BR0109195A - Processos de separação - Google Patents

Processos de separação

Info

Publication number
BR0109195A
BR0109195A BR0109195-6A BR0109195A BR0109195A BR 0109195 A BR0109195 A BR 0109195A BR 0109195 A BR0109195 A BR 0109195A BR 0109195 A BR0109195 A BR 0109195A
Authority
BR
Brazil
Prior art keywords
phase
polar
reaction
product fluid
separation
Prior art date
Application number
BR0109195-6A
Other languages
English (en)
Other versions
BR0109195B1 (pt
Inventor
Jeffrey Scott Kanel
David Robert Bryant
Brian Michael Roesch
Ailene Gardner Phillips
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of BR0109195A publication Critical patent/BR0109195A/pt
Publication of BR0109195B1 publication Critical patent/BR0109195B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
    • B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/18—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

"PROCESSOS DE SEPARAçãO". Esta invenção se refere a um processo para separar um ou mais produtos de um fluido produto de reação compreendendo um catalisador de complexo de metal - ligante de organofósforo, opcionalmente ligante de organofósforo livre, o dito um ou mais produtos, um ou mais solventes de reação apolares e um ou mais solventes de reação polares, em que o dito fluido produto de reação apresenta um comportamento de fases ilustrado pela Figura 1, em que o dito processo compreende (1) suprir o dito fluido produto de reação de uma zona reacional a uma zona de separação, (2) controlar a concentração do dito um ou mais solventes de reação apolares e o do dito um ou mais solventes de reação polares, a temperatura e a pressão na zona de separação suficientes para obter, por separação de fases, duas fases líquidas imiscíveis ilustradas pelas regiões 2, 4 e 6 da Figura 1, compreendendo uma fase polar e uma fase apolar, e impedir ou minimizar a formação de três fases líquidas imiscíveis ilustradas pela região 5 da Figura 1 e uma fase líquida homogênea ilustrada pelas regiões 1, 3 e 7 da Figura 1, e (3) recuperar a dita fase polar da dita fase apolar ou a dita fase apolar da dita fase polar.
BRPI0109195-6A 2000-03-15 2001-03-14 processo para separar um ou mais produtos de um fluido produto de reação compreendendo um catalisador de complexo de metal-ligante de organofósforo. BR0109195B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/526,039 US6307109B1 (en) 2000-03-15 2000-03-15 Separation processes
US09/526.039 2000-03-15
PCT/US2001/040286 WO2001068247A2 (en) 2000-03-15 2001-03-14 Separation of reaction products containing organophosphorus complexes

Publications (2)

Publication Number Publication Date
BR0109195A true BR0109195A (pt) 2004-07-06
BR0109195B1 BR0109195B1 (pt) 2012-01-24

Family

ID=24095670

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0109195-6A BR0109195B1 (pt) 2000-03-15 2001-03-14 processo para separar um ou mais produtos de um fluido produto de reação compreendendo um catalisador de complexo de metal-ligante de organofósforo.

Country Status (13)

