BE711042A - - Google Patents

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Publication number
BE711042A
BE711042A BE711042DA BE711042A BE 711042 A BE711042 A BE 711042A BE 711042D A BE711042D A BE 711042DA BE 711042 A BE711042 A BE 711042A
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BE
Belgium
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Filing date
Publication date
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Publication of BE711042A publication Critical patent/BE711042A/xx

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25Migration of carbon-to-carbon double bonds
    • C07C5/2506Catalytic processes
    • C07C5/2562Catalytic processes with hydrides or organic compounds
    • C07C5/2593Catalytic processes with hydrides or organic compounds containing phosphines, arsines, stibines or bismuthines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1616Coordination complexes, e.g. organometallic complexes, immobilised on an inorganic support, e.g. ship-in-a-bottle type catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20Carbonyls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/23Rearrangement of carbon-to-carbon unsaturated bonds
    • C07C5/25Migration of carbon-to-carbon double bonds
    • C07C5/2506Catalytic processes
    • C07C5/2562Catalytic processes with hydrides or organic compounds
    • C07C5/2581Catalytic processes with hydrides or organic compounds containing complexes, e.g. acetyl-acetonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84Metals of the iron group
    • B01J2531/845Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00Systems containing only non-condensed rings
    • C07C2601/12Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14The ring being saturated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/8995Catalyst and recycle considerations
    • Y10S585/906Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
BE711042D 1967-02-20 1968-02-20 BE711042A (nl)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US61733867A 1967-02-20 1967-02-20
US00703382A US3855307A (en) 1967-02-20 1968-02-06 Catalysis

Publications (1)

Publication Number Publication Date
BE711042A true BE711042A (nl) 1968-08-20

Family

ID=27088000

Family Applications (1)

Application Number Title Priority Date Filing Date
BE711042D BE711042A (nl) 1967-02-20 1968-02-20

Country Status (4)

Country Link
US (1) US3855307A (nl)
BE (1) BE711042A (nl)
DE (1) DE1667200A1 (nl)
FR (1) FR1554443A (nl)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB428103I5 (nl) * 1969-10-29 1976-02-10

Families Citing this family (57)

