AU2012351266B2 - Heavy oil catalytic cracking catalyst and preparation method therefor - Google Patents
Heavy oil catalytic cracking catalyst and preparation method thereforInfo
- Publication number
- AU2012351266B2 AU2012351266B2 AU2012351266A AU2012351266A AU2012351266B2 AU 2012351266 B2 AU2012351266 B2 AU 2012351266B2 AU 2012351266 A AU2012351266 A AU 2012351266A AU 2012351266 A AU2012351266 A AU 2012351266A AU 2012351266 B2 AU2012351266 B2 AU 2012351266B2
- Authority
- AU
- Australia
- Prior art keywords
- rare earth
- molecular sieve
- exchange
- weight
- roasted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/51—Spheres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/026—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/20—Faujasite type, e.g. type X or Y
- C01B39/24—Type Y
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J2029/062—Mixtures of different aluminosilicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/37—Acid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/40—Special temperature treatment, i.e. other than just for template removal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
- B01J29/088—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/67—Pore distribution monomodal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/69—Pore distribution bimodal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0045—Drying a slurry, e.g. spray drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/30—Ion-exchange
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110419922.2 | 2011-12-15 | ||
| CN201110419922.2A CN103157507B (zh) | 2011-12-15 | 2011-12-15 | 一种重油催化裂化催化剂及其制备方法 |
| PCT/CN2012/000508 WO2013086767A1 (zh) | 2011-12-15 | 2012-04-13 | 一种重油催化裂化催化剂及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2012351266A1 AU2012351266A1 (en) | 2014-08-07 |
| AU2012351266B2 true AU2012351266B2 (en) | 2016-07-14 |
Family
ID=48581342
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2012351266A Active AU2012351266B2 (en) | 2011-12-15 | 2012-04-13 | Heavy oil catalytic cracking catalyst and preparation method therefor |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9844772B2 (https=) |
| JP (1) | JP5941994B2 (https=) |
| CN (1) | CN103157507B (https=) |
| AU (1) | AU2012351266B2 (https=) |
| CA (1) | CA2862144C (https=) |
| SG (1) | SG11201404089RA (https=) |
| WO (1) | WO2013086767A1 (https=) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103157507B (zh) | 2011-12-15 | 2015-05-13 | 中国石油天然气股份有限公司 | 一种重油催化裂化催化剂及其制备方法 |
| CN104923282B (zh) * | 2015-06-25 | 2017-08-15 | 湖北赛因化工有限公司 | 一种高稀土含量原位晶化催化剂的超稳化处理方法 |
