AU2017212260B2 - Lithium-selective permeable membrane, lithium recovery device, lithium recovery method and hydrogen production method - Google Patents

Lithium-selective permeable membrane, lithium recovery device, lithium recovery method and hydrogen production method Download PDF

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Publication number
AU2017212260B2
AU2017212260B2 AU2017212260A AU2017212260A AU2017212260B2 AU 2017212260 B2 AU2017212260 B2 AU 2017212260B2 AU 2017212260 A AU2017212260 A AU 2017212260A AU 2017212260 A AU2017212260 A AU 2017212260A AU 2017212260 B2 AU2017212260 B2 AU 2017212260B2
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lithium
permeable membrane
recovery
liquid
selective permeable
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AU2017212260A1 (en
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Tsuyoshi Hoshino
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National Institutes For Quantum Science and Technology
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National Institutes For Quantum Science and Technology
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B7/00—Electrophoretic production of compounds or non-metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
    • B01D61/44—Ion-selective electrodialysis
    • B01D61/46—Apparatus therefor
    • B01D61/461—Apparatus therefor comprising only a single cell, only one anion or cation exchange membrane or one pair of anion and cation membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0093—Chemical modification
    • B01D67/00933—Chemical modification by addition of a layer chemically bonded to the membrane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/12—Composite membranes; Ultra-thin membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/024—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D15/00—Lithium compounds
    • C01D15/08—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/469—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis
    • C02F1/4693—Treatment of water, waste water, or sewage by electrochemical methods by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis electrodialysis
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/10—Obtaining alkali metals
    • C22B26/12—Obtaining lithium
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/08—Seawater, e.g. for desalination
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/22—Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/227—Dialytic cells or batteries; Reverse electrodialysis cells or batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Metallurgy (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Molecular Biology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Urology & Nephrology (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Geology (AREA)
  • Hydrology & Water Resources (AREA)
  • Analytical Chemistry (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
AU2017212260A 2016-01-29 2017-01-26 Lithium-selective permeable membrane, lithium recovery device, lithium recovery method and hydrogen production method Active AU2017212260B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2016015423A JP6818334B2 (ja) 2016-01-29 2016-01-29 リチウム選択透過膜、リチウム回収装置、リチウム回収方法、水素製造方法
JP2016-015423 2016-01-29
PCT/JP2017/002612 WO2017131051A1 (ja) 2016-01-29 2017-01-26 リチウム選択透過膜、リチウム回収装置、リチウム回収方法、水素製造方法

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AU2017212260A1 AU2017212260A1 (en) 2018-08-16
AU2017212260B2 true AU2017212260B2 (en) 2019-09-12

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US (1) US10689766B2 (enExample)
JP (1) JP6818334B2 (enExample)
KR (1) KR102064692B1 (enExample)
AU (1) AU2017212260B2 (enExample)
CL (1) CL2018002018A1 (enExample)
WO (1) WO2017131051A1 (enExample)

