AU2012351266B2 - Heavy oil catalytic cracking catalyst and preparation method therefor - Google Patents

Heavy oil catalytic cracking catalyst and preparation method therefor

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Publication number
AU2012351266B2
AU2012351266B2 AU2012351266A AU2012351266A AU2012351266B2 AU 2012351266 B2 AU2012351266 B2 AU 2012351266B2 AU 2012351266 A AU2012351266 A AU 2012351266A AU 2012351266 A AU2012351266 A AU 2012351266A AU 2012351266 B2 AU2012351266 B2 AU 2012351266B2
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rare earth
molecular sieve
exchange
weight
roasted
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AU2012351266A
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AU2012351266A1 (en
Inventor
Hongchang Duan
Xionghou Gao
Dong JI
Di Li
Zhengguo Tan
Chenxi Zhang
Haitao Zhang
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Petrochina Co Ltd
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Petrochina Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/51Spheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/70Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/026After-treatment
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20Faujasite type, e.g. type X or Y
    • C01B39/24Type Y
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J2029/062Mixtures of different aluminosilicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/37Acid treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/40Special temperature treatment, i.e. other than just for template removal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B01J29/088Y-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/67Pore distribution monomodal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66Pore distribution
    • B01J35/69Pore distribution bimodal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
AU2012351266A 2011-12-15 2012-04-13 Heavy oil catalytic cracking catalyst and preparation method therefor Active AU2012351266B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN201110419922.2 2011-12-15
CN201110419922.2A CN103157507B (zh) 2011-12-15 2011-12-15 一种重油催化裂化催化剂及其制备方法
PCT/CN2012/000508 WO2013086767A1 (zh) 2011-12-15 2012-04-13 一种重油催化裂化催化剂及其制备方法

Publications (2)

Publication Number Publication Date
AU2012351266A1 AU2012351266A1 (en) 2014-08-07
AU2012351266B2 true AU2012351266B2 (en) 2016-07-14

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Country Status (7)

Country Link
US (1) US9844772B2 (https=)
JP (1) JP5941994B2 (https=)
CN (1) CN103157507B (https=)
AU (1) AU2012351266B2 (https=)
CA (1) CA2862144C (https=)
SG (1) SG11201404089RA (https=)
WO (1) WO2013086767A1 (https=)

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CN103157507B (zh) 2011-12-15 2015-05-13 中国石油天然气股份有限公司 一种重油催化裂化催化剂及其制备方法
CN104923282B (zh) * 2015-06-25 2017-08-15 湖北赛因化工有限公司 一种高稀土含量原位晶化催化剂的超稳化处理方法
US11084024B2 (en) 2015-08-05 2021-08-10 Petrochina Company Limited Method for modifying molecular sieve and a catalytic cracking catalyst containing the molecular sieve
CN105314652B (zh) * 2015-11-27 2017-10-27 郑州大学 一种h型zsm‑5分子筛的制备方法
CN106809856A (zh) * 2015-12-01 2017-06-09 中国石油天然气股份有限公司 一种重油催化裂化催化剂及其制备方法
CN106925334B (zh) * 2015-12-29 2019-12-10 中国石油天然气股份有限公司 一种抗重金属的重油裂化催化剂及其制备方法
CN108404897B (zh) * 2017-02-10 2021-03-09 中国石油天然气股份有限公司 一种重油加氢催化剂载体、其制备方法、应用其的催化剂及催化剂的制备方法
CN108101073A (zh) * 2017-12-27 2018-06-01 洛阳神佳窑业有限公司 一种分子筛催化剂的制备方法
CA3087960A1 (en) 2018-01-12 2019-07-18 Albemarle Corporation Fcc catalyst with enhanced mesoporosity, its preparation and use
CN111085243B (zh) * 2018-10-23 2022-06-28 中国石油化工股份有限公司 一种负载金属的rey分子筛催化剂、制备方法及其应用
CN109772426B (zh) * 2019-01-23 2021-09-21 浙江恒澜科技有限公司 含微量稀土离子的微球型mfi拓扑学结构全硅-1分子筛催化剂及其喷雾成型制备方法
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CN111686787B (zh) * 2020-06-10 2023-10-03 中国石油天然气集团有限公司 加氢裂化催化剂载体及其制备方法与应用
CN114477218A (zh) * 2020-10-28 2022-05-13 中国石油化工股份有限公司 分子筛晶化浆料清洗设备和清洗方法
CN114433253B (zh) * 2020-11-02 2023-10-24 中国石油化工股份有限公司 催化裂化催化剂及其制备方法
CN112551489B (zh) * 2020-12-08 2023-02-28 中触媒新材料股份有限公司 一种改性y型分子筛再生剂、制备方法及其应用
CN115672380B (zh) * 2021-07-23 2024-05-24 中国石油化工股份有限公司 一种低生焦催化裂化催化剂制备方法
CN117225459B (zh) * 2022-06-07 2026-03-24 中国石油天然气股份有限公司 一种催化裂化催化剂及其制备方法
CN118831635B (zh) * 2023-04-23 2026-01-27 中国石油天然气股份有限公司 一种抗钒催化裂化催化剂的制备方法
CN119114149B (zh) * 2023-06-13 2026-01-20 中国石油天然气股份有限公司 一种多产丙烯催化裂化催化剂及其制备方法与应用
CN116809124B (zh) * 2023-07-13 2025-07-18 中油(长汀)催化剂有限公司 一种催化裂化催化剂的制备方法
TW202508967A (zh) 2023-08-28 2025-03-01 大陸商中國石油化工科技開發有限公司 一種單晶中空zsm-5分子篩、包含所述分子篩的催化劑及其製備方法與用途
WO2025045052A1 (zh) 2023-08-29 2025-03-06 中国石油化工股份有限公司 一种单晶中空zsm-5分子筛,包含所述分子筛的催化剂及其制备方法和用途

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Publication number Publication date
US9844772B2 (en) 2017-12-19
CN103157507A (zh) 2013-06-19
CN103157507B (zh) 2015-05-13
AU2012351266A1 (en) 2014-08-07
CA2862144C (en) 2018-02-13
US20150080209A1 (en) 2015-03-19
SG11201404089RA (en) 2014-10-30
JP2015506821A (ja) 2015-03-05
JP5941994B2 (ja) 2016-06-29
CA2862144A1 (en) 2013-06-20
WO2013086767A1 (zh) 2013-06-20

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