BR112012001914B1 - processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido - Google Patents
processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido Download PDFInfo
- Publication number
- BR112012001914B1 BR112012001914B1 BR112012001914-7A BR112012001914A BR112012001914B1 BR 112012001914 B1 BR112012001914 B1 BR 112012001914B1 BR 112012001914 A BR112012001914 A BR 112012001914A BR 112012001914 B1 BR112012001914 B1 BR 112012001914B1
- Authority
- BR
- Brazil
- Prior art keywords
- initiator
- organic peroxide
- carbon atoms
- process according
- stage
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/34—Per-compounds with one peroxy-radical
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/28—Oxygen or compounds releasing free oxygen
- C08F4/32—Organic compounds
- C08F4/38—Mixtures of peroxy-compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/141—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
- C08J9/20—Making expandable particles by suspension polymerisation in the presence of the blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
- C08J2325/06—Polystyrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22874009P | 2009-07-27 | 2009-07-27 | |
| FR0955241A FR2948375B1 (fr) | 2009-07-27 | 2009-07-27 | Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide |
| PCT/FR2010/051548 WO2011012798A1 (fr) | 2009-07-27 | 2010-07-22 | Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112012001914B1 true BR112012001914B1 (pt) | 2019-10-29 |
Family
ID=41820421
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112012001914-7A BR112012001914B1 (pt) | 2009-07-27 | 2010-07-22 | processo para a preparação de poliestireno expansível por injeção contínua de um peróxido orgânico líquido |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US9040600B2 (https=) |
| EP (1) | EP2459628B1 (https=) |
| CN (2) | CN106432554B (https=) |
| BR (1) | BR112012001914B1 (https=) |
| FR (1) | FR2948375B1 (https=) |
| IN (1) | IN2012DN01357A (https=) |
| MX (1) | MX2012001208A (https=) |
| WO (1) | WO2011012798A1 (https=) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3009561B1 (fr) * | 2013-08-06 | 2017-12-22 | Arkema France | Procede de preparation de polystyrene expansible noir |
| FR3057868B1 (fr) * | 2016-10-26 | 2018-10-26 | Arkema France | Composition a base de monomeres allyliques et de peroxyde(s) pour la fabrication de verres organiques |
| FR3105229B1 (fr) * | 2019-12-18 | 2022-04-01 | Arkema France | Procédé de polymérisation d’une suspension aqueuse de styrène à l’aide d’au moins un peroxyde organique hémi-peroxyacétal |
| FR3110169B1 (fr) * | 2020-05-15 | 2022-08-26 | Arkema France | Composition comprenant au moins deux peroxydes organiques pour la polymérisation de monomères éthyléniquement insaturés |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10146078A1 (de) * | 2001-09-19 | 2003-04-03 | Basf Ag | Verfahren zur Herstellung von expandierbarem Polystyrol |
| US6608150B1 (en) * | 2002-10-08 | 2003-08-19 | Atofina Chemicals, Inc. | Preparation of expandable styrene polymers |
| WO2004089999A2 (en) * | 2003-04-14 | 2004-10-21 | Akzo Nobel N.V. | Dosing of peroxide to a suspension process wherein styrene is polymerized |
| US20050256216A1 (en) * | 2004-05-14 | 2005-11-17 | Berti Douglas A | Production of polystyrene for foaming applications using a combination of peroxide initiators |
| EP2105457B2 (en) * | 2008-03-27 | 2018-10-24 | Arkema France | Process for the preparation of expandable polystyrene |
-
2009
- 2009-07-27 FR FR0955241A patent/FR2948375B1/fr not_active Expired - Fee Related
-
2010
- 2010-07-22 BR BR112012001914-7A patent/BR112012001914B1/pt not_active IP Right Cessation
- 2010-07-22 EP EP10752074.4A patent/EP2459628B1/fr not_active Revoked
- 2010-07-22 IN IN1357DEN2012 patent/IN2012DN01357A/en unknown
- 2010-07-22 US US13/386,958 patent/US9040600B2/en active Active
- 2010-07-22 CN CN201610833478.1A patent/CN106432554B/zh not_active Expired - Fee Related
- 2010-07-22 MX MX2012001208A patent/MX2012001208A/es unknown
- 2010-07-22 WO PCT/FR2010/051548 patent/WO2011012798A1/fr not_active Ceased
- 2010-07-22 CN CN2010800429750A patent/CN102575048A/zh active Pending
-
2015
- 2015-04-10 US US14/683,238 patent/US20150210819A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP2459628A1 (fr) | 2012-06-06 |
| US9040600B2 (en) | 2015-05-26 |
| MX2012001208A (es) | 2012-03-26 |
| FR2948375A1 (fr) | 2011-01-28 |
| US20150210819A1 (en) | 2015-07-30 |
| CN102575048A (zh) | 2012-07-11 |
| CN106432554A (zh) | 2017-02-22 |
| WO2011012798A1 (fr) | 2011-02-03 |
| CN106432554B (zh) | 2020-07-28 |
| US20120142797A1 (en) | 2012-06-07 |
| FR2948375B1 (fr) | 2011-12-30 |
| IN2012DN01357A (https=) | 2015-06-05 |
| EP2459628B1 (fr) | 2014-01-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B06T | Formal requirements before examination [chapter 6.20 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/07/2010, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/07/2010, OBSERVADAS AS CONDICOES LEGAIS |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 14A ANUIDADE. |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2784 DE 14-05-2024 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |