AU3737499A

AU3737499A - Cold work steel

Info

Publication number: AU3737499A
Application number: AU37374/99A
Authority: AU
Inventors: Borje Johansson; Odd Sandberg
Original assignee: Uddeholms AB
Current assignee: Uddeholms AB
Priority date: 1998-03-27
Filing date: 1999-03-08
Publication date: 1999-10-18
Anticipated expiration: 2019-03-08
Also published as: BR9909159A; SE511747C2; CN1295625A; WO1999050469A1; CA2325453A1; KR20010072559A; CA2325453C; TW500810B; CN1098369C; DE69907896D1; HK1033964A1; EP1068367B1; DE69907896T4; AU740280B2; JP2002509987A; KR100562760B1; EP1068367A1; ES2197637T3; SE9801045L; SE9801045D0

Abstract

A cold work steel has the following chemical composition in weight.%: 0.82-0.97 C, from traces to max. 1.10 Si, from traces to max. 0.62 Mn, at least 7.6 but less than 8.0 Cr, 2.30-2.70 Mo, 0.35-0.55 V, balance iron and impurities in normal amounts in the form of residual elements from the manufacture of the steel.

Description

WO 99/50469 PCT/SE99/00346 COLD WORK STEEL TECHNICAL FIELD 5 The invention relates to a new cold work steel, i.e. a steel intended for the manufacture of tools for cold working. Typical applications are blanking knives, punching tools, deep drawing moulds etc. BACKGROUND OF THE INVENTION 10 The most important feature of a cold work steel is that it shall have a high hardness. For most applications also a good abrasion resistance and a toughness sufficient for the application are required. In order to satisfy these primary and a number of other requirements, a very great number of steel alloys have been developed. Most of these alloys, especially when toughness is more important than wear resistance, have a 15 composition within the following alloying ranges: 0.8-1.2 C, 0.2-1.2 Si, 0.2-0.5 Mn, 5 12 Cr, 0.5-4 Mo, 0-3 W and 0.2-2 V. Further, small or moderately high contents of Ni, Nb, Cu and/or Al may be present. A steel of the latter type, which contains moderate though significant contents of niobium and aluminium, is described in US-A-5,160,553. 20 DISCLOSURE OF THE INVENTION It is the purpose of the invention to provide a cold work steel with a chemical composition which is balanced such that the steel shall satisfy the following requirements: - it shall be easy to manufacture in a non-powder metallurgical way and have a good 25 hot workability in order to get a high yield in production; - it shall be able to be manufactured in dimensions ranging from the very smallest dimensions, i.e. O 10 mm or less, up to 0 500 mm or corresponding sizes in square or flat sections; - it shall not contain any large amount of coarse primary carbides; 30 - it shall have good heat treatment features, which among other things means that it shall be able to be hardened from a moderately high austenitising temperature; - it shall have a good hardenability, i.e. a capacity to be through-hardened also in case of large dimensions; - it shall have good dimensional stability on heat treatment as well as in use, the latter 35 condition inter alia implying that it shall have small susceptibility to ageing; - it shall be able to secondary-harden in connection with tempering for the achievement of a hardness of 60-64 HRC; WO 99/50469 2 PCT/SE99/00346 - it shall have good surface deposition features, which means that it shall be able to be nitrided, case hardened and surface coated through PVD and CVD; - it shall have good sparking machinability; - it shall have an adequate abrasive wear resistance; 5 - it shall have an adequate toughness; - it shall have a high compressive strength; and - it shall have good fatigue features, good cuttability and good grindability. First a series of cold work steels known in the art were examined. The chemical 10 compositions of these steels are given in Table 1.