| US11084024B2 (en) | 2015-08-05 | 2021-08-10 | Petrochina Company Limited | Method for modifying molecular sieve and a catalytic cracking catalyst containing the molecular sieve |
| CN105314652B (zh) * | 2015-11-27 | 2017-10-27 | 郑州大学 | 一种h型zsm‑5分子筛的制备方法 |
| CN106809856A (zh) * | 2015-12-01 | 2017-06-09 | 中国石油天然气股份有限公司 | 一种重油催化裂化催化剂及其制备方法 |
| CN106925334B (zh) * | 2015-12-29 | 2019-12-10 | 中国石油天然气股份有限公司 | 一种抗重金属的重油裂化催化剂及其制备方法 |
| CN108404897B (zh) * | 2017-02-10 | 2021-03-09 | 中国石油天然气股份有限公司 | 一种重油加氢催化剂载体、其制备方法、应用其的催化剂及催化剂的制备方法 |
| CN108101073A (zh) * | 2017-12-27 | 2018-06-01 | 洛阳神佳窑业有限公司 | 一种分子筛催化剂的制备方法 |
| CA3087960A1 (en) | 2018-01-12 | 2019-07-18 | Albemarle Corporation | Fcc catalyst with enhanced mesoporosity, its preparation and use |
| CN111085243B (zh) * | 2018-10-23 | 2022-06-28 | 中国石油化工股份有限公司 | 一种负载金属的rey分子筛催化剂、制备方法及其应用 |
| CN109772426B (zh) * | 2019-01-23 | 2021-09-21 | 浙江恒澜科技有限公司 | 含微量稀土离子的微球型mfi拓扑学结构全硅-1分子筛催化剂及其喷雾成型制备方法 |
| JP7576429B2 (ja) * | 2019-11-15 | 2024-10-31 | 日揮触媒化成株式会社 | 流動接触分解触媒の製造方法 |
| CN111686787B (zh) * | 2020-06-10 | 2023-10-03 | 中国石油天然气集团有限公司 | 加氢裂化催化剂载体及其制备方法与应用 |
| CN114477218A (zh) * | 2020-10-28 | 2022-05-13 | 中国石油化工股份有限公司 | 分子筛晶化浆料清洗设备和清洗方法 |
| CN114433253B (zh) * | 2020-11-02 | 2023-10-24 | 中国石油化工股份有限公司 | 催化裂化催化剂及其制备方法 |
| CN112551489B (zh) * | 2020-12-08 | 2023-02-28 | 中触媒新材料股份有限公司 | 一种改性y型分子筛再生剂、制备方法及其应用 |
| CN115672380B (zh) * | 2021-07-23 | 2024-05-24 | 中国石油化工股份有限公司 | 一种低生焦催化裂化催化剂制备方法 |
| CN117225459B (zh) * | 2022-06-07 | 2026-03-24 | 中国石油天然气股份有限公司 | 一种催化裂化催化剂及其制备方法 |
| CN118831635B (zh) * | 2023-04-23 | 2026-01-27 | 中国石油天然气股份有限公司 | 一种抗钒催化裂化催化剂的制备方法 |
| CN119114149B (zh) * | 2023-06-13 | 2026-01-20 | 中国石油天然气股份有限公司 | 一种多产丙烯催化裂化催化剂及其制备方法与应用 |
| CN116809124B (zh) * | 2023-07-13 | 2025-07-18 | 中油(长汀)催化剂有限公司 | 一种催化裂化催化剂的制备方法 |
| TW202508967A (zh) | 2023-08-28 | 2025-03-01 | 大陸商中國石油化工科技開發有限公司 | 一種單晶中空zsm-5分子篩、包含所述分子篩的催化劑及其製備方法與用途 |
| WO2025045052A1 (zh) | 2023-08-29 | 2025-03-06 | 中国石油化工股份有限公司 | 一种单晶中空zsm-5分子筛,包含所述分子筛的催化剂及其制备方法和用途 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5006497A (en) | 1988-12-30 | 1991-04-09 | Mobil Oil Corporation | Multi component catalyst and a process for catalytic cracking of heavy hydrocarbon feed to lighter products |
| JPH04108608A (ja) | 1990-08-30 | 1992-04-09 | Kanebo Ltd | ゼオライトをイオン交換する方法 |
| ZA918623B (en) | 1990-12-04 | 1992-08-26 | Grace W R & Co | Dual zeolite fluid cracking catalyst composition for improved gasoline octane |
| JP3737155B2 (ja) | 1995-02-27 | 2006-01-18 | 触媒化成工業株式会社 | 炭化水素接触分解用触媒組成物 |
