BE829283A - Composition comportant des ions metalliques complexes et procede de traitement d'organismes nuisibles par des metaux - Google Patents

Composition comportant des ions metalliques complexes et procede de traitement d'organismes nuisibles par des metaux

Info

Publication number
BE829283A
BE829283A BE6045020A BE6045020A BE829283A BE 829283 A BE829283 A BE 829283A BE 6045020 A BE6045020 A BE 6045020A BE 6045020 A BE6045020 A BE 6045020A BE 829283 A BE829283 A BE 829283A
Authority
BE
Belgium
Prior art keywords
metals
treatment
composition containing
containing complex
metallic ions
Prior art date
Application number
BE6045020A
Other languages
English (en)
Inventor
Terence D Colegate
Eric J Davis
Christopher R Farnworth
Original Assignee
Laporte Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Industries Ltd filed Critical Laporte Industries Ltd
Publication of BE829283A publication Critical patent/BE829283A/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3214—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the method for obtaining this coating or impregnating
    • B01J20/3217—Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3242—Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
    • B01J20/3244—Non-macromolecular compounds
    • B01J20/3265—Non-macromolecular compounds with an organic functional group containing a metal, e.g. a metal affinity ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3425—Regenerating or reactivating of sorbents or filter aids comprising organic materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3433—Regenerating or reactivating of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3475—Regenerating or reactivating using a particular desorbing compound or mixture in the liquid phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/50—Aspects relating to the use of sorbent or filter aid materials
    • B01J2220/58—Use in a single column

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Wood Science & Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Materials Engineering (AREA)
  • Toxicology (AREA)
  • Pest Control & Pesticides (AREA)
  • Dispersion Chemistry (AREA)
  • Dentistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Removal Of Specific Substances (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Water Treatment By Sorption (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Paints Or Removers (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
BE6045020A 1974-05-21 1975-05-20 Composition comportant des ions metalliques complexes et procede de traitement d'organismes nuisibles par des metaux BE829283A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB22640/74A GB1482930A (en) 1974-05-21 1974-05-21 Removing metal ions from solution

Publications (1)

Publication Number Publication Date
BE829283A true BE829283A (fr) 1975-11-20

Family

ID=10182715

Family Applications (2)

Application Number Title Priority Date Filing Date
BE6045019A BE829282A (fr) 1974-05-21 1975-05-20 Elimination de metaux
BE6045020A BE829283A (fr) 1974-05-21 1975-05-20 Composition comportant des ions metalliques complexes et procede de traitement d'organismes nuisibles par des metaux

Family Applications Before (1)

Application Number Title Priority Date Filing Date
BE6045019A BE829282A (fr) 1974-05-21 1975-05-20 Elimination de metaux

Country Status (16)

Country Link
US (1) US4033764A (fr)
JP (2) JPS5857223B2 (fr)
AU (1) AU8137275A (fr)
BE (2) BE829282A (fr)
BR (2) BR7503199A (fr)
DE (2) DE2522249A1 (fr)
DK (2) DK215875A (fr)
ES (2) ES437802A1 (fr)
FR (2) FR2272046B1 (fr)
GB (1) GB1482930A (fr)
IT (1) IT1036899B (fr)
LU (2) LU72536A1 (fr)
NL (2) NL181557C (fr)
NO (2) NO751651L (fr)
SE (2) SE7505793L (fr)
ZA (2) ZA753278B (fr)

Families Citing this family (40)