WO 99/50469 PCTISE99/00346 3 00 cl C4 t 0 e N. c- cq ~ C) u 6 6 Cl) 66D 6 C; C d C>~ 54 C ) V-o 0 C=~t~ C Cl 0 00 09l 6 cc enI" __ 00 00 C,4OO: 4 4W -44 -44 -44

--

4 C) Co -lC 0 0 0 0 0 0! C> <D 0 Cl C C) > C) Cl C) C 0. 0 C l C 66 66 09 6600 0 CD CD irD CD 06 C 4) -: > > 00cC WO 99/50469 4 PCT/SE99/00346 The steels of the table were examined or compared with reference to micro structure, including the type and character of inclusions, response to heat treatment, hardenability, hardness after austenitising and after tempering, dimensional stability, spark machinability, toughness in terms of impact strength and bending strength, abrasive 5 wear resistance, compressive yield point, grindability, and cuttability. None of the examined steels had an in all respects desired combination of features. Then, during the continued development work, in view of the achieved results, a revised 10 series of requirements was designed, wherein in the first place the influence of hardness and volume of carbides on toughness and wear resistance were considered. In this second phase of the development work it was examined more in detail how small changes in the contents of C, N, Mn, V, and Mo have influence on a number of such critical features as toughness, response to heat treatment, hardenability, secondary 15 hardening, resistance to tempering, and wear resistance. In this work, there were made seven 50 kg laboratory heats with a chemical composition in weight-% according to Table 2. Table 2 Chemical composition in weight-% Steel Q-heat C Si Mn P S Cr Mo V N Bal. No. No. 12 9020 0.96 0.81 0.50 0.007 0.005 7.18 2.97 0.41 0.016 Fe 13 9021 0.98 0.95 0.47 0.008 0.005 7.05 2.90 0.41 0.016 -Fe 14 9024 0.92 0.93 0.53 0.009 0.005 7.06 2.53 0.40 0.074 Fe 15 9021 0.97 0.91 1.04 0.007 0.005 6.85 2.34 0.41 0.027 Fe 16 9023 1.03 1.06 1.20 0.008 0.005 6.97 1.99 0.66 0.047 Fe 17 9038 0.90 0.84 0.49 0.006 0.005 6.69 2.45 0.44 0.023 Fe 18 9039 0.85 0.86 0.47 0.007 0.004 7.28 2.46 0.43 0.022 Fe 20 All the heats were forged to the shape of bars, 60 x 60 mm. The material examinations showed that a steel that satisfies the raised requirements best in terms of the different features mentioned in the foregoing should have the following composition in weight %: 0.82-0.97 C, 0.70-1.10 Si, 0.38-0.62 Mn, at least 7.6 but less than 8.0 Cr, max 0.40 25 Ni, 2.30-2.70 Mo, max 0.25 W, 0.35-0.55 V, balance iron, impurities and accessory elements in normal amounts. Further, the steel normally contains max 0.15 N, preferably max 0.03 N, max 0.30 Cu, and max 6 ppm H. The Al content must be max WO 99/50469 5 PCT/SE99/00346 0.1 %, preferably max 0.045 %, but typically it amounts to 0.010-0.045 % as a residual element from the desoxidation treatment of the steel. Typically, the steel should contain 0.92 C, 0.95 Si, 0.5 Mn, 7.8 Cr, 2.5 Mo, 0.45 V. 5 As far as the micro structure of the steel is concerned, it consists, after austenitising at 1000-1080 0 C, cooling to room temperature and tempering once or several times at 180 650 0 C, of tempered martensite, containing a total carbide volume of 3-6 vol-%, preferably 3-5 vol-%, of which 0.25-0.45 vol-% consists of MC carbides and the rest essentially of M 7

