BR112013030262A2 - processo de hidroformilação - Google Patents

processo de hidroformilação

Info

Publication number
BR112013030262A2
BR112013030262A2 BR112013030262A BR112013030262A BR112013030262A2 BR 112013030262 A2 BR112013030262 A2 BR 112013030262A2 BR 112013030262 A BR112013030262 A BR 112013030262A BR 112013030262 A BR112013030262 A BR 112013030262A BR 112013030262 A2 BR112013030262 A2 BR 112013030262A2
Authority
BR
Brazil
Prior art keywords
binder
hydroformylation process
transcoordinated
dialkylphenylphosphinomethyl
hydroxybutyraldehyde
Prior art date
Application number
BR112013030262A
Other languages
English (en)
Inventor
Dieter Arlt
Original Assignee
Umicore Ag & Co Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE102011102666A external-priority patent/DE102011102666A1/de
Application filed by Umicore Ag & Co Kg filed Critical Umicore Ag & Co Kg
Publication of BR112013030262A2 publication Critical patent/BR112013030262A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C07C45/505—Asymmetric hydroformylation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/5027—Polyphosphines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C07C43/135—Saturated ethers containing hydroxy or O-metal groups having more than one ether bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/178—Unsaturated ethers containing hydroxy or O-metal groups
    • C07C43/1788—Unsaturated ethers containing hydroxy or O-metal groups containing six-membered aromatic rings and other rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/04—Systems containing only non-condensed rings with a four-membered ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

resumo patente de invenção: "processo de hidroformilação". a presente invenção refere-se a um processo para produzir 4-hidroxibutiraldeído, caracterizado pelo fato de que álcool alquila dissolvido em solventes polares é reagido com co e h2 na presença de um sistema catalítico que é formado de um complexo de ródio e um ligante de ciclobutano que contém pelo menos dois grupos transcoordenados 1,3-dialquilfenilfosfinometil, com a exclusão de catalisadores que contêm uma fosfina alifática, aralifático ou cicloalifático como ligante.
BR112013030262A 2011-05-27 2012-05-25 processo de hidroformilação BR112013030262A2 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102011102666A DE102011102666A1 (de) 2011-05-27 2011-05-27 Neues Verfahren zur Hydroformylierung
DE102011110621 2011-08-16
PCT/EP2012/059841 WO2012163831A1 (en) 2011-05-27 2012-05-25 Novel hydroformylation process

Publications (1)

Publication Number Publication Date
BR112013030262A2 true BR112013030262A2 (pt) 2016-12-06

Family

ID=46149490

Family Applications (2)

Application Number Title Priority Date Filing Date
BR112013029852A BR112013029852A2 (pt) 2011-05-27 2012-05-25 ligantes e sistemas catalisadores para processos de hidroformilação
BR112013030262A BR112013030262A2 (pt) 2011-05-27 2012-05-25 processo de hidroformilação

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BR112013029852A BR112013029852A2 (pt) 2011-05-27 2012-05-25 ligantes e sistemas catalisadores para processos de hidroformilação

Country Status (9)

Country Link
US (2) US8791305B2 (pt)
EP (2) EP2714700A1 (pt)
JP (2) JP2014524889A (pt)
CN (2) CN103748102A (pt)
BR (2) BR112013029852A2 (pt)
CA (1) CA2835744A1 (pt)
RU (1) RU2013157751A (pt)
TW (1) TW201306939A (pt)
WO (2) WO2012163837A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112013029852A2 (pt) 2011-05-27 2016-12-20 Umicore Ag & Co Kg ligantes e sistemas catalisadores para processos de hidroformilação
ES2673115T3 (es) 2015-12-16 2018-06-19 Evonik Degussa Gmbh Procedimiento para la carbonilación doble de alcoholes alílicos para dar los correspondientes diésteres
EP3530644B1 (en) 2018-02-26 2022-11-02 Lyondell Chemical Technology, L.P. Improving rhenium catalysts for glycerin to allyl alcohol conversion
EP3976625B1 (en) 2019-05-31 2023-08-02 Lyondell Chemical Technology, L.P. High linear selectivity ligand for allyl alcohol hydroformylation
CN112457165A (zh) * 2019-09-06 2021-03-09 南京延长反应技术研究院有限公司 一种烯丙醇加氢制备1，4-丁二醇的强化系统及工艺
CN110975941B (zh) * 2019-12-17 2022-08-05 万华化学集团股份有限公司 一种氢甲酰化反应催化剂组合物及丙烯氢甲酰化反应制备醛的方法
CN113061149B (zh) * 2021-03-29 2022-04-22 万华化学集团股份有限公司 一种互配型配体和氢甲酰化催化剂、及二元醇的制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4064145A (en) 1975-10-20 1977-12-20 Celanese Corporation Production of tetrahydrofuran
US4215077A (en) 1978-02-09 1980-07-29 Kuraray Co., Ltd. Hydroformylation of olefins
FR2428021A1 (fr) 1978-06-05 1980-01-04 Kuraray Co Hydroformylation de composes olefiniques
US4678857A (en) 1986-03-31 1987-07-07 Texaco Inc. Process for separation of product resulting from hydroformylation
US5290743A (en) 1993-03-22 1994-03-01 Arco Chemical Technology L.P. Process for regenerating a deactivated rhodium hydroformylation catalyst system
US7279606B1 (en) 2007-04-02 2007-10-09 Lyondell Chemical Technology, L.P. Hydroformylation process
US7655821B1 (en) 2008-11-25 2010-02-02 Lyondell Chemical Technology, L.P. Direct hydrocarbonylation process
US20100292514A1 (en) 2009-05-13 2010-11-18 White Daniel F Hydroformylation process
BR112013029852A2 (pt) 2011-05-27 2016-12-20 Umicore Ag & Co Kg ligantes e sistemas catalisadores para processos de hidroformilação

Also Published As

Publication number Publication date
JP2014524889A (ja) 2014-09-25
CA2835744A1 (en) 2012-12-06
US8791305B2 (en) 2014-07-29
US20140243558A1 (en) 2014-08-28
US9108912B2 (en) 2015-08-18
TW201306939A (zh) 2013-02-16
CN103748102A (zh) 2014-04-23
WO2012163837A1 (en) 2012-12-06
CN103562213A (zh) 2014-02-05
JP2014520089A (ja) 2014-08-21
US20140114090A1 (en) 2014-04-24
EP2714700A1 (en) 2014-04-09
BR112013029852A2 (pt) 2016-12-20
EP2714699A1 (en) 2014-04-09
RU2013157751A (ru) 2015-07-10
WO2012163831A1 (en) 2012-12-06

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Legal Events

Date Code Title Description
B08F Application fees: application dismissed [chapter 8.6 patent gazette]
B11A Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing
B11Y Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired