GB877864A - Flame retardant or self-extinguishing polymer compositions and method for their production - Google Patents
Flame retardant or self-extinguishing polymer compositions and method for their productionInfo
- Publication number
- GB877864A GB877864A GB24900/58A GB2490058A GB877864A GB 877864 A GB877864 A GB 877864A GB 24900/58 A GB24900/58 A GB 24900/58A GB 2490058 A GB2490058 A GB 2490058A GB 877864 A GB877864 A GB 877864A
- Authority
- GB
- United Kingdom
- Prior art keywords
- peroxide
- polymer
- polymers
- flame
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0023—Use of organic additives containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2325/02—Homopolymers or copolymers of hydrocarbons
- C08J2325/04—Homopolymers or copolymers of styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Emergency Medicine (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A flame-proof polymer composition comprises a halogen-containing flame-proofing agent, an organic peroxide in a proportion which enhances the effect of the halogen compound and, in the preferred embodiment of the invention, a volatile organic compound as foaming agent. The compositions may be obtained by dry blending, or by incorporation of the other ingredients into a melt, solution, gel, dispersion or emulsion of the polymer, or any or all of the composition components may be added during or before polymerization of the monomer, in which case the peroxide used as synergist must be a stable compound under the polymerization conditions. Particular compositions specified are those containing polymers and copolymers of alkenyl aromatic monomers, especially polymers of styrene, including cross-linked polymers, e.g. with divinyl benzene. Many organic peroxides are specified and those preferred are dicumyl and di-t-butyl peroxides, and di-t-butyl perphthalate, peracetate and perbenzoate. The exemplified halogen compounds include many bromine organic compounds, e.g. tetrabromoethane, dibromotetrachloroethane, tris (dibromopropyl) phosphate, pentabromomonochlorocyclohexane, ammonium bromide, and such materials as chlorinated paraffin and diiodomethane. The foaming agents disclosed are the pentanes, the butanes, hexane, heptane, petroleum ether, various perchlorofluorocarbons, methyl or ethyl chloride, dimethyl ether, methyl ethyl ether, butylene and propylene. Optional composition ingredients are inhibitors of corrosion when ammonium bromide is used, and specified are tris (nonylphenyl) phosphate, diethylamine salts of octylphenyl esters of phosphoric acid, salts of N-alkyl-b -aminobutyric acid and di (sec-butyl) phenyl monoethers of polyethylene glycols. Polymerization of monomer in the presence of composition components may be effected in mass or in aqueous dispersion in the presence of conventional ingredients such as benzoyl, acetyl, di-t-butyl or lauroyl peroxide, preformed polymers, potassium dichromate, polyvinyltoluene sulphonic acid sodium salt, sodium sulphate, sodium hydroxide and sodium lauryl sulphate. Foamed products may be prepared, (a) by forming a flowable gel of polymer and gaseous blowing agent, maintaining under pressure while the peroxide and flameproofing agent are incorporated and then extruding the gel into a low-pressure area, or (b) heat-blending the polymer with a saturated hydrocarbon or a chlorofluorocarbon and mixing the flowable gel with the flameproofing agent and organic peroxide, e.g. at 60 DEG -150 DEG C., extruding into a low-pressure and rapidly cooling; the composition may then be granulated and moulded to a foamed article, or (c) by polymerizing p the monomer in the presence of a volatile organic compound which is a non-solvent for the polymer obtained, the reaction preferably being effected in water or brine whereby latent-foaming beads may be obtained, or (d) by steeping or heating granules of polymer with the other composition ingredients while suspended in a non-solvent medium such as water, brine or aqueous solutions of alcohols, glycols or ketones. In a modification of the process for obtaining flame-proofed products, the shaped polymers, e.g. beads, pellicles, or expandable granules, are coated with a filmforming latex containing the peroxide and the flame-proofing agent. The products of the invention may be an admixture or a reaction product and may be formed into boards, rods, planks, floats, toys and ornaments.ALSO:Shaped polymers, particularly granules of polymers of alkenyl aromatic monomers-optionally expandable-are coated with a film-forming latex comprising a halogen-containing flame proofing agent and an organic peroxide in a proportion which enhances the effect of the halogen compound. Film-forming latices specified are those of butadiene/styrene copolymers, polybutadiene, vinylidine chloride/vinyl chloride copolymers, polyvinyl