BE386190A - - Google Patents

Info

Publication number

BE386190A

BE386190A BE386190DA BE386190A BE 386190 A BE386190 A BE 386190A BE 386190D A BE386190D A BE 386190DA BE 386190 A BE386190 A BE 386190A

Authority

BE

Belgium

Prior art keywords

acid

olefins

butylene

sulfuric acid

reaction

Prior art date

Links

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• 239000002253 acid Substances 0.000 claims description 32
• QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 21
• 238000000034 method Methods 0.000 claims description 15
• 150000001336 alkenes Chemical class 0.000 claims description 10
• 239000000203 mixture Substances 0.000 claims description 9
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
• 239000007788 liquid Substances 0.000 claims description 7
• 125000004432 carbon atom Chemical group C* 0.000 claims description 4
• 238000004519 manufacturing process Methods 0.000 claims description 4
• JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
• 230000003301 hydrolyzing effect Effects 0.000 claims 2
• 150000003467 sulfuric acid derivatives Chemical class 0.000 claims 2
• 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 19
• 238000006243 chemical reaction Methods 0.000 description 17
• QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 9
• 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
• 238000007086 side reaction Methods 0.000 description 7
• BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 4
• 239000001273 butane Substances 0.000 description 3
• IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
• IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
• OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
• 239000007864 aqueous solution Substances 0.000 description 2
• LMEDOLJKVASKTP-UHFFFAOYSA-N dibutyl sulfate Chemical compound CCCCOS(=O)(=O)OCCCC LMEDOLJKVASKTP-UHFFFAOYSA-N 0.000 description 2
• 239000007789 gas Substances 0.000 description 2
• 238000002360 preparation method Methods 0.000 description 2
• 239000000047 product Substances 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
• UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
• 238000010521 absorption reaction Methods 0.000 description 1
• 230000015572 biosynthetic process Effects 0.000 description 1
• 238000009835 boiling Methods 0.000 description 1
• ZTHQBROSBNNGPU-UHFFFAOYSA-M butyl sulfate(1-) Chemical compound CCCCOS([O-])(=O)=O ZTHQBROSBNNGPU-UHFFFAOYSA-M 0.000 description 1
• 229910052799 carbon Inorganic materials 0.000 description 1
• 239000007795 chemical reaction product Substances 0.000 description 1
• 239000003153 chemical reaction reagent Substances 0.000 description 1
• 238000000354 decomposition reaction Methods 0.000 description 1
• 230000007423 decrease Effects 0.000 description 1
• 238000010790 dilution Methods 0.000 description 1
• 239000012895 dilution Substances 0.000 description 1
• 238000004821 distillation Methods 0.000 description 1
• 239000000839 emulsion Substances 0.000 description 1
• 238000004508 fractional distillation Methods 0.000 description 1
• 238000005194 fractionation Methods 0.000 description 1
• 239000001257 hydrogen Substances 0.000 description 1
• 229910052739 hydrogen Inorganic materials 0.000 description 1
• 230000007062 hydrolysis Effects 0.000 description 1
• 238000006460 hydrolysis reaction Methods 0.000 description 1
• 239000003208 petroleum Substances 0.000 description 1
• 238000005120 petroleum cracking Methods 0.000 description 1
• 229920000642 polymer Polymers 0.000 description 1
• 239000012985 polymerization agent Substances 0.000 description 1
• 238000006116 polymerization reaction Methods 0.000 description 1
• 239000003507 refrigerant Substances 0.000 description 1
• 238000005185 salting out Methods 0.000 description 1
• 150000003839 salts Chemical class 0.000 description 1
• 238000010517 secondary reaction Methods 0.000 description 1
• 239000000243 solution Substances 0.000 description 1
• 229910021653 sulphate ion Inorganic materials 0.000 description 1
• IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical group C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1