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Publication number Priority date Publication date Assignee Title
JPS5940483B2 (ja) * 1977-07-21 1984-10-01 日本原子力研究所 オキシン（８−ハイドロオキシキノリン）添着活性炭の製造法
WO1980000313A1 (fr) * 1978-07-26 1980-03-06 Nat Res Dev Amelioration dans la stabilisation de sels hygroscopiques
US4259103A (en) * 1979-03-12 1981-03-31 Dow Corning Corporation Method of reducing the number of microorganisms in a media and a method of preservation
US4271043A (en) * 1979-09-04 1981-06-02 W. R. Grace & Co. Pillared interlayered clay products
US4386010A (en) * 1980-09-02 1983-05-31 Engelhard Corporation Treated attapulgite clay composition
AU554311B2 (en) * 1981-04-02 1986-08-14 Medichem A.G. Method for the preparation of molded bodies for asepticizing water and aqueous solutions
EP0073262B1 (fr) * 1981-08-31 1985-11-13 Kernforschungszentrum Karlsruhe Gmbh Procédé pour séparer les ions de césium de solutions aqueuses par utilisation d'un composé d'addition constitué d'un polyéther macrocyclique et d'un hétéropolyacide minéral
EP0073261B1 (fr) * 1981-08-31 1985-11-13 Kernforschungszentrum Karlsruhe Gmbh Procédé pour séparer les ions de césium de solutions par utilisation d'un composé d'addition sous forme solide d'un polyéther macrocyclique et d'un hétéropolyacide minéral
US4444665A (en) * 1981-12-02 1984-04-24 Engelhard Corporation Treated mineral and method for purifying liquids therewith
US4530963A (en) * 1982-08-20 1985-07-23 Devoe-Holbein International, N.V. Insoluble chelating compositions
DE3231982A1 (de) * 1982-08-27 1984-03-01 Süd-Chemie AG, 8000 München Thiolathaltiges mittel und verfahren zur entfernung von schwermetallionen aus verduennten waessrigen loesungen
IT1180222B (it) * 1983-09-08 1987-09-23 Little Inc A Procedimento per il recupero di metalli preziosi
US4659512A (en) * 1983-12-21 1987-04-21 Pedro B. Macedo Fixation of dissolved metal species with a complexing agent
US4740488A (en) * 1985-11-25 1988-04-26 The University Of Michigan Modified clay sorbents
US4778627A (en) * 1986-01-13 1988-10-18 James William Ayres Disposable hazardous and radioactive liquid hydrocarbon waste composition and method
USRE33915E (en) * 1986-01-13 1992-05-05 James William Ayres Disposable hazardous and radioactive liquid hydrocarbon waste composition and method
US4752397A (en) * 1986-06-30 1988-06-21 Aluminum Company Of America Process for removing heavy metal ions from solutions using adsorbents containing activated hydrotalcite
US4916095A (en) * 1988-07-14 1990-04-10 The University Of Michigan Modified clay sorbents
US5211843A (en) * 1990-07-03 1993-05-18 Spectrulite Consortium, Inc. Mobile apparatus for environmentally treating spent etchant safely
US5108620A (en) * 1990-07-03 1992-04-28 Spectrulite Consortium, Inc. Process for recovery of spent etchant
US5294417A (en) * 1992-04-06 1994-03-15 Olin Corporation Process for removal of mercury from hydroxyl-ammonium nitrate solutions
FI100981B (fi) * 1994-05-13 1998-03-31 Koskisen Oy Pinnoitekoostumus ja menetelmä rakennusmateriaalien pintojen suojaamis eksi mikro-organismien ei-toivotuilta reaktioilta
US5606056A (en) * 1994-05-24 1997-02-25 Arizona Board Of Regents Carbon nitride and its synthesis
US5667694A (en) * 1995-08-28 1997-09-16 Rheox, Inc. Process for the removal of heavy metals from aqueous systems using organoclays
US5780376A (en) * 1996-02-23 1998-07-14 Southern Clay Products, Inc. Organoclay compositions
US6077421A (en) * 1996-07-18 2000-06-20 The United States Of America As Represented By The Secretary Of The Navy Metal complexing
US6271298B1 (en) 1999-04-28 2001-08-07 Southern Clay Products, Inc. Process for treating smectite clays to facilitate exfoliation
US6787592B1 (en) 1999-10-21 2004-09-07 Southern Clay Products, Inc. Organoclay compositions prepared from ester quats and composites based on the compositions
GB0214355D0 (en) * 2002-06-21 2002-07-31 Rockwood Additives Ltd Synthetic magnesium silicate compositions and process for the production thereof
GB0229630D0 (en) * 2002-12-20 2003-01-22 Rockwood Additives Ltd Process for the production of synthetic magnesium silicate compositions
US20050090584A1 (en) * 2003-10-23 2005-04-28 Powell Clois E. Preparation of rubber compositions with organoclays
US20050187305A1 (en) * 2004-02-25 2005-08-25 Briell Robert G. Solvent gelation using particulate additives
US20050228103A1 (en) * 2004-04-13 2005-10-13 Eastman Kodak Company Composition comprising intercalated metal-ion sequestrants
WO2006048746A2 (fr) * 2004-11-02 2006-05-11 Pfizer Inc. Procedes d'evacuation de metaux lourds
US7871524B2 (en) * 2007-06-05 2011-01-18 Amcol International Corporation Method for removing merury and/or arsenic from water using a silane coupling agent reacted organoclay
US7910005B2 (en) * 2007-06-05 2011-03-22 Amcol International Corporation Method for removing mercury and/or arsenic from contaminated water using an intimate mixture of organoclay and elemental sulfur
US20080302733A1 (en) * 2007-06-05 2008-12-11 Amcol International Corporation Coupling agent-reacted mercury removal media
US8025160B2 (en) * 2007-06-05 2011-09-27 Amcol International Corporation Sulfur-impregnated organoclay mercury and/or arsenic ion removal media
US8357303B2 (en) * 2007-09-04 2013-01-22 Halliburton Energy Services, Inc. Method for removing metal contaminants from a metal containing solution
CN107840429B (zh) * 2017-11-13 2018-10-19 江苏环保产业技术研究院股份公司 一种去除六价铬的金属有机高分子材料及其制备方法和应用