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US4690912A (en) * 1968-08-15 1987-09-01 Monsanto Company Rhodium-containing carbonylation catalysts with halogen-containing promoter
US4012450A (en) * 1969-10-01 1977-03-15 Johnson Matthey & Co., Limited Catalytic reactions
US3937742A (en) * 1970-03-06 1976-02-10 Atlantic Richfield Company Hydroformylation process using catalyst comprising platinum group metal on support having separate alumina phase
US3954883A (en) * 1970-07-23 1976-05-04 Mobil Oil Corporation Catalytic polystep reactions
US3990993A (en) * 1974-11-13 1976-11-09 Exxon Research And Engineering Company Narrow particle size distribution catalysts and method therefor
US4626551A (en) * 1975-09-30 1986-12-02 Union Carbide Corporation Homogeneous liquid phase process for making alkane polyols
US4218340A (en) * 1975-11-19 1980-08-19 Eastman Kodak Company Nickel and cobalt containing carbonylation catalyst compositions for the production of carboxylic acids and their esters
US4133963A (en) * 1975-11-19 1979-01-09 Eastman Kodak Company Process for the production of carboxylic acids
DE2632545C2 (de) * 1976-07-20 1984-04-26 Collo Gmbh, 5303 Bornheim Reinigungskörper für die Körperpflege, für Haushaltszwecke und dgl.
NL7708158A (nl) * 1976-07-28 1978-01-31 Montedison Spa Werkwijze ter bereiding van esters.
US4356320A (en) * 1976-11-08 1982-10-26 The Halcon Sd Group, Inc. Preparation of carboxylic acids
AT356639B (de) * 1977-01-20 1980-05-12 Stamicarbon Verfahren zur katalytischen umsetzung ole- finisch ungesaettigter verbindungen mit wasser- stoff und kohlenmonoxid
ZA78146B (en) * 1977-01-25 1978-12-27 Union Carbide Corp Improved hydroformylation process
US4341907A (en) * 1978-09-19 1982-07-27 Du Pont Canada Inc. Catalytic oxidation of cycloparaffins
US4703064A (en) * 1979-11-15 1987-10-27 Union Carbide Corporation Process for producing alcohols
US4652677A (en) * 1980-03-10 1987-03-24 The Standard Oil Company Selective hydrocarboxylation of propylene to isobutyric acid
NL8003059A (nl) 1980-05-28 1982-01-04 Stamicarbon Werkwijze en katalysator voor het uitvoeren van hydroformyleringsreacties.
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins
CA1195340A (en) * 1980-11-14 1985-10-15 The Standard Oil Company Selective hydrocarboxylation of propylene to isobutyric acid
JPS6043767B2 (ja) * 1981-06-26 1985-09-30 薫 藤元 アルコ−ルのカルボニル化用触媒
US4569948A (en) * 1981-10-15 1986-02-11 Agency Of Industrial Science And Technology Preparation process of acetic acid
US4482647A (en) * 1981-12-03 1984-11-13 National Distillers And Chemical Corporation Manufacture of oxygenated compounds
US4482746A (en) * 1983-04-11 1984-11-13 E. I. Du Pont De Nemours & Company Staged catalyst process for cyclohexyl hydroperoxide decomposition
US4499305A (en) * 1983-04-11 1985-02-12 E. I. Du Pont De Nemours And Company Process for preparation of cyclohexyl hydroperoxide decomposition catalysts
US4503257A (en) * 1983-05-18 1985-03-05 E. I. Du Pont De Nemours And Company Cyclohexyl hydroperoxide decomposition process
US4629809A (en) * 1983-07-21 1986-12-16 Texaco Inc. Process for selectively preparing acetic acid by carbonylation of methanol in the presence of a novel iodide-free catalyst system
FI69620C (fi) * 1984-05-30 1986-03-10 Neste Oy Katalysator och foerfarande foer framstaellning av vaetgas ur kolmonoxid och vatten
US4947003A (en) * 1988-11-28 1990-08-07 Virginia Tech Intellectual Properties, Inc. Process for the hydroformulation of olefinically unsaturated organic reactants using a supported aqueous phase catalyst
US4994427A (en) * 1988-11-28 1991-02-19 Virginia Tech Intellectual Properties, Inc. Supported aqueous phase organometallic catalyst useful for hydroformylation and other reactions, and a method for its preparation
US4898845A (en) * 1988-12-12 1990-02-06 University Of Iowa Research Foundation Catalyst dispersed in supported molten salt
US5012008A (en) * 1990-01-08 1991-04-30 Drago Russell S Supported amorphous phase heterogeneous catalysts for biphasic hydroformylation
US5100851A (en) * 1990-09-04 1992-03-31 Exxon Research And Engineering Company Stationary aqueous acid phase transition metal catalysts for reduction of aromatics
KR930003648B1 (ko) * 1990-10-05 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 무기체 담지 촉매, 그 제조방법 및 이에 의한 에틸리덴 디 아세테이트의 제조방법
KR930003650B1 (ko) * 1990-10-08 1993-05-08 재단법인 한국화학연구소 에틸리덴 디 아세테이트 제조용 유기체 담지 촉매 및 이를 이용한 에틸리덴 디 아세테이트의 제조방법
US5132465A (en) * 1991-04-23 1992-07-21 Texaco Chemical Company Oxidation of primary alcohols to aldehydes using transition metal phthalocyanines as catalysts
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US5231175A (en) * 1992-02-10 1993-07-27 American Cyanamid Company Process for the preparation of 3'- or 2'-halo-substituted-2',3'-dideoxynucleosides
US5334755A (en) * 1992-04-24 1994-08-02 Chiyoda Corporation Process for the production of acetic acid from methanol and carbon monoxide using supported rhodium catalyst
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US5281359A (en) * 1992-08-31 1994-01-25 Hoechst Celanese Corporation Polymeric carbonylation catalyst system
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
US5334780A (en) * 1993-07-30 1994-08-02 Sun Company, Inc. Oxidation of hydrocarbons over ordered arrays of heteropolyacids and polyoxoanions on graphite
US6218326B1 (en) * 1998-07-29 2001-04-17 University Of Iowa Research Foundation Supported molten-metal catalysts
CN1122703C (zh) * 1998-12-29 2003-10-01 中国石油化工集团公司 用于烃类催化裂化的一种助剂及其使用方法
US6159896A (en) * 1999-02-16 2000-12-12 Eastman Chemical Company Iridium catalyst for carbonylation of lower aliphatic alcohols
EP1067108A3 (en) * 1999-07-07 2002-11-27 Sumitomo Chemical Company, Limited Process for producing aryloxyacetic acids
US6509293B1 (en) * 2000-05-22 2003-01-21 Eastman Chemical Company Gold based heterogeneous carbonylation catalysts
WO2002078842A1 (en) 2001-03-30 2002-10-10 Council Of Scientific And Industrial Research A novel catalytic formulation and its preparation
US6673737B2 (en) * 2001-05-30 2004-01-06 Exxonmobil Research And Engineering Company Ionic liquid compositions
FR2841798B1 (fr) * 2002-07-03 2005-03-04 Inst Francais Du Petrole Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation
US20040024263A1 (en) * 2002-08-02 2004-02-05 Boriack Clinton J. Process for preparing aryl allyl ethers
US7390868B2 (en) * 2003-05-29 2008-06-24 National Institute Of Advanced Industrial Science And Technology Catalyst for polycarbonate production and process for producing polycarbonate
US20050277799A1 (en) * 2004-06-12 2005-12-15 Ingrid Boehmer CH activation/dehydrogenation of hydrocarbons
JP4736368B2 (ja) * 2004-07-22 2011-07-27 住友化学株式会社 シクロアルカノール及び/又はシクロアルカノンの製造方法
US7696125B2 (en) * 2005-07-06 2010-04-13 Lee Chang Yung Chemical Industry Corporation Catalyst and process for preparing carboxylic acid esters
EP2904039B1 (en) * 2012-10-08 2020-10-07 Dow Global Technologies LLC Accelerated bonding of isocyanate functional adhesive to fiber reinforced plastics
CN115337940B (zh) * 2021-05-14 2023-12-15 江苏理工学院 一种用于合成柠檬酸三异丁酯催化剂的制备方法及应用

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GB651275A (en) * 1947-08-25 1951-03-14 Bataafsche Petroleum A process of producing ethyl alcohol
US3239566A (en) * 1960-07-22 1966-03-08 Shell Oil Co Hydroformylation of olefins
US3352924A (en) * 1963-01-23 1967-11-14 Exxon Research Engineering Co Carbonylation reactions
US3487112A (en) * 1967-04-27 1969-12-30 Monsanto Co Vapor phase hydroformylation process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USB428103I5 (nl) * 1969-10-29 1976-02-10
US4000211A (en) 1969-10-29 1976-12-28 Phillips Petroleum Company Dimerization of monoolefins with catalysts on solid supports

Also Published As

Publication number Publication date
DE1667200A1 (de) 1972-04-06
FR1554443A (nl) 1969-01-17
US3855307A (en) 1974-12-17

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