BR112012001914B1 - processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido - Google Patents

processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido Download PDF

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Publication number
BR112012001914B1
BR112012001914B1 BR112012001914-7A BR112012001914A BR112012001914B1 BR 112012001914 B1 BR112012001914 B1 BR 112012001914B1 BR 112012001914 A BR112012001914 A BR 112012001914A BR 112012001914 B1 BR112012001914 B1 BR 112012001914B1
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BR
Brazil
Prior art keywords
initiator
organic peroxide
carbon atoms
process according
stage
Prior art date
Application number
BR112012001914-7A
Other languages
English (en)
Portuguese (pt)
Inventor
Cochet Jacques
Nicol Pascal
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=41820421&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR112012001914(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Arkema France filed Critical Arkema France
Publication of BR112012001914B1 publication Critical patent/BR112012001914B1/pt

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/18Suspension polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/34Per-compounds with one peroxy-radical
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/28Oxygen or compounds releasing free oxygen
    • C08F4/32Organic compounds
    • C08F4/38Mixtures of peroxy-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0014Use of organic additives
    • C08J9/0023Use of organic additives containing oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/16Making expandable particles
    • C08J9/20Making expandable particles by suspension polymerisation in the presence of the blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02Homopolymers or copolymers of hydrocarbons
    • C08J2325/04Homopolymers or copolymers of styrene
    • C08J2325/06Polystyrene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Emergency Medicine (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polymerisation Methods In General (AREA)
BR112012001914-7A 2009-07-27 2010-07-22 processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido BR112012001914B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US22874009P 2009-07-27 2009-07-27
FR0955241A FR2948375B1 (fr) 2009-07-27 2009-07-27 Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide
PCT/FR2010/051548 WO2011012798A1 (fr) 2009-07-27 2010-07-22 Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide

Publications (1)

Publication Number Publication Date
BR112012001914B1 true BR112012001914B1 (pt) 2019-10-29

Family

ID=41820421

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112012001914-7A BR112012001914B1 (pt) 2009-07-27 2010-07-22 processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido

Country Status (8)

Country Link
US (2) US9040600B2 (https=)
EP (1) EP2459628B1 (https=)
CN (2) CN106432554B (https=)
BR (1) BR112012001914B1 (https=)
FR (1) FR2948375B1 (https=)
IN (1) IN2012DN01357A (https=)
MX (1) MX2012001208A (https=)
WO (1) WO2011012798A1 (https=)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3009561B1 (fr) * 2013-08-06 2017-12-22 Arkema France Procede de preparation de polystyrene expansible noir
FR3057868B1 (fr) * 2016-10-26 2018-10-26 Arkema France Composition a base de monomeres allyliques et de peroxyde(s) pour la fabrication de verres organiques
FR3105229B1 (fr) * 2019-12-18 2022-04-01 Arkema France Procédé de polymérisation d’une suspension aqueuse de styrène à l’aide d’au moins un peroxyde organique hémi-peroxyacétal
FR3110169B1 (fr) * 2020-05-15 2022-08-26 Arkema France Composition comprenant au moins deux peroxydes organiques pour la polymérisation de monomères éthyléniquement insaturés

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10146078A1 (de) * 2001-09-19 2003-04-03 Basf Ag Verfahren zur Herstellung von expandierbarem Polystyrol
US6608150B1 (en) * 2002-10-08 2003-08-19 Atofina Chemicals, Inc. Preparation of expandable styrene polymers
WO2004089999A2 (en) * 2003-04-14 2004-10-21 Akzo Nobel N.V. Dosing of peroxide to a suspension process wherein styrene is polymerized
US20050256216A1 (en) * 2004-05-14 2005-11-17 Berti Douglas A Production of polystyrene for foaming applications using a combination of peroxide initiators
EP2105457B2 (en) * 2008-03-27 2018-10-24 Arkema France Process for the preparation of expandable polystyrene

Also Published As

Publication number Publication date
EP2459628A1 (fr) 2012-06-06
US9040600B2 (en) 2015-05-26
MX2012001208A (es) 2012-03-26
FR2948375A1 (fr) 2011-01-28
US20150210819A1 (en) 2015-07-30
CN102575048A (zh) 2012-07-11
CN106432554A (zh) 2017-02-22
WO2011012798A1 (fr) 2011-02-03
CN106432554B (zh) 2020-07-28
US20120142797A1 (en) 2012-06-07
FR2948375B1 (fr) 2011-12-30
IN2012DN01357A (https=) 2015-06-05
EP2459628B1 (fr) 2014-01-22

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2784 DE 14-05-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.