BE830106A - Procede de preparation d'acetate de vinyle - Google Patents
Procede de preparation d'acetate de vinyleInfo
- Publication number
- BE830106A BE830106A BE157221A BE157221A BE830106A BE 830106 A BE830106 A BE 830106A BE 157221 A BE157221 A BE 157221A BE 157221 A BE157221 A BE 157221A BE 830106 A BE830106 A BE 830106A
- Authority
- BE
- Belgium
- Prior art keywords
- vinyl acetate
- preparation process
- acetate preparation
- vinyl
- preparation
- Prior art date
Links
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/52—Gold
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/396—Distribution of the active metal ingredient
- B01J35/397—Egg shell like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/638—Pore volume more than 1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP49073713A JPS514118A (en) | 1974-06-27 | 1974-06-27 | Sakusanbiniruno seizohoho |
Publications (1)
Publication Number | Publication Date |
---|---|
BE830106A true BE830106A (fr) | 1975-10-01 |
Family
ID=13526124
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BE157221A BE830106A (fr) | 1974-06-27 | 1975-06-11 | Procede de preparation d'acetate de vinyle |
Country Status (11)
Country | Link |
---|---|
US (1) | US4087622A (fr) |
JP (1) | JPS514118A (fr) |
AU (1) | AU500830B2 (fr) |
BE (1) | BE830106A (fr) |
BR (1) | BR7504072A (fr) |
CA (1) | CA1076097A (fr) |
DE (1) | DE2528363A1 (fr) |
FR (1) | FR2276285A1 (fr) |
GB (1) | GB1500167A (fr) |
IT (1) | IT1044300B (fr) |
NL (1) | NL7507549A (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1107538C (zh) * | 1997-06-03 | 2003-05-07 | 国际人造丝公司 | 包含沉积在含铜载体上的钯和金的乙酸乙烯酯催化剂 |
Families Citing this family (53)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4048096A (en) * | 1976-04-12 | 1977-09-13 | E. I. Du Pont De Nemours And Company | Surface impregnated catalyst |
DE2811115A1 (de) * | 1978-03-15 | 1979-09-27 | Hoechst Ag | Traeger-katalysator fuer die herstellung von vinylacetat aus ethylen, essigsaeure und sauerstoff in der gasphase |
US4654801A (en) * | 1984-11-30 | 1987-03-31 | Phillips Petroleum Company | Control of a vinyl acetate process |
DE3803900A1 (de) * | 1988-02-09 | 1989-08-17 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
DE3919524A1 (de) * | 1989-06-15 | 1990-12-20 | Hoechst Ag | Verfahren zur herstellung von vinylacetat |
US5274181A (en) * | 1991-05-06 | 1993-12-28 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5342987A (en) * | 1991-05-06 | 1994-08-30 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate production |
US5185308A (en) * | 1991-05-06 | 1993-02-09 | Bp Chemicals Limited | Catalysts and processes for the manufacture of vinyl acetate |
US5179057A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Catalysts for alkenyl alkanoate production |
US5179056A (en) * | 1991-05-06 | 1993-01-12 | Union Carbide Chemicals & Plastics Technology Corporation | Production of alkenyl alkanoate catalysts |
US5189004A (en) * | 1991-11-18 | 1993-02-23 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
AU643132B2 (en) * | 1991-11-18 | 1993-11-04 | Union Carbide Chemicals & Plastics Technology Corporation | Alkenyl alkanoate catalyst process |
US5194417A (en) * | 1991-12-05 | 1993-03-16 | Quantum Chemical Corporation | Pretreatment of palladium-gold catalysts useful in vinyl acetate synthesis |
DE69217648T2 (de) * | 1992-03-30 | 1997-06-12 | Union Carbide Chem Plastic | Verfahren für die Herstellung eines Katalysators für die Bereitung von Alkenylalkanoaten |
