BR0315926A - Uso de compostos de complexo de metal como catalisadores para oxidação usando-se oxigênio molecular ou ar - Google Patents
Uso de compostos de complexo de metal como catalisadores para oxidação usando-se oxigênio molecular ou arInfo
- Publication number
- BR0315926A BR0315926A BR0315926-4A BR0315926A BR0315926A BR 0315926 A BR0315926 A BR 0315926A BR 0315926 A BR0315926 A BR 0315926A BR 0315926 A BR0315926 A BR 0315926A
- Authority
- BR
- Brazil
- Prior art keywords
- alkylene
- unsubstituted
- metal complex
- substituted
- air
- Prior art date
Links
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title abstract 3
- 229910001882 dioxygen Inorganic materials 0.000 title abstract 3
- -1 metal complex compounds Chemical class 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/168—Organometallic compounds or orgometallic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Detergent Compositions (AREA)
- Pyridine Compounds (AREA)
Abstract
"USO DE COMPOSTOS DE COMPLEXO DE METAL COMO CATALISADORES PARA OXIDAçãO USANDO-SE OXIGêNIO MOLECULAR OU AR". A presente invenção refere-se ao uso, como o de um catalisador para reações de oxidação usando-se oxigênio molecular e/ou ar, de pelo menos um composto de complexo de metal da fórmula (1): ¢L~ n~Me~ m~X~ p~!¬ z¬Y~ q~ (1), em que Me é manganês, titânio, ferro, cobalto, níquel ou cobre, X é um radical de coordenação ou ligação em ponte, n e m são, cada um independentemente um do outro, um número inteiro tendo um valor de 1 a 8, p é um número inteiro tendo um valor de O a 32, z é a carga do complexo de metal, Y é um contra-íon, q = z/(carga de Y) e L é um ligante da fórmula (2): (2), em que: R~ 1~, R~ 2~, R~ 3~, R~ 4~, R~ 5, R~ 6~, R~ 7~, R~ 8~, R~ 9~, R~ 10~ e R~ 11~ são, cada um independentemente uns dos outros, hidrogênio; C~ 1~-C~ 18~alquila ou arila nãosubstituída ou substituída; ciano; halogênio; nitro; -COOR~ 12~ OU -SO~ 3~R~ 12~ em que R~ 12~ é, em cada caso, hidrogênio, um cátion ou C~ 1-C~ 18~alquila ou arila não-substituída ou substituída; -SR~ 13~, -SO~ 2~R~ 13~ ou -OR~ 13~ em que R~ 13~ é, em cada caso, hidrogênio ou C~ 1~-C~ 18~alquila ou arila não-substituída ou substituída; -NR~ 14~R~ 15~; -(C~ 1~-C~ 6~alquileno)-NR~ 14~R~ 15~; -N<sym>R~ 14~R~ 15~R~ 16~; -(C~ 1~-C~ 6~alquileno)N<sym>R~ 14~R~ 15~R~ 16~; -N(R~ 13~)-(C~ 1~-C~ 6~alquileno)-NR~ 14~R~ 15~; -N¢(C~ 1~-C~ 6~alquileno)-NR~ 14~R~ 15~!~ 2~; -N(R~ 13~)-(C~ 1~-C~ 6~alquileno)N<sym>R~ 14~R~ 15~R~ 16~; -N¢C~ 1~-C~ 6~alquileno)-N<sym>R~ 14~R~ 15~R~ 16~!~ 2~; -N(R~ 13~)-N-R~ 14~R~ 15~ or -N(R~ 13~)N<sym>R~ 14~R~ 15~R~ 16~, em que R~ 13~ é conforme definido acima e R~ 14~, R~ 15~ e R~ 16~ são, cada um independentemente uns dos outros, hidrogênio ou C~ 1~-C~ 18~alquila ou arila não-substituída ou substituída ou R~ 14~ e R~ 15~, junto com o átomo de nitrogênio que liga os mesmos, formam um anel de 5,6 ou 7 elementos nãosubstituídos ou substituídos o qual pode conter outros heteroátomos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405922 | 2002-10-29 | ||
| PCT/EP2003/011635 WO2004039933A1 (en) | 2002-10-29 | 2003-10-21 | Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0315926A true BR0315926A (pt) | 2005-09-20 |
Family
ID=32187290