| US5788834A (en) | 1996-07-19 | 1998-08-04 | Exxon Research And Engineering Company | Catalytic cracking process with Y zeolite catalyst comprising silica binder containing silica gel |
| CN1075466C (zh) | 1997-12-16 | 2001-11-28 | 中国石油化工总公司 | 一种超稳y沸石的制备方法 |
| CN1111136C (zh) | 2000-11-13 | 2003-06-11 | 中国石油化工股份有限公司 | 一种y型分子筛的制备 |
| JP3948905B2 (ja) * | 2001-02-21 | 2007-07-25 | 財団法人 国際石油交流センター | 重質油の流動接触分解法 |
| CN1215905C (zh) | 2002-12-13 | 2005-08-24 | 中国石油天然气股份有限公司 | 一种超稳稀土y分子筛活性组分及其制备方法 |
| CN1307098C (zh) | 2004-03-31 | 2007-03-28 | 中国石油化工股份有限公司 | 一种稀土超稳y型沸石的制备方法 |
| CN100344374C (zh) | 2004-08-13 | 2007-10-24 | 中国石油化工股份有限公司 | 一种稀土y分子筛及其制备方法 |
| CN1322928C (zh) | 2004-08-13 | 2007-06-27 | 中国石油化工股份有限公司 | 一种降低催化裂化汽油烯烃含量的裂化催化剂 |
| CN100357399C (zh) * | 2005-03-31 | 2007-12-26 | 中国石油化工股份有限公司 | 一种裂化催化剂的制备方法 |
| CN100497175C (zh) | 2005-10-31 | 2009-06-10 | 中国石油化工股份有限公司 | 一种提高超稳y型沸石稀土含量的方法 |
| CN101190416B (zh) * | 2006-12-01 | 2011-06-15 | 石大卓越科技股份有限公司 | 一种催化裂化催化剂及其制备方法 |
| CN101210187B (zh) | 2006-12-27 | 2011-09-14 | 中国石油化工股份有限公司 | 一种重油裂化催化剂的制备方法 |
| CN101285001B (zh) | 2007-04-12 | 2011-11-30 | 中国石油化工股份有限公司 | 一种催化裂化催化剂 |
| CN101284243B (zh) | 2007-04-12 | 2011-04-20 | 中国石油化工股份有限公司 | 一种催化裂化催化剂 |
| TW201029929A (en) * | 2008-12-18 | 2010-08-16 | Grace W R & Co | Novel ultra stable zeolite Y and method for manufacturing the same |
| CN101767027B (zh) * | 2008-12-31 | 2012-08-29 | 中国石油化工股份有限公司 | 一种含超稳分子筛的裂化催化剂的制备方法 |
| CN102029177B (zh) | 2009-09-28 | 2012-07-18 | 中国石油化工股份有限公司 | 一种裂化催化剂及其制备方法 |
| CN102133542A (zh) * | 2010-01-27 | 2011-07-27 | 华东理工大学 | 一种复合型催化裂化催化剂及其制备方法 |
| CN103157507B (zh) | 2011-12-15 | 2015-05-13 | 中国石油天然气股份有限公司 | 一种重油催化裂化催化剂及其制备方法 |
-
2011
- 2011-12-15 CN CN201110419922.2A patent/CN103157507B/zh active Active
-
2012
- 2012-04-13 SG SG11201404089RA patent/SG11201404089RA/en unknown
- 2012-04-13 AU AU2012351266A patent/AU2012351266B2/en active Active
- 2012-04-13 CA CA2862144A patent/CA2862144C/en active Active
- 2012-04-13 WO PCT/CN2012/000508 patent/WO2013086767A1/zh not_active Ceased
- 2012-04-13 JP JP2014546274A patent/JP5941994B2/ja active Active
- 2012-04-13 US US14/364,536 patent/US9844772B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US9844772B2 (en) | 2017-12-19 |
| CN103157507A (zh) | 2013-06-19 |
| CN103157507B (zh) | 2015-05-13 |
| AU2012351266A1 (en) | 2014-08-07 |
| CA2862144C (en) | 2018-02-13 |
| US20150080209A1 (en) | 2015-03-19 |
| SG11201404089RA (en) | 2014-10-30 |
| JP2015506821A (ja) | 2015-03-05 |
| JP5941994B2 (ja) | 2016-06-29 |
| CA2862144A1 (en) | 2013-06-20 |
| WO2013086767A1 (zh) | 2013-06-20 |
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