acetate, acrylate/methacrylate copolymers and butadiene/acrylonitrile copolymers. The flame proofing agent may be chlorinated paraffin, diiodomethane, ammonium bromide, tetrabromoethane, dibromotetrachloroethane, tris (dibromopropyl) phosphate, pentabromomonochlorocyclohexane or one of the many other specified bromo-organic compounds. Of the specified peroxides, dicumyl peroxide is preferred. In a modification the film-forming latex itself may be brominated to act as the flame-proofing agent and exemplified are the brominated latices of styrene/butadiene copolymers, styrene/butadiene/divinyl benzene copolymers, polyvinyl toluene and polystyrene. Thickening agents such as polyvinyl alcohol, polyacrylic acid and salts thereof, ammonium caseinate, carboxymethyl cellulose and salts thereof and methocel, are desirably included. A surface active agent also may be present. The coated beads obtained may be moulded to produce flame-proof products, optionally expanded. Preferred shaped polymers are those derived from styrene, ethyl vinyl benzene, vinyl toluene, vinyl xylene, isopropylstyrene, t-butylstyrene, chlorostyrene with or without acrylonitrile, methyl methacrylate or natural or synthetic rubber.ALSO:A flame-proof polymer composition comprises a halogen containing flame proofing agent, an organic peroxide in a proportion which enhances the effect of the halogen compound and in the preferred embodiment of the invention a volatile organic compound as foaming agent. The compositions may be obtained by dry blending, or by incorporation of the other ingredients into a melt, solution, gel, dispersion or emulsion of the polymer, or any or all of the composition components may be added during or before polymerization of the monomer, in which case the peroxide used as synergist must be a stable compound under the polymerization conditions. Particular compositions specified are those containing polymers and copolymers of alkenyl aromatic monomers, especially polymers of styrene, including cross-linked polymers, e.g. with divinyl benzene. Many organic peroxides are specified and those preferred are dicumyl and di-t-butyl peroxides, and di-t-butyl perphthalate, peracetate and perbenzoate. The exemplified halogen compounds include many bromine organic compounds, e.g. tetrabromoethane, dibromotetrachloroethane, tris (dibromopropyl) phosphate, pentabromomonochlorocyclohexane, ammonium bromide, and such materials as chlorinated paraffin and diiodomethane. The foaming agents disclosed are the pentanes, the butanes, hexane, heptane, petroleum ether, various perchlorofluorocarbons, methyl or ethyl chloride, dimethyl ether, methyl ethyl ether, butylene and propylene. Optional composition ingredients are inhibitors of corrosion when ammonium bromide is used and specified are tris (nonylphenyl) phosphate, diethylamine salts of octylphenyl esters of phosphoric acid, salts of N-alkyl-b -amino-butyric acid and di(sec -butyl) phenyl monoethers of polyethylene glycols. Polymerization of monomer in the presence of composition components may be effected in mass or in aqueous dispersion in the presence of conventional ingredients such as benzoyl, acetyl di-t-butyl or lauroyl peroxide, preformed polymers, potassium dichromate, polyvinyltoluene sulphonic acid sodium salt, sodium sulphate, sodium hydroxide and sodium lauryl sulphate. Foamed products may be prepared, (A) by forming a flowable gel of polymer + gaseous blowing agent, maintianing under pressure while the peroxide and flameproofing agent are incorporated and then extruding the gel into a low pressure area, or (B) heat-blending the polymer with a saturated hydrocarbon or a chlorofluorocarbon and mixing the flowable gel with the flameproofing agent and organic peroxide, e.g. at 60 DEG -150 DEG C., extruding into a low pressure and rapidly cooling; the composition may then be granulated and moulded to a foamed article, or (C) by polymerizing the monomer in the presence of a volatile organic compound which is a non-solvent for the polymer obtained, the reaction preferably being effected in water or brine whereby latent-foaming beads may be obtained, or (D) by steeping or heating granules of polymer with the other composition ingredients while suspended in a non-solvent medium such as water, brine, or aqueous solutions of alcohols, glycols or ketones. In a modification of the process for obtaining flame-proofed products the shaped polymers, e.g. beads, pellicles, or expandable granules, are coated with a film forming latex containing the peroxide and the flameproofing agent. The products of the invention may be an admixture or a reaction product and may be formed into boards, rods, planks, floats, toys and ornaments.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US75083858A | 1958-07-24 | 1958-07-24 | |
US75055858A | 1958-07-24 | 1958-07-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB877864A true GB877864A (en) | 1961-09-20 |
Family
ID=27115294
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB24900/58A Expired GB877864A (en) | 1958-07-24 | 1959-07-20 | Flame retardant or self-extinguishing polymer compositions and method for their production |
Country Status (8)
Country | Link |
---|---|
BE (1) | BE580958A (en) |
BR (1) | BR5911994D0 (en) |
CA (1) | CA667626A (en) |
DE (2) | DE1288306B (en) |
GB (1) | GB877864A (en) |
IT (1) | IT612628A (en) |
LU (1) | LU37464A1 (en) |
NL (1) | NL114127C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011087384A1 (en) * | 2010-01-14 | 2011-07-21 | Termo Organika Sp. Z O.O. | Styrene polymers and method of preparing styrene polymers |
US10059791B2 (en) | 2013-12-11 | 2018-08-28 | Ineos Styrolution Group Gmbh | ABS product with improved fire retardancy |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2906336C3 (en) * | 1979-02-19 | 1982-01-07 | Chemische Werke Hüls AG, 4370 Marl | Finely divided, self-extinguishing, expandable styrene polymers |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA570583A (en) * | 1959-02-10 | Badische Anilin- And Soda-Fabrik Aktiengesellschaft | Difficultly inflammable styrene polymers and the production of the same |
-
0
- LU LU37464D patent/LU37464A1/xx unknown
- CA CA667626A patent/CA667626A/en not_active Expired
- IT IT612628D patent/IT612628A/it unknown
- BE BE580958D patent/BE580958A/xx unknown
-
1959
- 1959-07-20 GB GB24900/58A patent/GB877864A/en not_active Expired
- 1959-07-23 BR BR111994/59A patent/BR5911994D0/en unknown
- 1959-07-24 DE DED31136A patent/DE1288306B/en not_active Ceased
- 1959-07-24 DE DE1959D0051769 patent/DE1273187C2/en not_active Expired
- 1959-07-24 NL NL241644A patent/NL114127C/en active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011087384A1 (en) * | 2010-01-14 | 2011-07-21 | Termo Organika Sp. Z O.O. | Styrene polymers and method of preparing styrene polymers |
US10059791B2 (en) | 2013-12-11 | 2018-08-28 | Ineos Styrolution Group Gmbh | ABS product with improved fire retardancy |
Also Published As
Publication number | Publication date |
---|---|
DE1273187B (en) | 1968-07-18 |
NL114127B (en) | 1968-10-15 |
IT612628A (en) | |
LU37464A1 (en) | |
DE1273187C2 (en) | 1976-03-11 |
BR5911994D0 (en) | 1973-04-17 |
CA667626A (en) | 1963-07-30 |
DE1288306B (en) | 1969-01-30 |
NL114127C (en) | 1973-10-15 |
BE580958A (en) |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR100492199B1 (en) | Method for Producing Expandable Styrene Polymers Containing Graphite Particles | |
US3050476A (en) | Method of making a self extinguishing expandable polymer of styrene by bromination | |
US20040039073A1 (en) | Expandable styrene polymers containing carbon particles | |
US3058929A (en) | Method of polymerizing a vinyl aromatic monomer in the presence of an organic bromide and an organic peroxide and a self-extinguishing vinyl aromatic polymer containing same | |
KR20010071028A (en) | Method for producing expandable styrene polymers containing exfoliated graphite particles | |
GB854347A (en) | Difficultly inflammable styrene polymer compositions and their production | |
US3639302A (en) | Flame-retardant resin compositions | |
US4286071A (en) | Self-extinguishing fine particulate expandable styrene polymers | |
JP5060001B2 (en) | Styrenic expandable resin particles and molded foam | |
US3361687A (en) | Self-extinguishing finely divided expandable plastics compositions | |
GB877864A (en) | Flame retardant or self-extinguishing polymer compositions and method for their production | |
GB1453992A (en) | Particulate expandable self-extinguishing styrene polymers showing good processability | |
JPH08311281A (en) | Production of particulate flame-retardant cellular polystyrene material containing recovered cellular polystyrene material | |
US4326044A (en) | Fire-retardant monocarboxylic acid copolymers | |
US3721634A (en) | Polymerization process | |
JP2003064212A (en) | Foamable polystyrene-based resin particle and foam molding of polystyrene-based resin | |
US3576770A (en) | Flame-retardant resin compositions | |
KR101353627B1 (en) | Process for preparing expandable styrene polymers | |
US4277567A (en) | Flame-retardant vinyl aromatic polymer compositions | |
JPS5858372B2 (en) | Method for producing foamable self-extinguishing thermoplastic resin particles | |
KR20160072411A (en) | Expandable polystyrene beads having excellent thermal insulation, flame retardancy and good moldability and a method of manufacturing the same | |
JPS5841302B2 (en) | Expandable polystyrene resin composition with flame retardancy | |
US3507816A (en) | Foamable polymers containing a flame retardant | |
US3178377A (en) | Expandable thermoplastic polymeric material | |
US4304874A (en) | Fire-retardant anhydride copolymers |