AU2012224772B2 - Composite elements - Google Patents
Composite elements Download PDFInfo
- Publication number
- AU2012224772B2 AU2012224772B2 AU2012224772A AU2012224772A AU2012224772B2 AU 2012224772 B2 AU2012224772 B2 AU 2012224772B2 AU 2012224772 A AU2012224772 A AU 2012224772A AU 2012224772 A AU2012224772 A AU 2012224772A AU 2012224772 B2 AU2012224772 B2 AU 2012224772B2
- Authority
- AU
- Australia
- Prior art keywords
- foil
- core
- process according
- outer layer
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 33
- 239000006260 foam Substances 0.000 claims abstract description 32
- 239000011148 porous material Substances 0.000 claims abstract description 11
- 239000011888 foil Substances 0.000 claims description 90
- 238000000034 method Methods 0.000 claims description 35
- 230000008569 process Effects 0.000 claims description 34
- 229920003023 plastic Polymers 0.000 claims description 14
- 239000004033 plastic Substances 0.000 claims description 14
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 13
- 230000001070 adhesive effect Effects 0.000 claims description 13
- 239000011496 polyurethane foam Substances 0.000 claims description 13
- 239000000853 adhesive Substances 0.000 claims description 12
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 11
- -1 polypropylene Polymers 0.000 claims description 11
- 238000005057 refrigeration Methods 0.000 claims description 11
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 230000004888 barrier function Effects 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000003825 pressing Methods 0.000 claims description 5
- 238000007789 sealing Methods 0.000 claims description 5
- 229920001169 thermoplastic Polymers 0.000 claims description 5
- 239000004416 thermosoftening plastic Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 239000004964 aerogel Substances 0.000 claims description 4
- 239000003063 flame retardant Substances 0.000 claims description 4
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 claims description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 230000003319 supportive effect Effects 0.000 claims description 3
- 239000002033 PVDF binder Substances 0.000 claims description 2
- 238000003475 lamination Methods 0.000 claims description 2
- 238000001465 metallisation Methods 0.000 claims description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 2
- 239000002905 metal composite material Substances 0.000 claims 1
- 239000012815 thermoplastic material Substances 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 39
- 238000000465 moulding Methods 0.000 description 10
- 229920002877 acrylic styrene acrylonitrile Polymers 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000009413 insulation Methods 0.000 description 7
- 239000000178 monomer Substances 0.000 description 6
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- YAAQEISEHDUIFO-UHFFFAOYSA-N C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 Chemical compound C=CC#N.OC(=O)C=CC=CC1=CC=CC=C1 YAAQEISEHDUIFO-UHFFFAOYSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- 239000002775 capsule Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920003009 polyurethane dispersion Polymers 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920005832 Basotect® Polymers 0.000 description 1
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000002146 bilateral effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- GOAJGXULHASQGJ-UHFFFAOYSA-N ethene;prop-2-enenitrile Chemical group C=C.C=CC#N GOAJGXULHASQGJ-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 229920005669 high impact polystyrene Polymers 0.000 description 1
- 239000004797 high-impact polystyrene Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229920000592 inorganic polymer Polymers 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000003763 resistance to breakage Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000012205 single-component adhesive Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
Classifications
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- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/18—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer of foamed material
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- B32B15/00—Layered products comprising a layer of metal
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- B32B15/082—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
