AU2001278460A1 - Bisphosphite compounds, the metal complexes thereof and the use of said compounds and complexes in olefin hydroformylation - Google Patents
Bisphosphite compounds, the metal complexes thereof and the use of said compounds and complexes in olefin hydroformylationInfo
- Publication number
- AU2001278460A1 AU2001278460A1 AU2001278460A AU7846001A AU2001278460A1 AU 2001278460 A1 AU2001278460 A1 AU 2001278460A1 AU 2001278460 A AU2001278460 A AU 2001278460A AU 7846001 A AU7846001 A AU 7846001A AU 2001278460 A1 AU2001278460 A1 AU 2001278460A1
- Authority
- AU
- Australia
- Prior art keywords
- aliphatic
- alicyclic
- heterocyclic
- compounds
- aromatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 title abstract 2
- 239000002184 metal Substances 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title 2
- 150000001336 alkenes Chemical class 0.000 title 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- -1 aliphatic-alicyclic Chemical group 0.000 abstract 3
- 125000003118 aryl group Chemical group 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 125000000623 heterocyclic group Chemical group 0.000 abstract 3
- 125000002723 alicyclic group Chemical group 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/0086—Platinum compounds
- C07F15/0093—Platinum compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/06—Cobalt compounds
- C07F15/065—Cobalt compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65744—Esters of oxyacids of phosphorus condensed with carbocyclic or heterocyclic rings or ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
- C07F9/6574—Esters of oxyacids of phosphorus
- C07F9/65746—Esters of oxyacids of phosphorus the molecule containing more than one cyclic phosphorus atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Materials For Medical Uses (AREA)
Abstract
The invention relates to the bisphosphites of the general formula(I), wherein R1, R2, R3, $4 R5 R6 represent H, an aliphatic, alicyclic, aliphatic-alicyclic, heterocyclic, aliphatic-heterocyclic, aromatic, aliphatic-aromatic hydrocarbon group with 1 to 50 carbon atoms, F, Cl, Br, I, -OR7, -COR7, -CO2R7, -CO2M, -SR7, -SO2R7, -SOR7, -SO3R7, -SO3M, -SO2NR7R8, NR7R8, N=CR7R8, NH2, wherein R1 to R6 are the same or different and can be covalently linked with each other, R7, R8 represent H, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon group with 1 to 25 carbon atoms, which are the same or different, M represents an alkali metal, alkaline earth metal, ammonium, phosphonium ion; Q represents a bivalent, aliphatic alicyclic, aliphatic-alicyclic, heterocyclic, aromatic, aliphatic-aromatic hydrocarbon group with 1 to 50 carbons atoms, W, X represent aliphatic, alicyclic, aliphatic-alicyclic, heterocyclic, aliphatic-heterocyclic, aromatic, aliphatic-aromatic hydrocarbon groups with 1 to 50 carbon atoms, which are the same or different or which are covalently linked each other. The invention further relates to the metal complexes of said bisphosphites and to the use thereof in hydroformylation reactions.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10031493 | 2000-06-28 | ||
DE10031493A DE10031493A1 (en) | 2000-06-28 | 2000-06-28 | New bisphosphite compounds and their metal complexes |
PCT/EP2001/006968 WO2002000670A1 (en) | 2000-06-28 | 2001-06-20 | Bisphosphite compounds, the metal complexes thereof and the use of said compounds and complexes in olefin hydroformylation |
Publications (1)
Publication Number | Publication Date |
---|---|
AU2001278460A1 true AU2001278460A1 (en) | 2002-01-08 |
Family
ID=7647092
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AU2001278460A Abandoned AU2001278460A1 (en) | 2000-06-28 | 2001-06-20 | Bisphosphite compounds, the metal complexes thereof and the use of said compounds and complexes in olefin hydroformylation |
Country Status (11)
Country | Link |
---|---|
US (1) | US20030195368A1 (en) |
EP (1) | EP1294731B1 (en) |