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US11253848B2 (en) 2017-08-02 2022-02-22 Lilac Solutions, Inc. Lithium extraction with porous ion exchange beads
CA3071649C (en) 2017-08-02 2025-05-20 Lilac Solutions, Inc. ION EXCHANGE SYSTEM FOR LITHIUM EXTRACTION
JP7270130B2 (ja) * 2017-10-31 2023-05-10 出光興産株式会社 リチウム回収装置及びリチウム回収方法
JP7029798B2 (ja) * 2018-02-22 2022-03-04 国立大学法人弘前大学 リチウム同位体濃縮装置および多段式リチウム同位体濃縮装置、ならびにリチウム同位体濃縮方法
MA52428A (fr) 2018-02-28 2021-06-02 Lilac Solutions Inc Réacteur d'échange d'ions à piège à particules pour extraction de lithium
AU2019297527B2 (en) 2018-07-06 2024-07-25 Moselle Technologies, Llc Methods and compositions for recovery of lithium from liquid solutions with nanoparticles
JP2022001341A (ja) * 2018-09-07 2022-01-06 富士フイルム株式会社 リチウムイオン選択透過膜、この膜を用いたリチウムイオン回収装置及びリチウム含有化合物回収装置、並びに、リチウムイオンの回収方法
CN109317087B (zh) * 2018-09-14 2021-09-07 四川泛宇锂能新材料科技有限公司 一种掺杂钛酸锂吸附剂及其制备方法
CN109487081B (zh) * 2018-12-05 2020-04-28 天津科技大学 采用流动电极的提锂单元及扩展装置和连续操作方法
AR118307A1 (es) * 2019-03-29 2021-09-29 National Institutes For Quantum And Radiological Science And Tech Dispositivo de recuperación de iones metálicos, sistema de recuperación de metales y método de recuperación de iones metálicos
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KR102208041B1 (ko) * 2019-06-11 2021-01-27 주식회사 셀젠 흡착재를 이용한 리튬의 흡착, 탈착 및 농축장치
KR102208040B1 (ko) * 2019-06-11 2021-01-27 주식회사 셀젠 흡착재를 이용한 리튬의 고농도화 방법
EP4013536A4 (en) 2019-08-12 2023-08-23 Monash University LITHIUM ION CONDUCTIVE POLYMER CERAMIC MEMBRANE
JP2023514803A (ja) 2020-01-09 2023-04-11 ライラック ソリューションズ，インク． 望ましくない金属を分離するための方法
CN111214959A (zh) * 2020-01-15 2020-06-02 上海应用技术大学 一种氧化石墨烯膜及其制备方法和应用
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JP7531298B2 (ja) * 2020-03-30 2024-08-09 株式会社日本触媒 リチウム分離シートの製造方法
US20230155244A1 (en) * 2020-04-08 2023-05-18 Idemitsu Kosan Co.,Ltd. Ion selective permeable membrane and ion recovery device
CA3178825A1 (en) 2020-06-09 2021-12-16 David Henry SNYDACKER Lithium extraction in the presence of scalants
JP2023541917A (ja) * 2020-09-16 2023-10-04 ザ リージェンツ オブ ザ ユニバーシティ オブ カリフォルニア 多孔質ポリマー骨格を組み込んだ荷電膜
EP4247759A1 (en) 2020-11-20 2023-09-27 Lilac Solutions, Inc. Lithium production with volatile acid
JP7542221B2 (ja) * 2021-01-19 2024-08-30 パナソニックＩｐマネジメント株式会社 イオン透過膜およびその製造方法
EP4281594A1 (en) 2021-01-19 2023-11-29 King Abdullah University of Science and Technology System and process for enriching lithium from seawater
JP7705925B2 (ja) * 2021-03-25 2025-07-10 出光興産株式会社 水酸化リチウムの製造方法
KR20240014047A (ko) 2021-04-23 2024-01-31 리락 솔루션즈, 인크. 리튬 추출을 위한 이온 교환 장치
CN113856490A (zh) * 2021-10-11 2021-12-31 中南大学 一种锂离子筛膜制备方法及双级电渗析装置
WO2023192192A1 (en) 2022-03-28 2023-10-05 Lilac Solutions, Inc. Lithium extraction enhanced by an alternate phase
AU2023245969A1 (en) * 2022-03-31 2024-10-10 Xerion Advanced Battery Corp. Redox membranes for lithium extraction
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CN120659658A (zh) 2023-02-21 2025-09-16 日本精细陶瓷有限公司 锂选择透过膜及该锂选择透过膜的制造方法
WO2025022530A1 (ja) 2023-07-24 2025-01-30 日産自動車株式会社 リチウムの回収方法

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JP2013001951A (ja) * 2011-06-16 2013-01-07 Hitachi Ltd 透析促進剤および金属回収方法

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WO2017131051A1 (ja) 2017-08-03
JP6818334B2 (ja) 2021-01-20
KR102064692B1 (ko) 2020-01-08
AU2017212260A1 (en) 2018-08-16
CL2018002018A1 (es) 2018-08-31
JP2017131863A (ja) 2017-08-03
KR20180098362A (ko) 2018-09-03
US10689766B2 (en) 2020-06-23
US20190032230A1 (en) 2019-01-31

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