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- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
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- B32B3/04—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
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- E—FIXED CONSTRUCTIONS
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- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
- E04B1/803—Heat insulating elements slab-shaped with vacuum spaces included in the slab
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/06—Walls
- F25D23/065—Details
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D23/00—General constructional features
- F25D23/08—Parts formed wholly or mainly of plastics materials
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- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
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- B32B2255/205—Metallic coating
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- B32B2266/00—Composition of foam
- B32B2266/02—Organic
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- B32B2266/0278—Polyurethane
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- B32B2266/00—Composition of foam
- B32B2266/02—Organic
- B32B2266/0214—Materials belonging to B32B27/00
- B32B2266/0285—Condensation resins of aldehydes, e.g. with phenols, ureas, melamines
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/304—Insulating
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- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
- B32B2307/7242—Non-permeable
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2509/00—Household appliances
- B32B2509/10—Refrigerators or refrigerating equipment
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B2001/7691—Heat reflecting layers or coatings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2201/00—Insulation
- F25D2201/10—Insulation with respect to heat
- F25D2201/14—Insulation with respect to heat using subatmospheric pressure
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/242—Slab shaped vacuum insulation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/10—Insulation, e.g. vacuum or aerogel insulation
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Architecture (AREA)
- Structural Engineering (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Acoustics & Sound (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Laminated Bodies (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11156998 | 2011-03-04 | ||
| EP11156998.4 | 2011-03-04 | ||
| PCT/EP2012/053393 WO2012119892A1 (fr) | 2011-03-04 | 2012-02-29 | Éléments composites |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2012224772A1 AU2012224772A1 (en) | 2013-09-19 |
| AU2012224772B2 true AU2012224772B2 (en) | 2015-09-03 |
Family
ID=45787200
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2012224772A Ceased AU2012224772B2 (en) | 2011-03-04 | 2012-02-29 | Composite elements |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP2681044A1 (fr) |
| JP (1) | JP2014508057A (fr) |
| KR (1) | KR20140009451A (fr) |
| CN (1) | CN103402754A (fr) |
| AU (1) | AU2012224772B2 (fr) |
| BR (1) | BR112013019576A2 (fr) |
| IN (1) | IN2013CN06932A (fr) |
| MX (1) | MX2013008937A (fr) |
| RU (1) | RU2013144410A (fr) |
| WO (1) | WO2012119892A1 (fr) |
| ZA (1) | ZA201307355B (fr) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9188384B2 (en) | 2011-03-31 | 2015-11-17 | Basf Se | Dynamically evacuable devices comprising organic aerogels or xerogels |
| US9140481B2 (en) | 2012-04-02 | 2015-09-22 | Whirlpool Corporation | Folded vacuum insulated structure |
| US9221210B2 (en) | 2012-04-11 | 2015-12-29 | Whirlpool Corporation | Method to create vacuum insulated cabinets for refrigerators |
| CN103555218B (zh) * | 2013-11-08 | 2015-11-25 | 山西长达交通设施有限公司 | 一种路面裂缝修补材料及其制备方法 |
| US9599392B2 (en) | 2014-02-24 | 2017-03-21 | Whirlpool Corporation | Folding approach to create a 3D vacuum insulated door from 2D flat vacuum insulation panels |
| US9689604B2 (en) | 2014-02-24 | 2017-06-27 | Whirlpool Corporation | Multi-section core vacuum insulation panels with hybrid barrier film envelope |
| US10052819B2 (en) | 2014-02-24 | 2018-08-21 | Whirlpool Corporation | Vacuum packaged 3D vacuum insulated door structure and method therefor using a tooling fixture |
| US10059084B2 (en) * | 2014-07-16 | 2018-08-28 | Valinge Innovation Ab | Method to produce a thermoplastic wear resistant foil |
| US10336040B2 (en) * | 2014-09-25 | 2019-07-02 | Basf Se | Method for manufacturing a composite element for vacuum insulation elements |
| US9476633B2 (en) | 2015-03-02 | 2016-10-25 | Whirlpool Corporation | 3D vacuum panel and a folding approach to create the 3D vacuum panel from a 2D vacuum panel of non-uniform thickness |
| US10161669B2 (en) | 2015-03-05 | 2018-12-25 | Whirlpool Corporation | Attachment arrangement for vacuum insulated door |
| US9897370B2 (en) | 2015-03-11 | 2018-02-20 | Whirlpool Corporation | Self-contained pantry box system for insertion into an appliance |
| US9441779B1 (en) | 2015-07-01 | 2016-09-13 | Whirlpool Corporation | Split hybrid insulation structure for an appliance |
| US10429125B2 (en) | 2015-12-08 | 2019-10-01 | Whirlpool Corporation | Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein |
| US11052579B2 (en) | 2015-12-08 | 2021-07-06 | Whirlpool Corporation | Method for preparing a densified insulation material for use in appliance insulated structure |
| US10041724B2 (en) | 2015-12-08 | 2018-08-07 | Whirlpool Corporation | Methods for dispensing and compacting insulation materials into a vacuum sealed structure |
| US10222116B2 (en) | 2015-12-08 | 2019-03-05 | Whirlpool Corporation | Method and apparatus for forming a vacuum insulated structure for an appliance having a pressing mechanism incorporated within an insulation delivery system |
| US10422573B2 (en) | 2015-12-08 | 2019-09-24 | Whirlpool Corporation | Insulation structure for an appliance having a uniformly mixed multi-component insulation material, and a method for even distribution of material combinations therein |
| US10422569B2 (en) | 2015-12-21 | 2019-09-24 | Whirlpool Corporation | Vacuum insulated door construction |
| US9840042B2 (en) | 2015-12-22 | 2017-12-12 | Whirlpool Corporation | Adhesively secured vacuum insulated panels for refrigerators |
| US9752818B2 (en) | 2015-12-22 | 2017-09-05 | Whirlpool Corporation | Umbilical for pass through in vacuum insulated refrigerator structures |
| US10610985B2 (en) | 2015-12-28 | 2020-04-07 | Whirlpool Corporation | Multilayer barrier materials with PVD or plasma coating for vacuum insulated structure |
| US10018406B2 (en) | 2015-12-28 | 2018-07-10 | Whirlpool Corporation | Multi-layer gas barrier materials for vacuum insulated structure |
| US10030905B2 (en) | 2015-12-29 | 2018-07-24 | Whirlpool Corporation | Method of fabricating a vacuum insulated appliance structure |
| US10807298B2 (en) | 2015-12-29 | 2020-10-20 | Whirlpool Corporation | Molded gas barrier parts for vacuum insulated structure |
| US11247369B2 (en) | 2015-12-30 | 2022-02-15 | Whirlpool Corporation | Method of fabricating 3D vacuum insulated refrigerator structure having core material |
| EP3443285B1 (fr) | 2016-04-15 | 2021-03-10 | Whirlpool Corporation | Armoire de réfrigérateur à isolation sous vide |
| EP3443284B1 (fr) | 2016-04-15 | 2020-11-18 | Whirlpool Corporation | Structure de réfrigérateur à isolation sous vide, dotée de caractéristiques tridimensionnelles |
| CN105922674A (zh) * | 2016-04-22 | 2016-09-07 | 北京航天动力研究所 | 一种轻质复合结构隔热层 |
| US11320193B2 (en) | 2016-07-26 | 2022-05-03 | Whirlpool Corporation | Vacuum insulated structure trim breaker |
| EP3500804B1 (fr) | 2016-08-18 | 2022-06-22 | Whirlpool Corporation | Armoire de réfrigérateur |
| US10598424B2 (en) | 2016-12-02 | 2020-03-24 | Whirlpool Corporation | Hinge support assembly |
| KR102648708B1 (ko) | 2017-10-12 | 2024-03-15 | 트레데가르 서피스 프로텍션, 엘엘씨 | 기판 사이의 인터리프로서 사용하기 위한 필름 |
| US10907888B2 (en) | 2018-06-25 | 2021-02-02 | Whirlpool Corporation | Hybrid pigmented hot stitched color liner system |
| US10907891B2 (en) | 2019-02-18 | 2021-02-02 | Whirlpool Corporation | Trim breaker for a structural cabinet that incorporates a structural glass contact surface |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036129A1 (fr) * | 1996-03-22 | 1997-10-02 | Bayer Aktiengesellschaft | Panneau isole par le vide, revetu des deux cotes d'une feuille composite renfermant un metal ou d'une couche de recouvrement metallique |
| DE19904799A1 (de) * | 1999-02-05 | 2000-08-10 | Zae Bayern | Vakuumisolationspaneel in Komponentenbauweise |
| DE19915311A1 (de) * | 1999-04-03 | 2000-10-05 | Bayer Ag | Vakuum Isolier Paneele |
| DE10028068A1 (de) * | 2000-04-04 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von Vakuum-Isolationspaneelen |
| WO2007147779A1 (fr) * | 2006-06-22 | 2007-12-27 | Basf Se | Éléments d'isolation thermique |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2915457A1 (de) | 1979-04-17 | 1980-10-30 | Basf Ag | Elastischer schaumstoff auf basis eines melamin/formaldehyd-kondensationsproduktes |
| JPS62181795U (fr) * | 1986-05-10 | 1987-11-18 | ||
| DE4319188A1 (de) * | 1993-06-09 | 1994-12-15 | Bayer Ag | Wärmeisolierender Körper |
| DE4418507A1 (de) * | 1994-05-27 | 1995-11-30 | Bayer Ag | Verfahren zur Herstellung offenzelliger Polyurethan-Hartschaumstoffe und ihre Verwendung als Isoliermaterial in Paneelen und als Isolierschaumstoffe |
| DE4439328A1 (de) * | 1994-11-04 | 1996-05-09 | Bayer Ag | Wärmeisolierender Körper |
| DE19503326A1 (de) | 1995-02-02 | 1996-08-08 | Basf Ag | Flexible, transparente Folie auf der Grundlage eines Styrol-Polymerisats, insbesondere für die Lebensmittelverpackung, sowie Verfahren zu deren Herstellung |
| DE19621688A1 (de) | 1996-05-30 | 1997-12-04 | Basf Ag | Transparente, nicht-blockende Folie |
| DE19726732C2 (de) * | 1997-06-24 | 1999-04-29 | Bayer Ag | Kombiniertes Vakuumisolierpaneel aus Polystyrol und Polyurethan sowie dessen Verwendung bei der Herstellung von Dämmelementen |
| ATE246588T1 (de) * | 1999-11-02 | 2003-08-15 | Richard Warrington George | Verfahren und vorrichtung zum warmformen von kunststofffolien |
| DE10321081A1 (de) | 2003-05-09 | 2004-12-02 | Basf Ag | Mischungen enthaltend thermoplastisches Polyurethan und ASA |
| DE102004049632B4 (de) | 2004-10-11 | 2008-07-31 | Basf Se | Verbundschichtplatte für Brandschutztüren |
| DE102005021994A1 (de) * | 2005-05-09 | 2006-11-23 | Basf Ag | Verfahren zur Herstellung von Vakuumisolations-Paneelen |
| JP2007056903A (ja) * | 2005-08-22 | 2007-03-08 | Nissan Motor Co Ltd | 断熱材及びその断熱材を用いた断熱構造体 |
| DE102005059303A1 (de) | 2005-12-09 | 2007-06-21 | Basf Ag | Nanoporösen Polymerschaumstoffe aus Polykondensations-Reaktivharzen |
| US20080248278A1 (en) * | 2007-04-02 | 2008-10-09 | General Electric Company | Fiber reinforced thermoplastic sheets with surface coverings and methods of making |
| WO2008135550A2 (fr) | 2007-05-08 | 2008-11-13 | Basf Se | Procédé de revêtement des deux faces d'une pièce moulée en un produit mousse dur |
| EP2072548B1 (fr) | 2007-12-19 | 2017-02-22 | Basf Se | Procédé de fabrication de mousses rigides contenant des groupes d'uréthane et de groupes d'isocyanurate |
-
2012
- 2012-02-29 CN CN2012800109431A patent/CN103402754A/zh active Pending
- 2012-02-29 JP JP2013555857A patent/JP2014508057A/ja active Pending
- 2012-02-29 BR BR112013019576A patent/BR112013019576A2/pt not_active IP Right Cessation
- 2012-02-29 MX MX2013008937A patent/MX2013008937A/es not_active Application Discontinuation
- 2012-02-29 KR KR1020137026345A patent/KR20140009451A/ko not_active Application Discontinuation
- 2012-02-29 AU AU2012224772A patent/AU2012224772B2/en not_active Ceased
- 2012-02-29 IN IN6932CHN2013 patent/IN2013CN06932A/en unknown
- 2012-02-29 WO PCT/EP2012/053393 patent/WO2012119892A1/fr active Application Filing
- 2012-02-29 RU RU2013144410/05A patent/RU2013144410A/ru not_active Application Discontinuation
- 2012-02-29 EP EP12706833.6A patent/EP2681044A1/fr not_active Withdrawn
-
2013
- 2013-10-02 ZA ZA2013/07355A patent/ZA201307355B/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997036129A1 (fr) * | 1996-03-22 | 1997-10-02 | Bayer Aktiengesellschaft | Panneau isole par le vide, revetu des deux cotes d'une feuille composite renfermant un metal ou d'une couche de recouvrement metallique |
| DE19904799A1 (de) * | 1999-02-05 | 2000-08-10 | Zae Bayern | Vakuumisolationspaneel in Komponentenbauweise |
| DE19915311A1 (de) * | 1999-04-03 | 2000-10-05 | Bayer Ag | Vakuum Isolier Paneele |
| DE10028068A1 (de) * | 2000-04-04 | 2001-10-11 | Basf Ag | Verfahren zur Herstellung von Vakuum-Isolationspaneelen |
| WO2007147779A1 (fr) * | 2006-06-22 | 2007-12-27 | Basf Se | Éléments d'isolation thermique |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2014508057A (ja) | 2014-04-03 |
| WO2012119892A1 (fr) | 2012-09-13 |
| CN103402754A (zh) | 2013-11-20 |
| AU2012224772A1 (en) | 2013-09-19 |
| IN2013CN06932A (fr) | 2015-08-07 |
| RU2013144410A (ru) | 2015-04-10 |
| ZA201307355B (en) | 2014-12-23 |
| BR112013019576A2 (pt) | 2017-06-13 |
| MX2013008937A (es) | 2013-10-01 |
| KR20140009451A (ko) | 2014-01-22 |
| EP2681044A1 (fr) | 2014-01-08 |
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| FGA | Letters patent sealed or granted (standard patent) | ||
| MK14 | Patent ceased section 143(a) (annual fees not paid) or expired |