AU2013330420B2 - Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming - Google Patents
Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming Download PDFInfo
- Publication number
- AU2013330420B2 AU2013330420B2 AU2013330420A AU2013330420A AU2013330420B2 AU 2013330420 B2 AU2013330420 B2 AU 2013330420B2 AU 2013330420 A AU2013330420 A AU 2013330420A AU 2013330420 A AU2013330420 A AU 2013330420A AU 2013330420 B2 AU2013330420 B2 AU 2013330420B2
- Authority
- AU
- Australia
- Prior art keywords
- methane
- carbon dioxide
- methanol
- combustion
- source
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 245
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 188
- 238000002407 reforming Methods 0.000 title abstract description 24
- 238000004519 manufacturing process Methods 0.000 title abstract description 13
- 230000001590 oxidative effect Effects 0.000 title description 4
- 238000000034 method Methods 0.000 claims abstract description 77
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 68
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 46
- 239000007789 gas Substances 0.000 claims abstract description 44
- 238000002485 combustion reaction Methods 0.000 claims abstract description 41
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 34
- 239000000203 mixture Substances 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 30
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000001301 oxygen Substances 0.000 claims abstract description 26
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 26
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 20
- 239000001257 hydrogen Substances 0.000 claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 15
- 239000003054 catalyst Substances 0.000 claims description 28
- 238000006057 reforming reaction Methods 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 229910044991 metal oxide Inorganic materials 0.000 claims description 13
- 239000000376 reactant Substances 0.000 claims description 13
- 150000004706 metal oxides Chemical class 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000003245 coal Substances 0.000 claims description 8
- 230000018044 dehydration Effects 0.000 claims description 7
- 238000006297 dehydration reaction Methods 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052802 copper Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims 1
- 229960003903 oxygen Drugs 0.000 claims 1
- 239000000047 product Substances 0.000 description 13
- 230000003647 oxidation Effects 0.000 description 11
- 238000007254 oxidation reaction Methods 0.000 description 11
- 239000000446 fuel Substances 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 238000002453 autothermal reforming Methods 0.000 description 5
- 239000003345 natural gas Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 108010027322 single cell proteins Proteins 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229910052797 bismuth Inorganic materials 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- 238000000629 steam reforming Methods 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 229910021485 fumed silica Inorganic materials 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 239000001294 propane Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261711610P | 2012-10-09 | 2012-10-09 | |
| US61/711,610 | 2012-10-09 | ||
| US13/791,778 US8697759B1 (en) | 2012-10-09 | 2013-03-08 | Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming |
| US13/791,778 | 2013-03-08 | ||
| PCT/US2013/058469 WO2014058549A1 (en) | 2012-10-09 | 2013-09-06 | Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2013330420A1 AU2013330420A1 (en) | 2015-04-09 |
| AU2013330420B2 true AU2013330420B2 (en) | 2016-10-27 |
Family
ID=50433203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2013330420A Ceased AU2013330420B2 (en) | 2012-10-09 | 2013-09-06 | Efficient, self sufficient production of methanol from a methane source via oxidative bi-reforming |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8697759B1 (enExample) |