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0315926-4A BR0315926A (pt) | 2002-10-29 | 2003-10-21 | Uso de compostos de complexo de metal como catalisadores para oxidação usando-se oxigênio molecular ou ar |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060019853A1 (pt) |
| EP (1) | EP1556468A1 (pt) |
| JP (1) | JP2006504516A (pt) |
| KR (1) | KR20050059312A (pt) |
| CN (1) | CN1708579A (pt) |
| AU (1) | AU2003282041A1 (pt) |
| BR (1) | BR0315926A (pt) |
| MX (1) | MXPA05003957A (pt) |
| WO (1) | WO2004039933A1 (pt) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9930248D0 (en) * | 1999-12-22 | 2000-02-09 | Johnson Matthey Plc | Surface cleaner |
| GB2409207B (en) * | 2003-12-20 | 2006-08-09 | Reckitt Benckiser Nv | Use of metal complex compounds as oxidation catalysts |
| JP2007538120A (ja) * | 2004-05-17 | 2007-12-27 | ヘンケル コマンディットゲゼルシャフト アウフ アクチエン | 場合によりイン・サイチューで生成される漂白増進遷移金属錯体を含む洗剤 |
| DE102004024816A1 (de) * | 2004-05-17 | 2005-12-15 | Henkel Kgaa | Bleichverstärkerkombination für den Einsatz in Wasch- und Reinigungsmitteln |
| DE102007017656A1 (de) * | 2007-04-12 | 2008-10-16 | Henkel Ag & Co. Kgaa | Biheteroaryl-Metallkomplexe als Bleichkatalysatoren |
| EP2135313B1 (en) * | 2007-04-12 | 2011-09-14 | 3M Innovative Properties Company | High performance, high durability non-precious metal fuel cell catalysts |
| EP2103735A1 (en) | 2008-03-18 | 2009-09-23 | Unilever PLC | Catalytic bleaching of substrates |
| WO2010020583A1 (en) * | 2008-08-20 | 2010-02-25 | Basf Se | Improved bleach process |
| CA2782133A1 (en) * | 2009-12-02 | 2011-06-09 | Basf Se | Use of metal complexes as oxygen absorber/scavenger elements for packaging applications |
| CN102584686B (zh) * | 2012-01-11 | 2014-02-12 | 淮海工学院 | 一种水溶性三联吡啶荧光化合物及其制备方法 |
| WO2016052196A1 (ja) * | 2014-09-29 | 2016-04-07 | 富士フイルム株式会社 | 光電変換素子、色素増感太陽電池、金属錯体色素、色素溶液、およびターピリジン化合物またはそのエステル化物 |
| CN105237575A (zh) * | 2015-08-25 | 2016-01-13 | 南阳师范学院 | 一种零维吡啶类配体锰金属磁性配合物及其制备方法 |
| CN105237574B (zh) * | 2015-08-25 | 2018-05-01 | 南阳师范学院 | 一种具有磁性、吸附双功能吡啶类配体锰金属配合物及其制备方法 |
| CN107686478A (zh) * | 2017-09-18 | 2018-02-13 | 东莞理工学院 | 一种三联吡啶衍生物及其合成方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH11999002188B1 (en) * | 1998-09-01 | 2007-08-06 | Unilever Nv | Method of treating a textile |
| ATE300604T1 (de) * | 1999-04-01 | 2005-08-15 | Unilever Nv | Zusammensetzung und verfahren zum bleichen eines substrats |
| WO2000060043A1 (en) * | 1999-04-01 | 2000-10-12 | Unilever Plc | Composition and method for bleaching a substrate |
| GB9930248D0 (en) * | 1999-12-22 | 2000-02-09 | Johnson Matthey Plc | Surface cleaner |
| ES2244484T3 (es) * | 1999-12-22 | 2005-12-16 | Reckitt Benckiser (Uk) Limited | Composiciones fotocataliticas y metodos. |
| WO2002088289A2 (en) * | 2001-04-30 | 2002-11-07 | Ciba Specialty Chemicals Holding Inc. | Use of metal complex compounds as oxidation catalysts |
| JP4643259B2 (ja) * | 2002-07-11 | 2011-03-02 | チバ ホールディング インコーポレーテッド | 金属錯体化合物及びその酸化触媒としての使用 |
-
2003
- 2003-10-21 AU AU2003282041A patent/AU2003282041A1/en not_active Abandoned
- 2003-10-21 MX MXPA05003957A patent/MXPA05003957A/es unknown
- 2003-10-21 BR BR0315926-4A patent/BR0315926A/pt not_active Application Discontinuation
- 2003-10-21 WO PCT/EP2003/011635 patent/WO2004039933A1/en not_active Application Discontinuation
