 (de) | 1990-08-17 | 1992-02-20 | Hoechst Ag | Acylaminomethyl-phosphinsaeuren und verfahren zur herstellung von acylaminomethanphosphonsaeuren und acylaminomethyl-phosphinsaeuren |
| TW263511B (enExample) | 1990-10-10 | 1995-11-21 | Hoechst Ag | |
| JP2525977B2 (ja) | 1991-10-17 | 1996-08-21 | 昭和電工株式会社 | Ｎ−アシルアミノメチルホスホン酸の製造法 |
| US5312972A (en) | 1992-10-29 | 1994-05-17 | Hampshire Chemical Corp. | Conversion of hydroxymethyl-iminodiacetic acid to phosphonomethyl-iminodiacetic acid |
| GB9300641D0 (en) | 1993-01-14 | 1993-03-03 | Zeneca Ltd | Process |
| US5312973A (en) | 1993-03-25 | 1994-05-17 | Finchimica S.P.A. | Process for producing n-phosphono-methyl-imino-diacetic acid |
| GB9307235D0 (en) | 1993-04-07 | 1993-06-02 | Zeneca Ltd | Process |
| DE4326887A1 (de) | 1993-08-11 | 1995-02-16 | Hoechst Ag | Verfahren zur Herstellung von N-substituierten Aminoalkylenphosphonsäureestern |
| PT833831E (pt) | 1995-06-07 | 2002-07-31 | Monsanto Technology Llc | Processo para a preparacao de acido n-fosfonometiliminodiacetico |
| US5986128A (en) | 1996-11-01 | 1999-11-16 | Monsanto Company | Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid |
| US6153753A (en) | 1997-02-13 | 2000-11-28 | Monsanto Company | Method of preparing amino carboxylic acids |
| IES980552A2 (en) | 1998-07-09 | 1999-08-11 | Agritech Chemical Ltd | Improved process for preparing N-phosphonomethyl iminodiacetic acid |
| WO2000009520A1 (en) | 1998-08-12 | 2000-02-24 | Monsanto Company | Continuous process for the preparation of n-(phosphonomethyl) iminodiacetic acid |
| AU6024599A (en) | 1998-09-08 | 2000-03-27 | Hampshire Chemical Corp. | Synthesis of phosphonomethyliminodiacetic acid with reduced effluent |
| DE19909200C1 (de) | 1999-03-03 | 2000-03-09 | Sueddeutsche Kalkstickstoff | Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure |
| DE19914375A1 (de) | 1999-03-30 | 2000-10-05 | Sueddeutsche Kalkstickstoff | Verfahren zur Herstellung von N-Phosphonomethyliminodiessigsäure |
| DE10019879A1 (de) | 2000-04-20 | 2001-10-25 | Degussa | Verfahren zur Herstellung von 2,5-Diketopiperazinen, neue 2,5-Diketopiperazine und deren Verwendung |
| US20020058834A1 (en) | 2000-06-01 | 2002-05-16 | Franczyk Thaddeus S. | Preparation of N-acyl amino carboxylic acids, amino carboxylic acids and their derivatives by metal-catalyzed carboxymethylation in the presence of a promoter |
| AR032096A1 (es) | 2001-01-12 | 2003-10-22 | Basf Ag | Procedimiento para elaborar acido n-fosfonometilimino-diacetico |
| CN1285600C (zh) | 2004-11-25 | 2006-11-22 | 浙江新安化工集团股份有限公司 | 一种草甘膦制剂及其制备方法 |
| EP1681294A1 (en) | 2005-01-17 | 2006-07-19 | Solutia Europe N.V./S.A. | Process for the manufacture of aminopolyalkylene-phosphonic acid compounds |
| EP1681295A1 (en) | 2005-01-17 | 2006-07-19 | Solutia Europe N.V./S.A. | Process for the manufacture of aminoakylenephosphonic acid compounds in the presence of a heterogeneous catalyst |
| CN104829648A (zh) | 2005-04-01 | 2015-08-12 | 孟山都技术公司 | 在草甘膦的生产中对n-(膦酰甲基)亚氨基二乙酸转化率的控制 |
| JP2007022956A (ja) | 2005-07-15 | 2007-02-01 | Mitsubishi Gas Chem Co Inc | 高純度アミノメチレンホスホン酸の製造方法 |
| EP1932850A1 (en) | 2006-12-11 | 2008-06-18 | Thermphos Trading GmbH | Phosphonate compounds |
| CL2008003539A1 (es) | 2007-11-28 | 2009-07-03 | Procedimiento para la produccion de p4o6 que comprende mezclar o2 o una mezcla de o2 mas un gas inerte y fosforo en donde el producto obtenido se mantiene dentro de una unidad de reaccion a una temperatura entre los 1600 y 2000 k durante por lo menos 1 segundo. | |
| EP2112156A1 (en) | 2008-04-25 | 2009-10-28 | Thermphos International B.V. | Method for the Manufacture of Aminoalkylene Phosphonic Acid |
| MX2010010991A (es) | 2008-04-25 | 2010-11-05 | Albert Devaux | Metodo para la fabricacion de acido aminoalquilenfosfonico. |
| US8551437B2 (en) | 2008-11-12 | 2013-10-08 | Straitmark Holding Ag | Process for the manufacture of P4O6 with improved yield |
| RU2011150961A (ru) * | 2009-05-28 | 2013-07-10 | Страйтмарк Холдинг Аг | Способ получения аминоалкиленфосфоновых кислот |
| US20120130120A1 (en) | 2009-05-28 | 2012-05-24 | Straitmark Holding Ag | Method for the manufacture of phosphonoalkyl iminodiacetic acids |
| AU2010302597B2 (en) | 2009-10-02 | 2016-06-09 | Monsanto Technology Llc | Method for the manufacture of aminohydroxy diphosphonic acids |
| RU2553683C2 (ru) | 2009-10-27 | 2015-06-20 | Страйтмарк Холдинг Аг | Способ получения фосфоноалкилиминодиуксусной кислоты |
| CN104620073B (zh) | 2012-06-13 | 2016-08-17 | 皇家飞利浦有限公司 | 确定表面波的传播速度 |
| CN104812763B (zh) | 2012-07-17 | 2016-11-23 | 斯特雷特马克控股股份公司 | 用于合成n-(膦酰基甲基)甘氨酸的方法 |
| WO2014012990A1 (en) | 2012-07-17 | 2014-01-23 | Straitmark Holding Ag | Method for the synthesis of alpha-aminoalkylenephosphonic acid |
| BR112015000988A2 (pt) | 2012-07-17 | 2017-06-27 | Straitmark Holding Ag | método para a síntese de ácido n-fosfonometiliminodiacético ou derivados do mesmo |
-
2013
- 2013-07-17 BR BR112015000990A patent/BR112015000990B1/pt active IP Right Grant
- 2013-07-17 RU RU2015103306A patent/RU2694047C2/ru active
- 2013-07-17 IN IN1079DEN2015 patent/IN2015DN01079A/en unknown
- 2013-07-17 US US14/415,686 patent/US10280189B2/en active Active
- 2013-07-17 WO PCT/EP2013/065121 patent/WO2014012987A1/en not_active Ceased
- 2013-07-17 EP EP13750855.2A patent/EP2875036A1/en not_active Withdrawn
- 2013-07-17 CN CN201380037546.8A patent/CN104812766B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2015103306A (ru) | 2016-09-10 |
| RU2694047C2 (ru) | 2019-07-09 |
| BR112015000990A2 (pt) | 2017-06-27 |
| US10280189B2 (en) | 2019-05-07 |
| WO2014012987A1 (en) | 2014-01-23 |
| EP2875036A1 (en) | 2015-05-27 |
| CN104812766B (zh) | 2017-06-06 |
| IN2015DN01079A (enExample) | 2015-06-26 |
| CN104812766A (zh) | 2015-07-29 |
| US20150225431A1 (en) | 2015-08-13 |
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