AU504310B2 - Alumina supported catalyst and its use in preparation of unsaturated organic esters - Google Patents

Alumina supported catalyst and its use in preparation of unsaturated organic esters

Info

Publication number
AU504310B2
AU504310B2 AU20392/76A AU2039276A AU504310B2 AU 504310 B2 AU504310 B2 AU 504310B2 AU 20392/76 A AU20392/76 A AU 20392/76A AU 2039276 A AU2039276 A AU 2039276A AU 504310 B2 AU504310 B2 AU 504310B2
Authority
AU
Australia
Prior art keywords
preparation
supported catalyst
unsaturated organic
organic esters
alumina supported
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
AU20392/76A
Other languages
English (en)
Other versions
AU2039276A (en
Inventor
R. C Bartsch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Millennium Petrochemicals Inc
Original Assignee
National Distillers and Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Distillers and Chemical Corp filed Critical National Distillers and Chemical Corp
Publication of AU2039276A publication Critical patent/AU2039276A/en
Application granted granted Critical
Publication of AU504310B2 publication Critical patent/AU504310B2/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • B01J23/52Gold
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/04Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/612Surface area less than 10 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
AU20392/76A 1975-12-18 1976-12-09 Alumina supported catalyst and its use in preparation of unsaturated organic esters Expired AU504310B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US64179975A 1975-12-18 1975-12-18
USUS6-41,799 1975-12-18

Publications (2)

Publication Number Publication Date
AU2039276A AU2039276A (en) 1978-06-15
AU504310B2 true AU504310B2 (en) 1979-10-11

Family

ID=24573901

Family Applications (1)

Application Number Title Priority Date Filing Date
AU20392/76A Expired AU504310B2 (en) 1975-12-18 1976-12-09 Alumina supported catalyst and its use in preparation of unsaturated organic esters

Country Status (20)

Country Link
US (1) US4119567A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
JP (1) JPS5276290A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AR (1) AR216295A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AT (1) AT357987B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
AU (1) AU504310B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BE (1) BE849565A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
BR (1) BR7608472A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DE (1) DE2657442A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
DK (1) DK569376A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
ES (1) ES454390A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FI (1) FI763621A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
FR (1) FR2335262A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
GB (1) GB1571910A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
IT (1) IT1065406B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
LU (1) LU76408A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NL (1) NL7614026A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NO (2) NO764285L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
NZ (1) NZ182888A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
SE (1) SE7614185L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)
YU (1) YU301276A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4656152A (en) * 1983-09-26 1987-04-07 The United States Of America As Represented By The United States Department Of Energy Catalyst for producing lower alcohols
US4577047A (en) * 1984-11-27 1986-03-18 Shell Oil Company Catalysts and process for the selective hydrogenation of acetylenes
US4551443A (en) * 1984-11-27 1985-11-05 Shell Oil Company Catalysts for the selective hydrogenation of acetylenes
JPS63175098U (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1987-02-17 1988-11-14
US4952389A (en) * 1989-09-15 1990-08-28 Norton Company Alumina particles
US5274181A (en) * 1991-05-06 1993-12-28 Bp Chemicals Limited Catalysts and processes for the manufacture of vinyl acetate
CA2364075A1 (en) 1992-05-22 1993-12-09 Hyperion Catalysis International, Inc. Improved methods and catalysts for the manufacture of carbon fibrils
US5347046A (en) * 1993-05-25 1994-09-13 Engelhard Corporation Catalyst and process for using same for the preparation of unsaturated carboxylic acid esters
CA2135021A1 (en) * 1993-11-19 1995-05-20 David J. Gulliver Process for the preparation of catalysts for use in the production of vinyl acetate
US5576457A (en) * 1995-05-23 1996-11-19 Hoechst Celanese Corporation Catalyst and procedure for preparation of vinyl acetate
US5968869A (en) * 1997-06-03 1999-10-19 Celanese International Corporation Vinyl acetate catalyst comprising palladium and gold deposited on a copper containing carrier
US5948724A (en) * 1997-10-28 1999-09-07 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium and gold and cupric acetate
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
GB9810928D0 (en) * 1998-05-22 1998-07-22 Bp Chem Int Ltd Catalyst and process
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
US6017847A (en) * 1998-06-02 2000-01-25 Celanese International Corporation Vinyl acetate catalyst prepared with potassium aurate and comprising metallic palladium and gold on a carrier precoated with copper
DE19843693A1 (de) * 1998-09-24 2000-03-30 Degussa Trägerkatalysator für die Produktion von Vinylacetatmonomer
CN1107704C (zh) * 2000-02-03 2003-05-07 中国石油天然气股份有限公司兰州石化分公司 裂解汽油选择性加氢催化剂
US6756340B2 (en) * 2002-04-08 2004-06-29 Uop Llc Dehydrogenation catalyst composition
JPWO2004000457A1 (ja) * 2002-06-24 2005-10-20 田中貴金属工業株式会社 改質ガス中の一酸化炭素の選択酸化触媒
US20070184974A1 (en) * 2006-02-06 2007-08-09 Bates Stephen C High temperature metal-on-oxide-ceramic catalysts
CN101423775B (zh) 2007-11-01 2010-05-12 中国石油天然气股份有限公司 一种选择性镍系加氢催化剂及其制备方法
CN101433841B (zh) * 2007-12-13 2010-04-14 中国石油天然气股份有限公司 一种选择性加氢催化剂及其制备方法
US20110028770A1 (en) * 2009-08-03 2011-02-03 Honeywell International Inc. Hydrogenation catalyst
WO2018093915A1 (en) 2016-11-17 2018-05-24 Lyondellbasell Acetyls, Llc High pore volume alumina supported catalyst for vinyl acetate monomer (vam) process
US10780424B2 (en) * 2016-11-17 2020-09-22 Lyondellbasell Acetyls, Llc Crush strength and porosity of an alumina carrier for enhanced VAM catalysts

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1307787A (fr) * 1961-12-11 1962-10-26 Shell Int Research Catalyseur au platine et à l'or pour la déshydrogénation par oxydation de composés organiques
US3190912A (en) * 1962-05-02 1965-06-22 Nat Distillers Chem Corp Process for preparing esters
DE1252662B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * 1965-06-25
US3567767A (en) * 1965-12-17 1971-03-02 Kurashiki Rayon Co Process for gas phase synthesis of vinyl esters
GB1283737A (en) * 1968-09-04 1972-08-02 Nat Distillers Chem Corp Method of catalyst preparation

Also Published As

Publication number Publication date
AR216295A1 (es) 1979-12-14
LU76408A1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1977-07-01
GB1571910A (en) 1980-07-23
SE7614185L (sv) 1977-06-19
ATA934776A (de) 1980-01-15
FR2335262A1 (fr) 1977-07-15
YU301276A (en) 1982-05-31
IT1065406B (it) 1985-02-25
DE2657442A1 (de) 1977-06-30
NO764285L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1977-06-21
BR7608472A (pt) 1977-12-20
FI763621A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1977-06-19
NO773478L (no) 1977-06-21
AT357987B (de) 1980-08-11
ES454390A1 (es) 1978-04-16
AU2039276A (en) 1978-06-15
DK569376A (da) 1977-06-19
BE849565A (fr) 1977-06-17
US4119567A (en) 1978-10-10
NL7614026A (nl) 1977-06-21
JPS5276290A (en) 1977-06-27
JPS5714898B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) 1982-03-27
NZ182888A (en) 1978-03-06

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