US5332710A (en) * | 1992-10-14 | 1994-07-26 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
US5314858A (en) * | 1992-10-14 | 1994-05-24 | Hoechst Celanese Corporation | Vinyl acetate catalyst preparation method |
DE4323978C1 (de) * | 1993-07-16 | 1995-02-16 | Hoechst Ag | Palladium und Kalium sowie Cadmium, Barium oder Gold enthaltender Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung zur Herstellung von Vinylacetat |
CA2135021A1 (fr) * | 1993-11-19 | 1995-05-20 | David J. Gulliver | Procede pour la preparation de catalyseurs pour la production d'acetate de vinyle |
US6034030A (en) * | 1994-02-22 | 2000-03-07 | Celanese International Corporation | Vinyl acetate catalyst preparation method |
US5466652A (en) * | 1994-02-22 | 1995-11-14 | The Standard Oil Co. | Process for the preparation of vinyl acetate catalyst |
DE69535514T2 (de) * | 1994-02-22 | 2008-02-14 | The Standard Oil Co., Cleveland | Verfahren zur Herstellung eines Trägers eines Katalysators für die Vorbereitung von Vinylacetat in einem Wirbelbett |
US6395676B2 (en) | 1994-02-22 | 2002-05-28 | The Standard Oil Company | Process for the preparation of fluid bed vinyl acetate catalyst |
US5665667A (en) * | 1994-06-02 | 1997-09-09 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
US5550281A (en) * | 1994-06-02 | 1996-08-27 | Cirjak; Larry M. | Fluid bed process for the acetoxylation of ethylene in the production of vinyl acetate |
US5536693A (en) * | 1994-06-02 | 1996-07-16 | The Standard Oil Company | Process for the preparation of vinyl acetate catalyst |
DE69511464T2 (de) * | 1994-06-02 | 1999-12-16 | The Standard Oil Co., Cleveland | Fliessbett-Verfahren zur Acetoxylierung von Äthylen zur Herstellung von Vinylacetat |
DE19501891C1 (de) * | 1995-01-23 | 1996-09-26 | Degussa | Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat |
US6022823A (en) * | 1995-11-07 | 2000-02-08 | Millennium Petrochemicals, Inc. | Process for the production of supported palladium-gold catalysts |
US5705679A (en) * | 1996-04-02 | 1998-01-06 | Nicolau; Ioan | Honeycomb catalyst for vinyl acetate synthesis |
US5691267A (en) * | 1996-04-16 | 1997-11-25 | Hoechst Celanese Corporation | Two step gold addition method for preparing a vinyl acetate catalyst |
US6207610B1 (en) * | 1996-05-17 | 2001-03-27 | Degussa-Huls Ag | Compacts based on pyrogenically produced silicon dioxide |
SA97180048B1 (ar) * | 1996-05-24 | 2005-12-21 | هوكست سيلانس كوربوريشن | محفز بلاديوم - ذهب palladium gold ثنائي المعدن متغاير الخواص heterogeneous bimetallic vinyl acetate لإنتاج أسيتات فينيل |
US5693586A (en) * | 1996-06-28 | 1997-12-02 | Hoechst Celanese Corporation | Palladium-gold catalyst for vinyl acetate production |
DE19734973A1 (de) * | 1997-08-13 | 1999-02-25 | Hoechst Ag | Edelmetallcluster enthaltende nano-poröse Aluminium-oxid-Membranen |
US6072078A (en) * | 1997-12-12 | 2000-06-06 | Celanese International Corporation | Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals |
KR20010040654A (ko) * | 1998-02-05 | 2001-05-15 | 스티븐 아이. 밀러 | Pd-Au 비닐 아세테이트 모노머 촉매의 노화 방지 |
GB9810928D0 (en) * | 1998-05-22 | 1998-07-22 | Bp Chem Int Ltd | Catalyst and process |
TW471982B (en) | 1998-06-02 | 2002-01-11 | Dairen Chemical Corp | Catalyst manufacture method and its use for preparing vinyl acetate |
US6015769A (en) * | 1998-06-02 | 2000-01-18 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate |
CN1089638C (zh) * | 1998-10-12 | 2002-08-28 | 大连化学工业股份有限公司 | 催化剂的制法及其在制备乙酸烯酯中的用途 |
US6358882B1 (en) | 1998-12-08 | 2002-03-19 | The Standard Oil Company | Fluid bed vinyl acetate catalyst |