Country Link
US (1) US6307109B1 (pt)
EP (1) EP1265832B1 (pt)
JP (1) JP2003526688A (pt)
KR (1) KR100693774B1 (pt)
CN (1) CN1212293C (pt)
AU (1) AU2001253850A1 (pt)
BR (1) BR0109195B1 (pt)
CA (1) CA2402892A1 (pt)
DE (1) DE60138692D1 (pt)
IN (1) IN2002CH01451A (pt)
MX (1) MXPA02009079A (pt)
RU (1) RU2002127587A (pt)
WO (1) WO2001068247A2 (pt)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1532094A1 (de) 2002-08-31 2005-05-25 Oxeno Olefinchemie GmbH Verfahren zur hydroformylierung von olefinisch ungesättigten verbindungen, insbesondere olefinen in gegenwart cyclischer kohlensäureester
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
KR101287661B1 (ko) 2004-08-02 2013-07-24 다우 테크놀로지 인베스트먼츠 엘엘씨. 히드로포르밀화 공정의 안정화
WO2007046799A1 (en) 2005-10-18 2007-04-26 Invista Technologies S.A R.L. Process of making 3-aminopentanenitrile
EP2395010B1 (en) 2006-03-17 2016-07-13 Invista Technologies S.à.r.l. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7892498B2 (en) * 2007-03-08 2011-02-22 Eastman Chemical Company Polyester production system employing an unagitated esterification reactor
CN101657407B (zh) * 2007-03-20 2014-02-12 陶氏技术投资有限公司 改善对产物同分异构体的控制的加氢甲酰基化方法
CN101687658B (zh) 2007-05-14 2013-07-24 因温斯特技术公司 高效反应器和方法
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
CN101918356B (zh) 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
CN101910119B (zh) 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
CN102177122B (zh) 2008-10-14 2013-12-11 因温斯特技术公司 用于制备2-仲烷基-4，5-二-(正烷基)苯酚的方法
EP2414314B1 (en) 2009-03-31 2017-09-13 Dow Technology Investments LLC Hydroformylation process with triphenylphosphine and a doubly open-ended bisphosphite ligand
UA104324C2 (ru) 2009-06-26 2014-01-27 Басф Се Способ получения муравьиной кислоты
WO2011017543A1 (en) 2009-08-07 2011-02-10 Invista Technologies S.A. R.L. Hydrogenation and esterification to form diesters
US8829248B2 (en) 2010-08-18 2014-09-09 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US8466328B2 (en) 2010-08-18 2013-06-18 Eastman Chemical Company Method for recovery and recycle of ruthenium homogeneous catalysts
US9227896B2 (en) 2010-08-18 2016-01-05 Eastman Chemical Company Process for the separation and purification of a mixed diol stream
US8785686B2 (en) 2010-09-23 2014-07-22 Eastman Chemical Company Process for recovering and recycling an acid catalyst
US8709376B2 (en) 2010-09-23 2014-04-29 Eastman Chemical Company Process for recovering and recycling an acid catalyst
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
JP2015503510A (ja) * 2011-12-21 2015-02-02 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
US8703999B2 (en) 2012-03-27 2014-04-22 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of propionic acid and a heterogeneous catalyst
US8829234B2 (en) 2012-03-27 2014-09-09 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and heterogeneous catalyst
US8927766B2 (en) 2012-03-27 2015-01-06 Eastman Chemical Company Hydrocarboxylation of methylene dipropionate in the presence of a propionic acid and a homogeneous catalyst
US8765999B2 (en) 2012-03-27 2014-07-01 Eastman Chemical Company Hydrocarboxylation of formaldehyde in the presence of a higher order carboxylic acid and a homogeneous catalyst
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3904547A (en) 1973-06-06 1975-09-09 Gen Electric Process for recycling a cobalt hydroformylation catalyst
JPS55118429A (en) 1979-03-05 1980-09-11 Mitsubishi Petrochem Co Ltd Preparation of tricyclodecanedimethylol
US4633021A (en) 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4845306A (en) 1987-04-24 1989-07-04 Eastman Kodak Company Catalyst material recovery or concentration process
US5180854A (en) 1988-07-14 1993-01-19 Union Carbide Chemicals & Plastics Technology Corporation Process for catalyst aldehyde product separation
US5138101A (en) 1991-07-19 1992-08-11 Eastman Kodak Company Recovery of high-boiling aldehydes from rhodium-catalyzed hydroformylation processes
DE4204808A1 (de) 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5463082A (en) 1993-07-08 1995-10-31 Exxon Research And Engineering Company Fluorous multiphase systems
BE1007944A3 (nl) 1993-12-30 1995-11-21 Dsm Nv Werkwijze voor de bereiding van 5-formylvaleriaanzuur en -ester.
FR2729385B1 (fr) 1995-01-17 1997-04-04 Centre Nat Rech Scient Procede d'hydroformylation d'une olefine en milieu biphasique
US5648554A (en) 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
JP3959754B2 (ja) * 1995-04-12 2007-08-15 三菱化学株式会社 アルデヒド類の製造方法
DE19532393A1 (de) 1995-09-02 1997-03-06 Hoechst Ag Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen
WO1997011931A1 (fr) 1995-09-26 1997-04-03 Kuraray Co., Ltd. Procede d'hydroformylation
US5811590A (en) 1995-10-25 1998-09-22 Shell Oil Company Hydroformylation process
US5789625A (en) 1995-12-06 1998-08-04 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
MY120454A (en) 1997-07-29 2005-10-31 Du Pont Improved process of preparation of linear aldehydes
ZA9810973B (en) * 1997-12-03 1999-06-01 Shell Int Research Hydroformylation process
EP0922691B1 (en) 1997-12-03 2004-04-28 Shell Internationale Research Maatschappij B.V. Hydroformylation process
US5932772A (en) 1998-02-02 1999-08-03 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US5952530A (en) 1998-02-02 1999-09-14 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
US6252121B1 (en) * 1999-07-27 2001-06-26 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes

Also Published As

Publication number Publication date
KR100693774B1 (ko) 2007-03-12
DE60138692D1 (de) 2009-06-25
AU2001253850A1 (en) 2001-09-24
IN2002CH01451A (pt) 2005-01-28
MXPA02009079A (es) 2004-08-12
EP1265832B1 (en) 2009-05-13
BR0109195B1 (pt) 2012-01-24
US6307109B1 (en) 2001-10-23
CN1427807A (zh) 2003-07-02
RU2002127587A (ru) 2004-02-27
KR20020080488A (ko) 2002-10-23
JP2003526688A (ja) 2003-09-09
WO2001068247A2 (en) 2001-09-20
CA2402892A1 (en) 2001-09-20
WO2001068247A8 (en) 2004-06-24
EP1265832A2 (en) 2002-12-18
WO2001068247A3 (en) 2002-03-07
CN1212293C (zh) 2005-07-27

Similar Documents

Publication Publication Date Title
BR0109195A (pt) Processos de separação
BR9908360A (pt) Processos de separação aperfeiçoados
BR9908212A (pt) Processos aperfeiçoados de separação
MXPA04006695A (es) Procedimiento para separar acidos de mezclas de reaccion quimicas con la ayuda de liquidos ionicos.
RU2226418C2 (ru) Система для получения очищенного мономерного стирола и способ выделения мономерного стирола из смешанного углеводородного потока
Sarrade et al. Supercritical CO2 extraction coupled with nanofiltration separation: applications to natural products
NO20020378D0 (no) Forbedrede metall-ligandkompleks-katalyserte prosesser
BR9911830A (pt) Processos catalisados por complexo de metal-ligante aperfeiçoados
MY138435A (en) Selective separation of fluid compounds utilizing a membrane separation process
BR0308158A (pt) Processo para o melhoramento de correntes brutas de hidrocarbonetos
BR0109223A (pt) Processos de separação
ES531582A0 (es) Procedimiento para la separacion de etanol de la solucion que contiene etanol que resulta de la fermentacion alcoholica
DE69401506D1 (de) Verfahren zur chromatografischer fraktionierung von fettsäuren und ihre derivaten
WO2007103736A3 (en) Compact sulfur recovery plant and process
NO862441D0 (no) Fremgangsmaate og apparat for agitering av et vaeskeholdig system.
WO2006107900A3 (en) Monitoring by means of an on-line sensor and fluidic operations involving unit separation and reaction operations
WO2004085022A8 (en) Purification of fluid compounds utilizing a distillation-membrane separation process
Fontalvo et al. A hybrid distillation–pervaporation system in a single unit for breaking distillation boundaries in multicomponent mixtures
BR0214730A (pt) Método para separar pelo menos uma fração de produtos quìmicos não-ácidos de pelo menos uma fração de um produto bruto gasoso produzido durante uma reação de fischer-tropsch ou de um seu condensado
BR0209081A (pt) Processo de remoção de produto e sistema de remoção de produto in situ
BR0311982A (pt) Processo para recuperação de um ácido de lewis de uma mistura de reação
BR0200881A (pt) Método para destilar solução de ácido (met) acrìlico
CA2163913A1 (en) Process for the removal of elemental sulfur from fluids by mixing said fluid with an immiscible solution of alcoholic caustic and an inorganic sulfide or hydrosulfide
WO2009016677A3 (en) Continuous process for microspheres production by using expanded fluids
BRPI0405436A (pt) Processo para a produção de ácidos carboxìlicos insaturados ou de nitrilas insaturadas

Legal Events

Date Code Title Description
B25D Requested change of name of applicant approved

Owner name: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY LL

Free format text: ALTERADO DE: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY CORPORATION

B25A Requested transfer of rights approved

Owner name: DOW TECHNOLOGY INVESTMENTS LLC (US)

Free format text: TRANSFERIDO DE: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY LLC

B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 24/01/2012, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 20A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2622 DE 06-04-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.