BR0112069A - Compostos bisfosfita, seus complexos de metais e emprego dos compostos e complexos na hidroformilação de olefinas - Google Patents
Compostos bisfosfita, seus complexos de metais e emprego dos compostos e complexos na hidroformilação de olefinasInfo
- Publication number
- BR0112069A BR0112069A BR0112069-7A BR0112069A BR0112069A BR 0112069 A BR0112069 A BR 0112069A BR 0112069 A BR0112069 A BR 0112069A BR 0112069 A BR0112069 A BR 0112069A
- Authority
- BR
- Brazil
- Prior art keywords
- aliphatic
- alicyclic
- heterocyclic
- compounds
- aromatic
- Prior art date
Links
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title 2
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- -1 aliphatic-alicyclic Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000000623 heterocyclic group Chemical group 0.000 abstract 3
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0086—Platinum compounds
- C07F15/0093—Platinum compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Materials For Medical Uses (AREA)
Abstract
"COMPOSTOS BISFOSFITA, SEUS COMPLEXOS DE METAIS E EMPREGO DOS COMPOSTOS E COMPLEXOS NA HIDROFORMILAçãO DE OLEFINAS". A invenção refere-se a bisfosfitas da fórmula geral (I) com R^ 1^, R^ 2^, R^ 3^, R^ 4^, R^ 5^, R^ 6^ = H, radical hidrocarboneto alifático, alicíclico, alifático-alicíclico, heterocíclico, alifático-heterocíclico, aromático, alifático-aromático com 1 até 50 átomos de carbono, F, CI, Br, I, -OR^ 7^, -COR^ 7^, CO~ 2~R^ 7^, -CO~ 2~M, SR^ 7^, -SOR^ 7^. -SO~ 3~M, -SO~ 2~NR^ 7^R^ 8^, N=CR^ 7^R^ 8^, NH~ 2~ em que R^ 1^ até R^ 6^ possuem significado igual ou diferente e podem ser ligados covalentes uns com os outros, R^ 7^, R^ 8^ = H, radical hidrocarboneto alifático ou aromático, substituído ou não-substituído com 1 até 25 átomos de carbono, com significado igual ou diferente, M representa íon de metal alcalino, de metal alcalino-terroso, de amónio, fosfónio, Q representa radical hidrocarboneto bivalente alifático, alicíclico, alifático-alicíclico, heterocíclico, alifático-heterocíclico, aromático, alifático-aromático com 1 até 50 átomos de carbono, W, X representam radicais hidrocarboneto alifáticos, alicíclicos, alifático-alicíclicos, heterocíclicos, alifático-heterocíclicos, aromáticos, alifático-aromáticos com 1 até 50 átomos de carbono, que podem ser iguais ou diferentes ou podem ser ligados covalentes uns com os outros. Além disso, a invenção refere-se a complexos de metais destas bisfosfitas e sua aplicação em reações de hidroformilação.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10031493A DE10031493A1 (de) | 2000-06-28 | 2000-06-28 | Neue Bisphosphitverbindungen und deren Metallkomplexe |
PCT/EP2001/006968 WO2002000670A1 (de) | 2000-06-28 | 2001-06-20 | Bisphosphitverbindungen, deren metallkomplexe und verwendung der verbindungen und komplexe in der olefinhydroformylierung |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0112069A true BR0112069A (pt) | 2003-04-01 |
Family
ID=7647092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0112069-7A BR0112069A (pt) | 2000-06-28 | 2001-06-20 | Compostos bisfosfita, seus complexos de metais e emprego dos compostos e complexos na hidroformilação de olefinas |
Country Status (11)
Country | Link |
---|---|
US (1) | US20030195368A1 (pt) |
EP (1) | EP1294731B1 (pt) |
JP (1) | JP2004501927A (pt) |
CN (1) | CN1449402A (pt) |
AT (1) | ATE259820T1 (pt) |
AU (1) | AU2001278460A1 (pt) |
BR (1) | BR0112069A (pt) |
CA (1) | CA2414123A1 (pt) |
DE (2) | DE10031493A1 (pt) |
ES (1) | ES2214437T3 (pt) |
WO (1) | WO2002000670A1 (pt) |
Families Citing this family (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10058383A1 (de) | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | Neue Phosphininverbindungen und deren Metallkomplexe |
ATE320438T1 (de) | 2002-03-11 | 2006-04-15 | Union Carbide Chem Plastic | Bisphosphit-ligande für carbonylierungsverfahren |
DE10210918B4 (de) | 2002-03-13 | 2004-06-03 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Bisphosphiten |
DE10223593A1 (de) * | 2002-05-27 | 2003-12-11 | Degussa | Hydroxydiphosphine und deren Verwendung in der Katalyse |
BR0313866A (pt) | 2002-08-31 | 2005-07-05 | Oxeno Olefinchemie Gmbh | Processo para a hidroformilação de compostos olefinicamente insaturados, especialmente olefinas na presença de ésteres de ácido carbÈnico cìclicos |
PL206922B1 (pl) | 2002-08-31 | 2010-10-29 | Oxeno Olefinchemie Gmbh | Sposób katalitycznego hydroformylowania związków nienasyconych olefinowo |
AU2003270902A1 (en) | 2002-10-15 | 2004-05-04 | Union Carbide Chemicals And Plastics Technology Corporation | Bis-chelating ligand and use thereof in carbonylation processes |
US6890102B2 (en) * | 2003-04-03 | 2005-05-10 | Kool Wraps, L. L. C. | Gift bag with napped filamentary surface |
US7118276B2 (en) * | 2003-04-03 | 2006-10-10 | Kool Wraps, L.L.C. | Gift bag with napped filamentary surface |
DE10360772A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von Organoacylphosphiten |
DE10360771A1 (de) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von dreiwertigen Organophosphor-Verbindungen |
DE102004013514A1 (de) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Verfahren zur Hydroformylierung von Olefinen in Anwesenheit von neuen phosphororganischen Verbindungen |
DE602005019989D1 (de) | 2004-03-23 | 2010-04-29 | Kuraray Co | Bisphosphit und verfahren zur herstellung einer aldehydverbindung mit dem bisphosphit |
JP4964760B2 (ja) * | 2005-02-25 | 2012-07-04 | 株式会社クラレ | ビスホスファイト、並びに該ビスホスファイトおよび第8〜10族金属化合物を用いたアルデヒド化合物の製造方法 |
DE102005014055A1 (de) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrisch substituierte Phospholankatalysatoren |
DE102005042464A1 (de) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylierungsverfahren unter Zusatz von sterisch gehinderten sekundären Aminen |
US7365234B2 (en) | 2006-03-17 | 2008-04-29 | University Of Kansas | Tuning product selectivity in catalytic hydroformylation reactions with carbon dioxide expanded liquids |
CN101415717B (zh) * | 2006-04-04 | 2012-12-12 | 可乐丽股份有限公司 | 使用双亚磷酸酯和第8-10族金属化合物制备醛的方法以及该双亚磷酸酯 |
DE102006034442A1 (de) * | 2006-07-26 | 2008-01-31 | Oxeno Olefinchemie Gmbh | Katalysatorvorstufe für einen Rh-Komplexkatalysator |
DE102006058682A1 (de) * | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphitliganden für die übergangsmetallkatalysierte Hydroformylierung |
DE102007023514A1 (de) * | 2007-05-18 | 2008-11-20 | Evonik Oxeno Gmbh | Stabile Katalysatorvorstufe von Rh-Komplexkatalysatoren |
DE102008002188A1 (de) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
AU2009313838B2 (en) | 2008-11-14 | 2015-02-05 | University Of Kansas | Polymer-supported transition metal catalyst complexes and methods of use |
DE102011085883A1 (de) * | 2011-11-08 | 2013-05-08 | Evonik Oxeno Gmbh | Neue Organophosphorverbindungen auf Basis von Anthracentriol |
EP2906572B1 (de) * | 2012-10-12 | 2016-11-23 | Evonik Degussa GmbH | Gemische konstitutionsisomerer bisphosphite |
DE102013219508A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemische konstitutionsisomerer Bisphosphite |
DE102013219512A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung |
DE102013219510A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung |
DE102013219506A1 (de) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Unsymmetrisches Bisphosphit |
DE102013214378A1 (de) | 2013-07-23 | 2015-01-29 | Evonik Industries Ag | Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen |
DE102013217166A1 (de) * | 2013-08-28 | 2015-03-05 | Evonik Industries Ag | Verfahren zur Hydroformylierung von ungesättigten Verbindungen durch SILP-Katalyse |
EP3029056B1 (de) | 2014-12-04 | 2018-11-07 | Evonik Degussa GmbH | Bisphosphite die einen unsymmetrischen biaryl-zentral-baustein aufweisen |
DE102015207864A1 (de) * | 2015-04-29 | 2016-11-03 | Evonik Degussa Gmbh | Neue Monophosphitverbindungen mit einer Ethergruppe |
DE102015207860A1 (de) * | 2015-04-29 | 2016-11-03 | Evonik Degussa Gmbh | Neue Monophosphitverbindungen mit einer Methylgruppe |
EP3293191B1 (de) * | 2016-09-07 | 2018-11-14 | Evonik Degussa GmbH | Phosphite mit einem dihydroxyterphenyl |
CN115814833A (zh) * | 2022-11-16 | 2023-03-21 | 北京化工大学 | 低负载量的双金属纳米催化剂、合成方法及其应用 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5312996A (en) * | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
-
2000
- 2000-06-28 DE DE10031493A patent/DE10031493A1/de not_active Withdrawn
-
2001
- 2001-06-20 WO PCT/EP2001/006968 patent/WO2002000670A1/de active IP Right Grant
- 2001-06-20 AT AT01956490T patent/ATE259820T1/de not_active IP Right Cessation
- 2001-06-20 US US10/311,322 patent/US20030195368A1/en not_active Abandoned
- 2001-06-20 EP EP01956490A patent/EP1294731B1/de not_active Expired - Lifetime
- 2001-06-20 AU AU2001278460A patent/AU2001278460A1/en not_active Abandoned
- 2001-06-20 ES ES01956490T patent/ES2214437T3/es not_active Expired - Lifetime
- 2001-06-20 JP JP2002505792A patent/JP2004501927A/ja active Pending
- 2001-06-20 CN CN01814888A patent/CN1449402A/zh active Pending
- 2001-06-20 CA CA002414123A patent/CA2414123A1/en not_active Abandoned
- 2001-06-20 BR BR0112069-7A patent/BR0112069A/pt not_active IP Right Cessation
- 2001-06-20 DE DE50101518T patent/DE50101518D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20030195368A1 (en) | 2003-10-16 |
WO2002000670A1 (de) | 2002-01-03 |
EP1294731A1 (de) | 2003-03-26 |
ATE259820T1 (de) | 2004-03-15 |
DE10031493A1 (de) | 2002-01-10 |
EP1294731B1 (de) | 2004-02-18 |
CN1449402A (zh) | 2003-10-15 |
JP2004501927A (ja) | 2004-01-22 |
ES2214437T3 (es) | 2004-09-16 |
AU2001278460A1 (en) | 2002-01-08 |
CA2414123A1 (en) | 2002-12-23 |
DE50101518D1 (de) | 2004-03-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A, 6A E 7A ANUIDADES. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO PUBLICADO NA RPI 1963 DE 19.08.2008. |