C

3 carbides. Suitably, the amount of primary carbides is about 4 vol-%. 10 The steel of the invention can be manufactured in a conventional way through production of a melt, which is cast to ingots, which can be hot worked to the shape of bars, plates, etc., of which there can be made tools or other articles, which can be heat treated for the achievement of a final product having the desired combination of 15 features. The conventional production of ingots can be complemented by any subsequent melt-metallurgical process step, such as e.g. Electro Slag Refining (ESR) or, as an alternative process, the building up of castings of solidifying drops of the melt, such as the process which is known by the name Osprey. 20 Further characteristics and aspects of the steel of the invention will be apparent from the appending patent claims and from the following description of performed experiments. BRIEF DESCRIPTION OF DRAWING In the following description of performed experiments, reference will be made to the 25 drawing, which in a form of a diagram illustrates the punch wear versus the number of strokes in connection with punching ultrahigh strength steel plate. DESCRIPTION OF PERFORMED EXPERIMENTS The steel of the invention is intended to be used for the manufacture of tools for cold 30 working. Cold work tools are used e.g. in the automotive industry for blanking, punching, pressing and bending thin steel plates. In this field, new, ultrahigh strength steels have been developed in recent years. One of these steels has been developed by SSAB Tunnpl it AB and is known by its trade name DocolTM 1400 DP and contains, besides iron and unavoidable impurities, in weight-% typically: 0.18 C, 0.50 Si, 1.80 35 Mn, 0.015 P, 0.002 S, 0.040 A, and 0.030 Nb. This steel is manufactured in gauges between 0.50 and 2.00 mm, in its delivery condition it has the mechanical features stated in Table 3.

WO 99/50469 6 PCT/SE99/00346 Table 3 - Mechanical Properties of Work Material Steel Yield strength Yield strength after Tensile strength Elongation Min. grade Rpo.

2 or ReL 2 % deformation Rm As 0 radius for N/mm 2 and bake hardening N/mm 2 % 90' bend 170 0 C/20 min in transverse min.-max. Rp2.0+BH direction N/mm 2 mm. min.-max. min. Docol(TM) 4.0 x 1400 DP 1200-(1450) 1350 1400-1600 3 thickness Details in side impact protect systems, bumper reinforcements, seat frames and beams and other structural parts in motor cars are typical applications of this steel. The 5 performed investigations aimed at evaluating the feasibility of the steel for tools for the manufacture of products of the said kind and at comparing the features of the steel with other, commercially available steels for cold work tools. The chemical compositions of the examined steels are listed in Table 4. Steel No. 19 is a 10 steel of the invention. The steel was manufactured as a 35 tons production heat in an electric arc furnace. Of the steel there were cast ingots, which were forged and rolled to the shape of bars. The contents of nickel, niobium, titanium, and copper are residuals from used raw materials and are unintentional. Aluminium has been added for the desoxidation of the steel, and the stated content of aluminium is a residue from that 15 process. Steel No. 20 is a steel according to the above mentioned US-A-5,160,553, which has been manufactured by another producer. The steel, which is commercially available, has been analysed by the applicant with reference to its chemical composition. Steels Nos. 21, 22, and 23 are commercial steels, which are manufactured by the applicant. The contents of steels Nos. 21-23 stated in Table 4 are nominal 20 contents. Steel No. 21 is a conventionally manufactured steel, while steels Nos. 22 and 23 have been manufactured powder metallurgically. Besides the contents of the different elements stated in the tables, these steels also contain impurities in normal amounts eminating from the raw materials which were used for the manufacture of steel.