| EP (1) | EP2906523B1 (enExample) |
| JP (1) | JP6352929B2 (enExample) |
| KR (1) | KR101951985B1 (enExample) |
| CN (1) | CN104822644B (enExample) |
| AU (1) | AU2013330420B2 (enExample) |
| CA (1) | CA2886004C (enExample) |
| ES (1) | ES2615892T3 (enExample) |
| WO (1) | WO2014058549A1 (enExample) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20160237362A1 (en) | 2015-02-18 | 2016-08-18 | University Of Southern California | Methanol fuels for internal combustion engines |
| WO2016144942A1 (en) * | 2015-03-09 | 2016-09-15 | Olah George A | Common regenerative and environmentally benign methanol fuels for all internal combustion engines for transportation vehicles and other applications |
| US10364398B2 (en) | 2016-08-30 | 2019-07-30 | Thermochem Recovery International, Inc. | Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas |
| GB2556929A (en) * | 2016-11-26 | 2018-06-13 | Avocet Infinite Plc | Apparatus and method for producing methanol |
| GB2556930A (en) * | 2016-11-27 | 2018-06-13 | Avocet Infinite Plc | Apparatus and method for producing methanol |
| EP3833651B1 (en) * | 2018-08-06 | 2023-03-08 | SABIC Global Technologies B.V. | Process for producing methanol |
| CN110013857A (zh) * | 2019-04-04 | 2019-07-16 | 江苏科技大学 | 一种焦炉煤气改质催化剂及其制备方法和应用 |
| US11555157B2 (en) | 2020-03-10 | 2023-01-17 | Thermochem Recovery International, Inc. | System and method for liquid fuel production from carbonaceous materials using recycled conditioned syngas |
| KR102590896B1 (ko) | 2020-12-22 | 2023-10-19 | 울산대학교 산학협력단 | 고체 전해질의 제조방법 및 이로부터 제조된 고체 전해질 |
| US20230415114A1 (en) * | 2021-03-10 | 2023-12-28 | Korea Institute Of Machinery & Materials | Biogas reformer |
| US12098122B2 (en) | 2021-03-19 | 2024-09-24 | Saudi Arabian Oil Company | Production of acetic acid through cryogenic separation of syngas |
| EP4351765A4 (en) * | 2021-05-19 | 2025-06-04 | Massachusetts Institute Of Technology | LOW-LEVEL METHANE REDUCTION USING CATALYTIC MATERIALS, ABUNDANT ON EARTH |
| CN115231522A (zh) * | 2022-09-22 | 2022-10-25 | 小跃科技(北京)有限公司 | 一种用于高温裂解二氧化碳的反应釜 |
| CN118950076A (zh) * | 2023-05-15 | 2024-11-15 | 华东师范大学 | 一种甲烷氧化耦合二氧化碳加氢制备甲醇的双功能催化剂及其制备方法和应用 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4618732A (en) * | 1985-05-20 | 1986-10-21 | Gesser Hyman D | Direct conversion of natural gas to methanol by controlled oxidation |
| US5342702A (en) * | 1993-01-05 | 1994-08-30 | Integrated Energy Development Corp. | Synergistic process for the production of carbon dioxide using a cogeneration reactor |
| US5856585A (en) * | 1993-08-27 | 1999-01-05 | Snamprogetti S.P.A. | Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde |
| US20080319093A1 (en) * | 2007-06-21 | 2008-12-25 | Olah George A | Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas |
| WO2012045373A1 (en) * | 2010-10-06 | 2012-04-12 | Silicon Fire Ag | Method and apparatus for the integrated synthesis of methanol in a plant |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3993457A (en) | 1973-07-30 | 1976-11-23 | Exxon Research And Engineering Company | Concurrent production of methanol and synthetic natural gas |
| US4098339A (en) | 1976-06-21 | 1978-07-04 | Mobil Oil Corporation | Utilization of low BTU natural gas |
| GB1545329A (en) | 1976-06-21 | 1979-05-10 | Mobil Oil Corp | Utilization of low btu natural gas to produce methanol or liquid hydrocarbons |
| NZ194405A (en) | 1979-08-02 | 1982-05-25 | Dut Pty Ltd | Producing liquid hydrocarbon streams by hydrogenation of fossil-based feedstock |
| CA1241667A (en) | 1984-04-25 | 1988-09-06 | Martin F.M. Post | Process for the preparation of hydrocarbons |
| JPS61516A (ja) * | 1984-06-12 | 1986-01-06 | Toyo Rokougiyou Kk | 雰囲気ガス発生装置 |
| JPS63252904A (ja) * | 1987-01-28 | 1988-10-20 | Toyo Rokougiyou Kk | 雰囲気ガス製造方法 |
| FR2684313B1 (fr) * | 1991-12-03 | 1994-01-28 | Institut Francais Petrole | Procede et dispositif pour la fabrication de gaz de synthese et application. |
| US5599638A (en) | 1993-10-12 | 1997-02-04 | California Institute Of Technology | Aqueous liquid feed organic fuel cell using solid polymer electrolyte membrane |