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Publication number Priority date Publication date Assignee Title
CA592862A (en) * 1960-02-16 Arthur D. Little Process for the recovery of metals employing a chelating agent
GB831745A (en) * 1956-08-09 1960-03-30 Little Inc A Process for the recovery of dissolved metal values
NL243444A (fr) * 1958-09-24
DE1929661B2 (de) * 1969-06-11 1975-11-06 Bayer Ag, 5090 Leverkusen Verfahren zur Reinigung von Cadmiumlösungen
CA955035A (en) * 1970-02-05 1974-09-24 Osaka Soda Co. Treatment process for removal of metals and treating agent therefor
CH544574A (de) * 1971-06-10 1973-11-30 Roth Handels Gmbh Mittel zur Sorption von flüssigen Metallen und von Metalldämpfen
JPS4829479A (fr) * 1971-08-18 1973-04-19
US3847841A (en) * 1972-03-11 1974-11-12 Tokuyama Soda Kk Thiosemicarbazido heavy metal adsorbing resins
US3872001A (en) * 1973-05-31 1975-03-18 Celanese Corp Removal of heavy metal pollutants from aqueous media
JPS5025489A (fr) * 1973-07-10 1975-03-18
US3888435A (en) * 1974-07-18 1975-06-10 Kenneth R Foote Helicopter with auxiliary load-supporting and lifting capacity

Also Published As

Publication number Publication date
AU8137275A (en) 1976-11-25
ZA753279B (en) 1976-04-28
BE829282A (fr) 1975-11-20
US4033764A (en) 1977-07-05
ZA753278B (en) 1976-04-28
NL7505888A (nl) 1975-11-25
DK215875A (da) 1975-11-22
IT1036899B (it) 1979-10-30
DK215775A (da) 1975-11-22
DE2522248A1 (de) 1975-12-11
NO751651L (fr) 1975-11-24
AU8137375A (en) 1976-11-25
SE7505793L (sv) 1975-11-24
FR2272046B1 (fr) 1982-07-16
BR7503200A (pt) 1976-04-20
NO751650L (fr) 1975-11-24
ES437802A1 (es) 1977-01-16
NL7505887A (nl) 1975-11-25
NL181557C (nl) 1987-09-16
FR2272157A1 (fr) 1975-12-19
JPS5857223B2 (ja) 1983-12-19
GB1482930A (en) 1977-08-17
JPS50160425A (fr) 1975-12-25
FR2272046A1 (fr) 1975-12-19
DE2522249A1 (de) 1975-12-11
SE7505794L (sv) 1975-11-24
LU72537A1 (fr) 1976-03-17
ES437801A1 (es) 1977-01-01
DE2522248C2 (de) 1986-01-30
JPS515288A (fr) 1976-01-16
BR7503199A (pt) 1976-11-16
LU72536A1 (fr) 1976-03-17

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