WO 99/50469 7PCT/SE99/00346 CD 000 __ 661 ON V u CD 1, 0 0 C)o 'r 0 C 00 k ~- t~ 00 C) c> o0 -'4-~ el Cl .- C> " 66 ci 'r 000 00 I-C c0Cl0\ 60 IkV V) 0 al C4 Cl Cl C;Cl C;00 o cq Z t cq, C- ,r 0 WO 99/50469 8 PCT/SE99/00346 Punches with the punch diameter 10 mm were manufactured of bars of steels Nos. 19 23. The bar dimensions are listed in Table 5. All punches were taken out from the centre of the bars and cross-wise the bar direction, the longitudinal direction of the punch coinciding with the height direction of the bar. The working material consisted of said 5 Docol T M 1400 DP with a thickness of 1.0 mm. The material was cold rolled and heat treated for the achievement of highest strength level and it therefore gave a good indication concerning abrasive wear resistance and ductility/toughness. The punching operatings were carried out in a 15 tons excenter press. The punching rate was 200 strokes/min; punching play 6 %; no lubrication. The measurement of the wear was made 10 by means of a prism, the curve deviation being measured before and after the punching series. The difference was transformed to number of ptm 2 , which represents the wear. Table 5 shows the testing parameters and the registered punch wear after 200,000 punching strokes. The table also shows the heat treatment of the tools. All the tools had 15 been hardened from the stated austenitising temperature (TA as is shown in the table) and tempered twice after cooling, each time for two hours at the tempering temperature given in the table. Table 5 Steel Punch wear Bar dimension Hardness Heat treatment No. (ptm 2 ) mm) (HRC) 19 13125 254x76.2 60 TA=1030 0 C/30 min+ 550 0 /2x2h 20 36105 200x100 59.5 TA=1050 0 C/30 min+ 550 0 /2x2h 21 18743 250x80 60,5 TA=102 0 0C/30 min+ 550 0 /2x2h 22 9618 250x80 60 TA=1020 0 C/30 min+ 525 0 /2x2h 23 7790 250x63 60.5 TA=102 0 0C/30 min+ 525'/2x2h 20 In the drawing, the wear during the course of the complete punching test is shown. The results can be explained in the following way. The powder metallurgically manufactured steels Nos. 22 and 23 have sufficient ductility to avoid microchipping of the punch edge, and the smallest abrasive wear stated for steel No. 23 is due to the 25 higher vanadium content in that steel. Steel No. 19 of the invention, which has a well WO 99/50469 9 PCT/SE99/00346 9 balanced chemical composition of alloy elements, also has a balanced combination of features, where abrasive wear dominates over microchipping of the punch edge. The wear resistance was better than that of the substantially higher alloyed steel No. 21 and was comparable with that of the exclusive, powder metallurgically manufactured steels 5 Nos. 22 and 23, which contained high vanadium contents. Especially, steel No. 20 had a pronounced tendency to microchipping of the punch edge, which explains why that material is less good in this test.

Claims

1. Cold work steel, c h a r a c t e r i s e d in that it has the following chemical composition in weight-%: 0.82-0.97 C 5 from traces to max 1.10 Si from traces to max 0.62 Mn at least 7.6 but less than 8.0 Cr

2.30-2.70 Mo 0.35-0.55 V 10 balance iron and impurities in normal amounts in the form of residual elements from the manufacture of the steel. 2. Cold work steel according to claim 1, c h a r a c t e r i s e d in that it contains at least 0.70 Si and at least 0.38 Mn. 15

3. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains max 0.25 W.

4. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains max 20 0.40 Ni.

5. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains max 0.15 N, preferably max 0.03 N. 25

6. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains max 0.30 Cu.

7. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains 0.85 0.95 C. 30

8. Cold work steel according to claim 1, c h a r a c t e r i s e d in that it contains 0.46 0.54 Mn.

9. Cold work steel according to claim 1, c h a r a c t e r i s e d in that it contains 2.40 35 2.60 Mo. WO 99/50469 1 PCT/SE99/00346

10. Cold work steel according to claim 1, c h a r a c t e r i s e d in that it contains 0.4 0.5 V.

11. Cold work steel according to claim 1, c h a r a c t e r is e d in that it contains 0-0.1 5 Al, preferably max 0.045 Al, suitably 0.010-0.045 Al.

12. Cold work steel according to claim 1, c h a r a c t e r i s e d in that it contains 0.92 C, 0.95 Si, 0.5 Mn, 7.8 Cr, 2.5 Mo, 0.45 V. 10

13. Cold work steel according to any of the claims 1-12, c h a r a c t e r i s e d in that it after austenitising at 1000-1080 0 C, cooling to room temperature and tempering once or several times and 180-650 0 C contains 3-6 vol-% carbides, preferably 3-5 vol-% carbides, thereof 0.25-0.45 vol-% MC carbides and the rest essentially M 7 C 3 carbides. 15

14. Use of a cold work steel according to any of the claims 1-13 for the manufacture of cold work tools.

15. Use according to claim 14 for blanking, punching or forming sheet metal. 20

16. Use according to claim 14 for working constructional elements, preferably steel sheets.

17. Use according to claim 14 for working sheet metal for construction elements within the automotive industry, white goods industry and the electronic industry.