JP (1) | JP2004501927A (en) |
CN (1) | CN1449402A (en) |
AT (1) | ATE259820T1 (en) |
AU (1) | AU2001278460A1 (en) |
BR (1) | BR0112069A (en) |
CA (1) | CA2414123A1 (en) |
DE (2) | DE10031493A1 (en) |
ES (1) | ES2214437T3 (en) |
WO (1) | WO2002000670A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115814833A (en) * | 2022-11-16 | 2023-03-21 | 北京化工大学 | Low-load bimetallic nano-catalyst, synthesis method and application thereof |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10058383A1 (en) | 2000-11-24 | 2002-05-29 | Oxeno Olefinchemie Gmbh | New phosphinin compounds and their metal complexes |
JP4694787B2 (en) | 2002-03-11 | 2011-06-08 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | Novel phosoxophyte ligands and their use in carbonylation processes |
DE10210918B4 (en) | 2002-03-13 | 2004-06-03 | Oxeno Olefinchemie Gmbh | Process for the preparation of bisphosphites |
DE10223593A1 (en) * | 2002-05-27 | 2003-12-11 | Degussa | Hydroxydiphosphines and their use in catalysis |
AU2003253389A1 (en) | 2002-08-31 | 2004-03-19 | Oxeno Olefinchemie Gmbh | Method for the hydroformylation of olefinically unsaturated compounds, especially olefins, in the presence of cyclic carbonic acid esters |
RU2336261C2 (en) | 2002-08-31 | 2008-10-20 | Оксено Олефинхеми Гмбх | Method of catalitic hydrophormilation of higher olefines in presence of cyclic ethers of carbonic acid |
BR0314566A (en) * | 2002-10-15 | 2006-06-27 | Union Carbide Chem Plastic | bis-chelating binder and its use in carbonylation processes |
US6890102B2 (en) | 2003-04-03 | 2005-05-10 | Kool Wraps, L. L. C. | Gift bag with napped filamentary surface |
US7118276B2 (en) * | 2003-04-03 | 2006-10-10 | Kool Wraps, L.L.C. | Gift bag with napped filamentary surface |
DE10360771A1 (en) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Process for the preparation of trivalent organophosphorus compounds |
DE10360772A1 (en) * | 2003-12-23 | 2005-07-28 | Oxeno Olefinchemie Gmbh | Process for the preparation of organoacyl phosphites |
DE102004013514A1 (en) * | 2004-03-19 | 2005-10-06 | Oxeno Olefinchemie Gmbh | Process for the hydroformylation of olefins in the presence of novel organophosphorus compounds |
WO2005090369A1 (en) * | 2004-03-23 | 2005-09-29 | Kuraray. Co., Ltd. | Bisphosphite and process for producing aldehyde compound with the bisphosphite |
JP4964760B2 (en) * | 2005-02-25 | 2012-07-04 | 株式会社クラレ | Bisphosphite and method for producing aldehyde compound using the bisphosphite and Group 8-10 metal compound |
DE102005014055A1 (en) * | 2005-03-23 | 2006-09-28 | Degussa Ag | Unsymmetrically substituted phospholane catalysts |
DE102005042464A1 (en) * | 2005-09-07 | 2007-03-08 | Oxeno Olefinchemie Gmbh | Carbonylation process with the addition of sterically hindered secondary amines |
WO2007109549A2 (en) | 2006-03-17 | 2007-09-27 | University Of Kansas | Tuning product selectivity in catalytic hyroformylation reactions with carbon dioxide expanded liquids |
CA2649019C (en) | 2006-04-04 | 2014-07-08 | Kuraray Co., Ltd. | Method for producing aldehyde using bisphosphite and group 8-10 metal compound, and such bisphosphite |
DE102006034442A1 (en) * | 2006-07-26 | 2008-01-31 | Oxeno Olefinchemie Gmbh | Catalyst precursor for a Rh complex catalyst |
DE102006058682A1 (en) * | 2006-12-13 | 2008-06-19 | Evonik Oxeno Gmbh | Bisphosphite ligands for transition metal-catalyzed hydroformylation |
DE102007023514A1 (en) * | 2007-05-18 | 2008-11-20 | Evonik Oxeno Gmbh | Stable catalyst precursor of Rh complex catalysts |
DE102008002188A1 (en) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Process for the separation of 1-butene from C4-containing hydrocarbon streams by hydroformylation |
AU2009313838B2 (en) | 2008-11-14 | 2015-02-05 | University Of Kansas | Polymer-supported transition metal catalyst complexes and methods of use |
DE102011085883A1 (en) * | 2011-11-08 | 2013-05-08 | Evonik Oxeno Gmbh | New organophosphorus compounds based on anthracentriol |