- 2003-10-21 KR KR1020057007307A patent/KR20050059312A/ko not_active Application Discontinuation
- 2003-10-21 CN CNA2003801023034A patent/CN1708579A/zh active Pending
- 2003-10-21 JP JP2004547538A patent/JP2006504516A/ja active Pending
- 2003-10-21 EP EP03773656A patent/EP1556468A1/en not_active Withdrawn
- 2003-10-21 US US10/531,907 patent/US20060019853A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1556468A1 (en) | 2005-07-27 |
| WO2004039933A1 (en) | 2004-05-13 |
| CN1708579A (zh) | 2005-12-14 |
| AU2003282041A1 (en) | 2004-05-25 |
| US20060019853A1 (en) | 2006-01-26 |
| MXPA05003957A (es) | 2005-06-22 |
| KR20050059312A (ko) | 2005-06-17 |
| JP2006504516A (ja) | 2006-02-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR0312694A (pt) | Uso de compostos de complexo de metal como catalisadores de oxidação | |
| BR0315926A (pt) | Uso de compostos de complexo de metal como catalisadores para oxidação usando-se oxigênio molecular ou ar | |
| BRPI0417462A (pt) | uso de compostos de complexo de metal como catalisadores de oxidação | |
| Kulszewicz-Bajer et al. | Synthesis and spectroscopic properties of aniline tetramers. Comparative studies | |
| BR0100318A (pt) | Compostos de uracila e uso dos mesmos | |
| BRPI0506799A (pt) | uso de compostos de complexo metal compreendendo ligandos derivados de s-triazina ou pirimidina de piridina como catalisadores para oxidações com peroxiácidos orgánicos e/ou precursores de peroxiácidos orgánicos e h2o2 | |
| KR950011421A (ko) | 하이드록시페닐-1,3,5-트리아진의 제조방법 | |
| CO5080772A1 (es) | 4-pirimidinil-n-acil-l-fenilalaninas | |
| RO96802B (ro) | Compozitie erbicida lichida | |
| Herres‐Pawlis et al. | A Library of Peralkylated Bis‐guanidine Ligands for Use in Biomimetic Coordination Chemistry | |
| CO5080771A1 (es) | 4-piridinil-n-acil-l-fenilalaninas | |
| TR200000213T2 (tr) | Mikrobisit N-Sülfonilglisin alkiniloksifenemetil amid türevleri | |
| PL360494A1 (en) | Process to prepare sulfonamides | |
| ES2126693T3 (es) | Derivado de triazina, su produccion y su uso. | |
| BRPI0113837B8 (pt) | compostos mutilinas com atividade antimicrobiana e composição farmacêutica que os compreende | |
| BR0317724A (pt) | Derivados de naftiridina e seu uso como fungicidas | |
| Zhou et al. | Tributylphosphine-catalyzed aziridine-based cycloaddition polymerization toward thiacyclic polymers | |
| TR200002851T2 (tr) | MRP1'i inhibe etmek için yöntemler. | |
| TR200002803T2 (tr) | MRP1 inhibe etmek için yöntemler. | |
| BR0215260A (pt) | Inibidores de hiv protease de sulfonamida contendo fenila substituìda heterocìclica de amplo espectro | |
| TR200002804T2 (tr) | MRP1 inhibe etmek için yöntemler | |
| CO4770926A1 (es) | Procedimiento para la preparacion de compuestos 4,6-bis (ariloxi) pirimidina asimetricos | |
| BRPI0512571A (pt) | processo para a preparação de biarildifosfinas assimetricamente substituìdas | |
| ATE302209T1 (de) | Tetraphenylbacteriochlorin-derivate und diese enthaltenden zusammensetzungen | |
| DE60226869D1 (de) | Variolinderivate und ihre verwendung als cytostatika |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B11A | Dismissal acc. art.33 of ipl - examination not requested within 36 months of filing | ||
| B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |