BR112013011269A2 - produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação - Google Patents

produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação

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Publication number
BR112013011269A2
BR112013011269A2 BR112013011269A BR112013011269A BR112013011269A2 BR 112013011269 A2 BR112013011269 A2 BR 112013011269A2 BR 112013011269 A BR112013011269 A BR 112013011269A BR 112013011269 A BR112013011269 A BR 112013011269A BR 112013011269 A2 BR112013011269 A2 BR 112013011269A2
Authority
BR
Brazil
Prior art keywords
isobutanol
stream
etherification
reactor
butenes
Prior art date
Application number
BR112013011269A
Other languages
English (en)
Portuguese (pt)
Inventor
Cindy Adam
Delphine Minoux
Nikolaï Nesterenko
Original Assignee
Total Raffinage Marketing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Raffinage Marketing filed Critical Total Raffinage Marketing
Publication of BR112013011269A2 publication Critical patent/BR112013011269A2/pt

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/08Alkenes with four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • C07C11/08Alkenes with four carbon atoms
    • C07C11/09Isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01Preparation of ethers
    • C07C41/05Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/82Phosphates
    • C07C2529/84Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85Silicoaluminophosphates (SAPO compounds)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BR112013011269A 2010-12-21 2011-12-20 produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação BR112013011269A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1060911A FR2969147B1 (fr) 2010-12-21 2010-12-21 Production d'additifs pour carburant par deshydratation et isomerisation squelettique simultanee d'isobutanol sur des catalyseurs acides suivies par une etherification
PCT/EP2011/073413 WO2012084950A1 (en) 2010-12-21 2011-12-20 Production of fuel additives via simultaneous dehydration and skeletal isomerisation of isobutanol on acid catalysts followed by etherification

Publications (1)

Publication Number Publication Date
BR112013011269A2 true BR112013011269A2 (pt) 2016-11-01

Family

ID=44260184

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013011269A BR112013011269A2 (pt) 2010-12-21 2011-12-20 produção de aditivos para combustível através da desidratação e isomerização estrutural simultâneas de isobutanol sobre catalisadores ácidos seguido pela eterificação

Country Status (6)

Country Link
US (1) US20130261345A1 (de)
EP (1) EP2655300A1 (de)
CN (1) CN103261129A (de)
BR (1) BR112013011269A2 (de)
FR (1) FR2969147B1 (de)
WO (1) WO2012084950A1 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106278788B (zh) * 2015-05-22 2018-11-02 中国石油化工股份有限公司 一种以混合醇生产甲基叔丁基醚和/或异丁烯的方法
EP3162763A1 (de) * 2015-10-30 2017-05-03 Total Research & Technology Feluy SA Gleichzeitige dehydrierung und skelettisomerisierung von isobutanol auf ti-haltigen zeolithkatalysatoren
CN107987898A (zh) * 2017-12-01 2018-05-04 山东滨州裕华化工厂有限公司 一种乙醇汽油及其制备方法
CN112898121A (zh) * 2021-01-23 2021-06-04 四川上氟科技有限公司 一种全氟烷基乙醇的制备方法
FR3135265A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé d’obtention d’hydrocarbures, et installation associée
FR3135263A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur comprenant une étape de conversion d’un flux d’alcool dans un lit fluidisé, carburéacteur et installation associés
FR3135264A1 (fr) * 2022-05-06 2023-11-10 Totalenergies Onetech Procédé de fabrication d’un carburéacteur, carburéacteur et installation associés

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IT1012686B (it) 1974-05-21 1977-03-10 Snam Progetti Procedimento per la preparazione di eteri ter alchilici
US4071567A (en) 1974-05-21 1978-01-31 Snamprogetti S.P.A. Process for the production of methyl tert-butyl ether
DE2629769B2 (de) 1976-07-02 1980-03-13 Chemische Werke Huels Ag, 4370 Marl Verfahren zur Herstellung von reinem Methyl-tertiär-butyläther
DE2706465C3 (de) 1977-02-16 1980-10-02 Deutsche Texaco Ag, 2000 Hamburg Verfahren zur Gewinnung von Butadien bzw. n-Butenen aus diese enthaltenden Kohlenwasserstoffgemischen unter Abtrennung von Isobuten
NL7803135A (nl) 1978-03-23 1979-09-25 Shell Int Research Werkwijze ter bereiding van tertiaire alkyl- ethers.
DE2967531D1 (en) 1978-07-27 1985-11-21 Chemical Res & Licensin Catalytic distillation process and catalyst
US4469911A (en) 1980-10-23 1984-09-04 Petro Tex Chemical Corporation Isobutene removal from C4 streams
DE4013711A1 (de) 1990-04-28 1991-10-31 Erdoelchemie Gmbh Verfahren zur herstellung von hochoktanigen, olefinarmen kraftstoffen und kraftstoffkomponenten
ZA966107B (en) * 1995-07-21 1997-02-03 Shell Int Research Dehydration of primary alcohols.
US5895830A (en) 1995-12-15 1999-04-20 Uop Llc Process for oligomer production and saturation
US5877372A (en) 1997-11-21 1999-03-02 Arco Chemical Technology, L.P. Isobutylene oligomerization using isooctane diluent
US6689927B1 (en) 2001-05-07 2004-02-10 Uop Lcc Process for oligomer production and saturation
US6768035B2 (en) * 2002-01-31 2004-07-27 Chevron U.S.A. Inc. Manufacture of high octane alkylate
DE10302457B3 (de) 2003-01-23 2004-10-07 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Butenoligomeren und tert.-Butylethern aus Isobuten-haltigen C4-Strömen
US6977318B2 (en) 2004-05-04 2005-12-20 Equistar Chemicals, Lp Propylene production
US20090030239A1 (en) 2006-06-16 2009-01-29 D Amore Michael B Process for making butenes from aqueous isobutanol
US8975047B2 (en) 2006-06-16 2015-03-10 E I Du Pont De Nemours And Company Process for making isooctenes from dry 1-butanol
US20080132741A1 (en) * 2006-06-16 2008-06-05 D Amore Michael B Process for making butenes from dry isobutanol
MX2009011192A (es) 2007-04-18 2009-10-30 Du Pont Produccion fermentativa de isobutanol con el uso de enzimas reductoisomerasas con alta actividad acida y cetolica.
EP2225351A4 (de) * 2007-12-03 2016-11-09 Gevo Inc Erneuerbare zusammensetzungen
EP2401307A4 (de) * 2009-02-24 2015-08-05 Gevo Inc Verfahren für die herstellung von erneuerbarem butadien und erneuerbarem isopren

Also Published As

Publication number Publication date
FR2969147A1 (fr) 2012-06-22
WO2012084950A1 (en) 2012-06-28
US20130261345A1 (en) 2013-10-03
FR2969147B1 (fr) 2013-01-04
CN103261129A (zh) 2013-08-21
EP2655300A1 (de) 2013-10-30

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Legal Events

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]