DE102013219510A1 (en) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Mixture, useful as a catalyst in a hydroformylation reaction of unsaturated compounds, comprises a combination of two substituted bis(6-phenoxybenzo(d)(1,3,2)benzodioxaphosphepine) compounds |
JP2015536302A (en) * | 2012-10-12 | 2015-12-21 | エボニック インダストリーズ アクチエンゲゼルシャフトEvonik Industries AG | Long time stable method for producing C5 aldehyde |
DE102013219512A1 (en) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Mixture useful as a catalyst for hydroformylating an unsaturated compound or its mixture, comprises bisphosphite compounds which are not identical |
DE102013219508A1 (en) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | Mixture useful as a catalyst for hydroformylating unsaturated compound or its mixture, comprises e.g. 6,6'-(3,3'-di-tert-butyl-5,5'-dimethoxybiphenyl-2,2'-diyl)bis(oxy)bis(2,4,8,10-tetramethyldibenzo(d,f)(1,3,2)dioxaphosphepine) |
DE102013219506A1 (en) | 2012-10-12 | 2014-04-17 | Evonik Degussa Gmbh | New 4,8-di-tert-butyl-2,10-dimethoxy-6-(3,3',5,5'-tetramethyl-2'-(2,4,8,10-tetramethyldibenzo(d,f)(1,3,2)dioxaphosphepin-6-yloxy)biphenyl-2-yloxy)dibenzo(d,f)(1,3,2)dioxaphosphepine useful as catalyst to hydroformylate unsaturated compound |
DE102013214378A1 (en) | 2013-07-23 | 2015-01-29 | Evonik Industries Ag | Phosphoramidite derivatives in the hydroformylation of olefin-containing mixtures |
DE102013217166A1 (en) * | 2013-08-28 | 2015-03-05 | Evonik Industries Ag | Process for the hydroformylation of unsaturated compounds by SILP catalysis |
ES2733102T3 (en) | 2014-12-04 | 2019-11-27 | Evonik Operations Gmbh | Bisphosphites presenting a central component of asymmetric biaryl |
DE102015207864A1 (en) * | 2015-04-29 | 2016-11-03 | Evonik Degussa Gmbh | New monophosphite compounds with an ether group |
DE102015207860A1 (en) * | 2015-04-29 | 2016-11-03 | Evonik Degussa Gmbh | New monophosphite compounds with a methyl group |
EP3293191B1 (en) * | 2016-09-07 | 2018-11-14 | Evonik Degussa GmbH | Phosphites with a dihydroxyterphenyl |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5312996A (en) * | 1992-06-29 | 1994-05-17 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process for producing 1,6-hexanedials |
-
2000
- 2000-06-28 DE DE10031493A patent/DE10031493A1/en not_active Withdrawn
-
2001
- 2001-06-20 WO PCT/EP2001/006968 patent/WO2002000670A1/en active IP Right Grant
- 2001-06-20 AU AU2001278460A patent/AU2001278460A1/en not_active Abandoned
- 2001-06-20 CN CN01814888A patent/CN1449402A/en active Pending
- 2001-06-20 US US10/311,322 patent/US20030195368A1/en not_active Abandoned
- 2001-06-20 CA CA002414123A patent/CA2414123A1/en not_active Abandoned
- 2001-06-20 DE DE50101518T patent/DE50101518D1/en not_active Expired - Fee Related
- 2001-06-20 AT AT01956490T patent/ATE259820T1/en not_active IP Right Cessation
- 2001-06-20 ES ES01956490T patent/ES2214437T3/en not_active Expired - Lifetime
- 2001-06-20 EP EP01956490A patent/EP1294731B1/en not_active Expired - Lifetime
- 2001-06-20 BR BR0112069-7A patent/BR0112069A/en not_active IP Right Cessation
- 2001-06-20 JP JP2002505792A patent/JP2004501927A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN115814833A (en) * | 2022-11-16 | 2023-03-21 | 北京化工大学 | Low-load bimetallic nano-catalyst, synthesis method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
DE10031493A1 (en) | 2002-01-10 |
US20030195368A1 (en) | 2003-10-16 |
CA2414123A1 (en) | 2002-12-23 |
BR0112069A (en) | 2003-04-01 |
WO2002000670A1 (en) | 2002-01-03 |
CN1449402A (en) | 2003-10-15 |
JP2004501927A (en) | 2004-01-22 |
ES2214437T3 (en) | 2004-09-16 |
EP1294731B1 (en) | 2004-02-18 |
ATE259820T1 (en) | 2004-03-15 |
DE50101518D1 (en) | 2004-03-25 |
EP1294731A1 (en) | 2003-03-26 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MK4 | Application lapsed section 142(2)(d) - no continuation fee paid for the application |