DE19914066A1 (de) * | 1999-03-27 | 2000-10-05 | Celanese Chem Europe Gmbh | Katalysatoren für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat, Verfahren zu ihrer Herstellung und ihre Verwendung |
US6303537B1 (en) * | 1999-11-17 | 2001-10-16 | Celanese International Corporation | Vinyl acetate catalyst comprising metallic palladium and gold and prepared utilizing sonication |
US6534438B1 (en) | 2000-07-26 | 2003-03-18 | Bp Chemicals Limited | Catalyst composition |
US6936568B2 (en) * | 2002-06-12 | 2005-08-30 | Sud-Chemie Inc. | Selective hydrogenation catalyst |
CN101973546B (zh) | 2003-09-26 | 2012-09-05 | 3M创新有限公司 | 一种氧化一氧化碳的方法 |
TW200539941A (en) * | 2003-12-19 | 2005-12-16 | Celanese Int Corp | Methods of making alkenyl alkanoates |
UA95442C2 (ru) * | 2004-12-20 | 2011-08-10 | Селаниз Интернешнл Корпорейшн | Модифицированные материалы носителей для катализаторов |
JP4865250B2 (ja) * | 2005-04-15 | 2012-02-01 | 三菱重工業株式会社 | 排ガス処理用触媒の製造方法 |
US8227369B2 (en) * | 2005-05-25 | 2012-07-24 | Celanese International Corp. | Layered composition and processes for preparing and using the composition |
US7709407B1 (en) | 2009-01-21 | 2010-05-04 | Nanostellar, Inc. | Palladium-gold catalyst synthesis |
US8415269B2 (en) * | 2009-01-21 | 2013-04-09 | WGCH Technology Limited | Palladium-gold catalyst synthesis |
GB201110850D0 (en) | 2011-03-04 | 2011-08-10 | Johnson Matthey Plc | Catalyst and mehtod of preparation |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1252662B (fr) * | 1965-06-25 | |||
DE1296621B (de) * | 1966-11-12 | 1969-06-04 | Bayer Ag | Verfahren zur Herstellung von Vinylacetat |
DE1618591C3 (de) * | 1967-04-05 | 1974-01-31 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung ungesättigter Ester von Carbonsäuren |
GB1177515A (en) * | 1967-05-31 | 1970-01-14 | Bp Chem Int Ltd | Preparation of Vinyl Acetate. |
NL167680C (nl) * | 1968-07-19 | 1982-01-18 | Hoechst Ag | Werkwijze voor het bereiden van allylesters van carbonzuren uit propeen, zuurstof en carbonzuur. |
US3939199A (en) * | 1971-01-06 | 1976-02-17 | Hoechst Aktiengesellschaft | Oxacylation of olefins in the gaseous phase |
-
1974
- 1974-06-27 JP JP49073713A patent/JPS514118A/ja active Pending
-
1975
- 1975-06-11 BE BE157221A patent/BE830106A/fr unknown
- 1975-06-20 GB GB26375/75A patent/GB1500167A/en not_active Expired
- 1975-06-23 US US05/589,619 patent/US4087622A/en not_active Expired - Lifetime
- 1975-06-24 CA CA230,035A patent/CA1076097A/fr not_active Expired
- 1975-06-25 NL NL7507549A patent/NL7507549A/xx not_active Application Discontinuation
- 1975-06-25 DE DE19752528363 patent/DE2528363A1/de not_active Withdrawn
- 1975-06-25 AU AU82447/75A patent/AU500830B2/en not_active Expired
- 1975-06-26 IT IT24818/75A patent/IT1044300B/it active
- 1975-06-27 BR BR5217/75D patent/BR7504072A/pt unknown
- 1975-06-27 FR FR7520344A patent/FR2276285A1/fr active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1107538C (zh) * | 1997-06-03 | 2003-05-07 | 国际人造丝公司 | 包含沉积在含铜载体上的钯和金的乙酸乙烯酯催化剂 |
Also Published As
Publication number | Publication date |
---|---|
BR7504072A (pt) | 1976-07-06 |
US4087622A (en) | 1978-05-02 |
DE2528363A1 (de) | 1976-01-15 |
JPS514118A (en) | 1976-01-14 |
GB1500167A (en) | 1978-02-08 |
CA1076097A (fr) | 1980-04-22 |
AU500830B2 (en) | 1979-05-31 |
AU8244775A (en) | 1977-01-13 |
FR2276285B1 (fr) | 1977-07-08 |
FR2276285A1 (fr) | 1976-01-23 |
IT1044300B (it) | 1980-03-20 |
NL7507549A (nl) | 1975-12-30 |
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