| US5767165A (en) | 1995-03-16 | 1998-06-16 | Steinberg; Meyer | Method for converting natural gas and carbon dioxide to methanol and reducing CO2 emissions |
| US7132183B2 (en) | 2002-06-27 | 2006-11-07 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
| JP4309627B2 (ja) | 2002-09-06 | 2009-08-05 | 東洋エンジニアリング株式会社 | ジメチルエーテルの製造方法 |
| US7608743B2 (en) | 2005-04-15 | 2009-10-27 | University Of Southern California | Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products |
| WO2006113293A1 (en) | 2005-04-15 | 2006-10-26 | University Of Southern California | Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products |
| CA2604574C (en) | 2005-04-15 | 2013-11-19 | University Of Southern California | Selective oxidative conversion of methane to methanol, dimethyl ether and derived products |
| WO2007014487A1 (en) | 2005-08-01 | 2007-02-08 | Dalian Institute Of Chemical Physics, Chinese Academy Of Sciences | An integrated process for the co-production of methanol and demethyl ether from syngas containing nitrogen |
| US7378561B2 (en) * | 2006-08-10 | 2008-05-27 | University Of Southern California | Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material |
| US7795175B2 (en) | 2006-08-10 | 2010-09-14 | University Of Southern California | Nano-structure supported solid regenerative polyamine and polyamine polyol absorbents for the separation of carbon dioxide from gas mixtures including the air |
| KR20120005447A (ko) * | 2009-04-10 | 2012-01-16 | 유니버시티 오브 써던 캘리포니아 | 석유를 연료용의 환경적으로 이산화탄소 중립 공급 물질, 유도 생성물, 및 재생 탄소 공급원으로 만드는 방법 |
| CN102388011A (zh) * | 2009-04-10 | 2012-03-21 | 南加州大学 | 使天然气成为环境上二氧化碳中性燃料和再生碳源 |
| US8461215B2 (en) * | 2009-04-10 | 2013-06-11 | University Of Southern California | Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source |
-
2013
- 2013-03-08 US US13/791,778 patent/US8697759B1/en active Active
- 2013-09-06 JP JP2015535660A patent/JP6352929B2/ja active Active
- 2013-09-06 CA CA2886004A patent/CA2886004C/en active Active
- 2013-09-06 AU AU2013330420A patent/AU2013330420B2/en not_active Ceased
- 2013-09-06 EP EP13770737.8A patent/EP2906523B1/en not_active Not-in-force
- 2013-09-06 WO PCT/US2013/058469 patent/WO2014058549A1/en not_active Ceased
- 2013-09-06 CN CN201380052887.2A patent/CN104822644B/zh not_active Expired - Fee Related
- 2013-09-06 ES ES13770737.8T patent/ES2615892T3/es active Active
- 2013-09-06 KR KR1020157008826A patent/KR101951985B1/ko not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4618732A (en) * | 1985-05-20 | 1986-10-21 | Gesser Hyman D | Direct conversion of natural gas to methanol by controlled oxidation |
| US5342702A (en) * | 1993-01-05 | 1994-08-30 | Integrated Energy Development Corp. | Synergistic process for the production of carbon dioxide using a cogeneration reactor |
| US5856585A (en) * | 1993-08-27 | 1999-01-05 | Snamprogetti S.P.A. | Process of catalytic partial oxidation of natural gas in order to obtain synthesis gas and formaldehyde |
| US20080319093A1 (en) * | 2007-06-21 | 2008-12-25 | Olah George A | Conversion of carbon dioxide to methanol and/or dimethyl ether using bi-reforming of methane or natural gas |
| WO2012045373A1 (en) * | 2010-10-06 | 2012-04-12 | Silicon Fire Ag | Method and apparatus for the integrated synthesis of methanol in a plant |
Non-Patent Citations (1)
| Title |
|---|
| Catalysis Letters, 1998, pp 69-75 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US8697759B1 (en) | 2014-04-15 |
| CA2886004C (en) | 2018-07-03 |
| CN104822644B (zh) | 2017-10-10 |
| EP2906523B1 (en) | 2016-11-16 |
| AU2013330420A1 (en) | 2015-04-09 |
| CN104822644A (zh) | 2015-08-05 |
| WO2014058549A1 (en) | 2014-04-17 |
| ES2615892T3 (es) | 2017-06-08 |
| JP6352929B2 (ja) | 2018-07-04 |
| KR20150093652A (ko) | 2015-08-18 |
| EP2906523A1 (en) | 2015-08-19 |
| US20140100391A1 (en) | 2014-04-10 |
| KR101951985B1 (ko) | 2019-02-25 |
| JP2015533827A (ja) | 2015-11-26 |
| CA2886004A1 (en) | 2014-04-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |